{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,19]],"date-time":"2026-09-19T01:17:40Z","timestamp":1789780660370,"version":"4.0.1"},"reference-count":78,"publisher":"Royal Society of Chemistry (RSC)","issue":"39","license":[{"start":{"date-parts":[[2021,9,20]],"date-time":"2021-09-20T00:00:00Z","timestamp":1632096000000},"content-version":"vor","delay-in-days":262,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["RTG 2620"],"award-info":[{"award-number":["RTG 2620"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100010663","name":"H2020 European Research Council","doi-asserted-by":"publisher","award":["ERC CoG 772299"],"award-info":[{"award-number":["ERC CoG 772299"]}],"id":[{"id":"10.13039\/100010663","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100007215","name":"Verband der Chemischen Industrie","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100007215","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<jats:p>Ion-pairing strongly influence the reactivity of low-oxidation state transition metalate anions, enabling the synthesis of novel phosphaorganometallic compounds.<\/jats:p>","DOI":"10.1039\/d1dt02621f","type":"journal-article","created":{"date-parts":[[2021,9,20]],"date-time":"2021-09-20T07:29:59Z","timestamp":1632122999000},"page":"13985-13992","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":25,"title":["Low-oxidation state cobalt\u2013magnesium complexes: ion-pairing and reactivity"],"prefix":"10.1039","volume":"50","author":[{"given":"John A.","family":"Kelly","sequence":"first","affiliation":[{"name":"University of Regensburg, Institute of Inorganic Chemistry, 93040 Regensburg, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Johannes","family":"Gram\u00fcller","sequence":"additional","affiliation":[{"name":"University of Regensburg, Institute of Organic Chemistry, 93040 Regensburg, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3052-0077","authenticated-orcid":false,"given":"Ruth M.","family":"Gschwind","sequence":"additional","affiliation":[{"name":"University of Regensburg, Institute of Organic Chemistry, 93040 Regensburg, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4066-6483","authenticated-orcid":false,"given":"Robert","family":"Wolf","sequence":"additional","affiliation":[{"name":"University of Regensburg, Institute of Inorganic Chemistry, 93040 Regensburg, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2021]]},"reference":[{"key":"D1DT02621F\/cit1a\/1","doi-asserted-by":"crossref","first-page":"3167","DOI":"10.1021\/ic052110i","volume":"45","author":"Ellis","year":"2006","journal-title":"Inorg. Chem."},{"key":"D1DT02621F\/cit1b\/1","doi-asserted-by":"crossref","first-page":"9538","DOI":"10.1039\/C8DT05029E","volume":"48","author":"Ellis","year":"2019","journal-title":"Dalton Trans."},{"key":"D1DT02621F\/cit2a\/1","doi-asserted-by":"crossref","first-page":"752","DOI":"10.1002\/anie.197507521","volume":"14","author":"Jonas","year":"1975","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"D1DT02621F\/cit2b\/1","doi-asserted-by":"crossref","first-page":"767","DOI":"10.1002\/anie.197607671","volume":"15","author":"Jonas","year":"1976","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"D1DT02621F\/cit2c\/1","doi-asserted-by":"crossref","first-page":"1211","DOI":"10.1002\/1521-3773(20020402)41:7<1211::AID-ANIE1211>3.0.CO;2-I","volume":"41","author":"Brennessel","year":"2002","journal-title":"Angew. Chem., Int. Ed."},{"key":"D1DT02621F\/cit2d\/1","doi-asserted-by":"crossref","first-page":"6132","DOI":"10.1002\/anie.200701353","volume":"46","author":"Brennessel","year":"2007","journal-title":"Angew. Chem., Int. Ed."},{"key":"D1DT02621F\/cit2e\/1","doi-asserted-by":"crossref","first-page":"9076","DOI":"10.1021\/ic301240u","volume":"51","author":"Brennessel","year":"2012","journal-title":"Inorg. Chem."},{"key":"D1DT02621F\/cit3a\/1","first-page":"3556","volume":"12","author":"Clark","year":"1975","journal-title":"J. Am. Chem. Soc."},{"key":"D1DT02621F\/cit3b\/1","doi-asserted-by":"crossref","first-page":"6132","DOI":"10.1002\/anie.200701353","volume":"46","author":"Brennessel","year":"2007","journal-title":"Angew. Chem., Int. Ed."},{"key":"D1DT02621F\/cit3c\/1","doi-asserted-by":"crossref","first-page":"8692","DOI":"10.1002\/anie.200802780","volume":"47","author":"Jilek","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"D1DT02621F\/cit3d\/1","doi-asserted-by":"crossref","first-page":"10410","DOI":"10.1021\/ja204304f","volume":"133","author":"Huang","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"D1DT02621F\/cit4a\/1","doi-asserted-by":"crossref","first-page":"832","DOI":"10.1126\/science.1067325","volume":"295","author":"Urn\u00e9\u017eius","year":"2002","journal-title":"Science"},{"key":"D1DT02621F\/cit4b\/1","doi-asserted-by":"crossref","first-page":"3322","DOI":"10.1021\/om030105l","volume":"22","author":"Ellis","year":"2003","journal-title":"Organometallics"},{"key":"D1DT02621F\/cit4c\/1","doi-asserted-by":"crossref","first-page":"6113","DOI":"10.1002\/chem.201905537","volume":"26","author":"Maier","year":"2020","journal-title":"Chem. \u2013 Eur. J."},{"key":"D1DT02621F\/cit5a\/1","doi-asserted-by":"crossref","first-page":"440","DOI":"10.1002\/anie.200502859","volume":"45","author":"F\u00fcrstner","year":"2006","journal-title":"Angew. Chem., Int. Ed."},{"key":"D1DT02621F\/cit5b\/1","doi-asserted-by":"crossref","first-page":"776","DOI":"10.1039\/C2SC21667A","volume":"4","author":"G\u00fclak","year":"2013","journal-title":"Chem. Sci."},{"key":"D1DT02621F\/cit5c\/1","doi-asserted-by":"crossref","first-page":"1572","DOI":"10.1002\/cctc.201100199","volume":"3","author":"Weber","year":"2011","journal-title":"ChemCatChem"},{"key":"D1DT02621F\/cit5d\/1","doi-asserted-by":"crossref","first-page":"13628","DOI":"10.1021\/jacs.8b09849","volume":"140","author":"Nattmann","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"D1DT02621F\/cit6a\/1","doi-asserted-by":"crossref","first-page":"44","DOI":"10.1039\/C39740000044","author":"Felkin","year":"1974","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"D1DT02621F\/cit6b\/1","doi-asserted-by":"crossref","first-page":"3315","DOI":"10.1039\/c3cc41360h","volume":"49","author":"Blake","year":"2013","journal-title":"Chem. Commun."},{"key":"D1DT02621F\/cit6c\/1","doi-asserted-by":"crossref","first-page":"923","DOI":"10.1002\/anie.198609231","volume":"25","author":"Jonas","year":"1986","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"D1DT02621F\/cit6c\/2","doi-asserted-by":"crossref","first-page":"12352","DOI":"10.1021\/jacs.5b07866","volume":"137","author":"Blake","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"D1DT02621F\/cit6d\/1","doi-asserted-by":"crossref","first-page":"64","DOI":"10.1016\/j.poly.2016.02.028","volume":"116","author":"Green","year":"2016","journal-title":"Polyhedron"},{"key":"D1DT02621F\/cit6e\/1","doi-asserted-by":"crossref","first-page":"97","DOI":"10.1016\/j.ica.2016.12.029","volume":"458","author":"Birchall","year":"2017","journal-title":"Inorg. Chim. Acta"},{"key":"D1DT02621F\/cit6f\/1","doi-asserted-by":"crossref","first-page":"1805","DOI":"10.1039\/C8CC09701A","volume":"55","author":"Gar\u00e7on","year":"2019","journal-title":"Chem. Commun."},{"key":"D1DT02621F\/cit7a\/1","doi-asserted-by":"crossref","first-page":"5283","DOI":"10.1021\/ja5021348","volume":"136","author":"Hicks","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"D1DT02621F\/cit7b\/1","doi-asserted-by":"crossref","first-page":"10000","DOI":"10.1002\/anie.201504818","volume":"54","author":"Hicks","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"D1DT02621F\/cit7c\/1","doi-asserted-by":"crossref","first-page":"2348","DOI":"10.1039\/C7SC05059C","volume":"9","author":"Bakewell","year":"2018","journal-title":"Chem. Sci."},{"key":"D1DT02621F\/cit7d\/1","first-page":"390","volume":"574","author":"Gar\u00e7on","year":"2019","journal-title":"Science"},{"key":"D1DT02621F\/cit8a\/1","doi-asserted-by":"crossref","first-page":"15358","DOI":"10.1021\/ja207487j","volume":"133","author":"Blake","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"D1DT02621F\/cit8b\/1","first-page":"47","volume-title":"Molecular Metal\u2013Metal Bonds: Compounds, Synthesis, Properties","author":"Gade","year":"2015","unstructured":"L. H.Gade ,  Group 4 Metal\u2013Metal Bonds , in  Molecular Metal\u2013Metal Bonds: Compounds, Synthesis, Properties , ed.  S. T. Liddle ,  Wiley-VCH ,  Weinheim ,  2015 , p.  47"},{"key":"D1DT02621F\/cit9a\/1","doi-asserted-by":"crossref","first-page":"3139","DOI":"10.1002\/chem.201605222","volume":"23","author":"B\u00fcschelburger","year":"2017","journal-title":"Chem. \u2013 Eur. J."},{"key":"D1DT02621F\/cit9b\/1","doi-asserted-by":"crossref","first-page":"13195","DOI":"10.1021\/jacs.8b08517","volume":"140","author":"Hoidn","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"D1DT02621F\/cit9c\/1","doi-asserted-by":"crossref","first-page":"18931","DOI":"10.1002\/anie.201908744","volume":"58","author":"Hoidn","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"D1DT02621F\/cit10a\/1","doi-asserted-by":"crossref","first-page":"3315","DOI":"10.1039\/c3cc41360h","volume":"49","author":"Blake","year":"2013","journal-title":"Chem. Commun."},{"key":"D1DT02621F\/cit10b\/1","doi-asserted-by":"crossref","first-page":"5283","DOI":"10.1021\/ja5021348","volume":"136","author":"Hicks","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"D1DT02621F\/cit11\/1","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Crystallogr., Sect. B: Struct. Sci., Cryst. Eng. Mater."},{"key":"D1DT02621F\/cit12a\/1","doi-asserted-by":"crossref","first-page":"3297","DOI":"10.1039\/b508541a","volume":"7","author":"Weigend","year":"2005","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D1DT02621F\/cit12b\/1","doi-asserted-by":"crossref","first-page":"1057","DOI":"10.1039\/b515623h","volume":"8","author":"Weigend","year":"2006","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D1DT02621F\/cit12c\/1","doi-asserted-by":"crossref","first-page":"1456","DOI":"10.1002\/jcc.21759","volume":"32","author":"Grimme","year":"2011","journal-title":"J. Comput. Chem."},{"key":"D1DT02621F\/cit12d\/1","doi-asserted-by":"crossref","first-page":"154104","DOI":"10.1063\/1.3382344","volume":"132","author":"Grimme","year":"2010","journal-title":"J. Chem. Phys."},{"key":"D1DT02621F\/cit12e\/1","first-page":"73","volume":"2","author":"Neese","year":"2012","journal-title":"Wiley Interdiscip. Rev.: Comput. Mol. Sci."},{"key":"D1DT02621F\/cit12f\/1","first-page":"e1327","volume":"8","author":"Neese","year":"2018","journal-title":"Wiley Interdiscip. Rev.: Comput. Mol. Sci."},{"key":"D1DT02621F\/cit13\/1","doi-asserted-by":"crossref","first-page":"4834","DOI":"10.1021\/ct400687b","volume":"9","author":"Knizia","year":"2013","journal-title":"J. Chem. Theory Comput."},{"key":"D1DT02621F\/cit14a\/1","doi-asserted-by":"crossref","first-page":"4329","DOI":"10.1021\/cr3000048","volume":"112","author":"Bauer","year":"2012","journal-title":"Chem. Rev."},{"key":"D1DT02621F\/cit14b\/1","doi-asserted-by":"crossref","first-page":"10030","DOI":"10.1002\/anie.201205438","volume":"51","author":"Bauer","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"key":"D1DT02621F\/cit14c\/1","doi-asserted-by":"crossref","first-page":"4240","DOI":"10.1002\/anie.201310520","volume":"53","author":"Bertsch","year":"2014","journal-title":"Angew. Chem., Int. Ed."},{"key":"D1DT02621F\/cit14d\/1","doi-asserted-by":"crossref","first-page":"3649","DOI":"10.1021\/om5002414","volume":"33","author":"Bertsch","year":"2014","journal-title":"Organometallics"},{"key":"D1DT02621F\/cit14e\/1","doi-asserted-by":"crossref","first-page":"16140","DOI":"10.1021\/jacs.6b10609","volume":"138","author":"Bertermann","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"D1DT02621F\/cit15a\/1","doi-asserted-by":"crossref","first-page":"4584","DOI":"10.1002\/anie.200800813","volume":"47","author":"Wolf","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"D1DT02621F\/cit15b\/1","doi-asserted-by":"crossref","first-page":"14322","DOI":"10.1002\/chem.201001913","volume":"16","author":"Wolf","year":"2010","journal-title":"Chem. \u2013 Eur. J."},{"key":"D1DT02621F\/cit16a\/1","doi-asserted-by":"crossref","first-page":"12684","DOI":"10.1039\/C8DT03124J","volume":"47","author":"Garcia","year":"2018","journal-title":"Dalton Trans."},{"key":"D1DT02621F\/cit16b\/1","doi-asserted-by":"crossref","first-page":"2025","DOI":"10.1002\/chem.201804802","volume":"25","author":"Pahl","year":"2019","journal-title":"Chem. \u2013 Eur. J."},{"key":"D1DT02621F\/cit17a\/1","doi-asserted-by":"crossref","first-page":"1638","DOI":"10.1002\/ejic.201301173","author":"Malberg","year":"2014","journal-title":"Eur. J. Inorg. Chem."},{"key":"D1DT02621F\/cit17b\/1","doi-asserted-by":"crossref","first-page":"2021","DOI":"10.1021\/om980862x","volume":"18","author":"Heinemann","year":"1999","journal-title":"Organometallics"},{"key":"D1DT02621F\/cit17c\/1","doi-asserted-by":"crossref","first-page":"3733","DOI":"10.1039\/B607489H","author":"Jones","year":"2006","journal-title":"Dalton Trans."},{"key":"D1DT02621F\/cit17d\/1","doi-asserted-by":"crossref","first-page":"2356","DOI":"10.1002\/chem.201203606","volume":"19","author":"Malberg","year":"2013","journal-title":"Chem. \u2013 Eur. J."},{"key":"D1DT02621F\/cit17e\/1","doi-asserted-by":"crossref","first-page":"1625","DOI":"10.1002\/ejic.201301299","author":"Rummel","year":"2014","journal-title":"Eur. J. Inorg. Chem."},{"key":"D1DT02621F\/cit17f\/1","doi-asserted-by":"crossref","first-page":"57","DOI":"10.1016\/j.ccr.2013.10.005","volume":"270","author":"Chirila","year":"2014","journal-title":"Coord. Chem. Rev."},{"key":"D1DT02621F\/cit17g\/1","doi-asserted-by":"crossref","first-page":"736","DOI":"10.1002\/ejic.201500583","author":"R\u00f6dl","year":"2016","journal-title":"Eur. J. Inorg. Chem."},{"key":"D1DT02621F\/cit17h\/1","doi-asserted-by":"crossref","first-page":"6180","DOI":"10.1002\/chem.201900170","volume":"25","author":"R\u00f6dl","year":"2019","journal-title":"Chem. \u2013 Eur. J."},{"key":"D1DT02621F\/cit18a\/1","doi-asserted-by":"crossref","first-page":"644","DOI":"10.1002\/anie.198606441","volume":"25","author":"Binger","year":"1986","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"D1DT02621F\/cit18b\/1","doi-asserted-by":"crossref","first-page":"20","DOI":"10.1016\/0022-328X(88)80385-1","volume":"350","author":"Scherer","year":"1988","journal-title":"J. Organomet. Chem."},{"key":"D1DT02621F\/cit18c\/1","doi-asserted-by":"crossref","first-page":"1355","DOI":"10.1002\/anie.198913551","volume":"28","author":"Scherer","year":"1989","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"D1DT02621F\/cit18d\/1","doi-asserted-by":"crossref","first-page":"827","DOI":"10.1002\/zaac.19936190504","volume":"619","author":"Scherer","year":"1993","journal-title":"Z. Anorg. Allg. Chem."},{"key":"D1DT02621F\/cit18e\/1","doi-asserted-by":"crossref","first-page":"185","DOI":"10.1016\/0022-328X(96)06305-X","volume":"522","author":"Herberhold","year":"1996","journal-title":"J. Organomet. Chem."},{"key":"D1DT02621F\/cit18f\/1","doi-asserted-by":"crossref","first-page":"2120","DOI":"10.1039\/c1sc00413a","volume":"2","author":"Walter","year":"2011","journal-title":"Chem. Sci."},{"key":"D1DT02621F\/cit19a\/1","doi-asserted-by":"crossref","first-page":"451","DOI":"10.1016\/S0022-328X(97)00342-2","volume":"545","author":"Scheer","year":"1997","journal-title":"J. Organomet. Chem."},{"key":"D1DT02621F\/cit19b\/1","first-page":"1617","volume":"56","author":"Dielmann","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"D1DT02621F\/cit20a\/1","doi-asserted-by":"crossref","first-page":"1355","DOI":"10.1002\/anie.198913551","volume":"28","author":"Scherer","year":"1989","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"D1DT02621F\/cit20b\/1","doi-asserted-by":"crossref","first-page":"185","DOI":"10.1016\/0022-328X(96)06305-X","volume":"522","author":"Herberhold","year":"1996","journal-title":"J. Organomet. Chem."},{"key":"D1DT02621F\/cit20c\/1","doi-asserted-by":"crossref","first-page":"14833","DOI":"10.1002\/anie.201606074","volume":"55","author":"Dielmann","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"D1DT02621F\/cit20d\/1","doi-asserted-by":"crossref","first-page":"3693","DOI":"10.1039\/C7DT04641C","volume":"47","author":"Chakraborty","year":"2018","journal-title":"Dalton Trans."},{"key":"D1DT02621F\/cit20e\/1","doi-asserted-by":"crossref","first-page":"2244","DOI":"10.1039\/C7CC09730A","volume":"54","author":"Heinl","year":"2018","journal-title":"Chem. Commun."},{"key":"D1DT02621F\/cit20f\/1","doi-asserted-by":"crossref","first-page":"15329","DOI":"10.1002\/anie.201908885","volume":"58","author":"Mandla","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"D1DT02621F\/cit21a\/1","doi-asserted-by":"crossref","first-page":"7312","DOI":"10.1002\/anie.201703175","volume":"56","author":"M\u00fcller","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"D1DT02621F\/cit21b\/1","doi-asserted-by":"crossref","first-page":"3675","DOI":"10.1002\/chem.202005025","volume":"27","author":"M\u00fcller","year":"2020","journal-title":"Chem. \u2013 Eur. J."},{"key":"D1DT02621F\/cit22\/1","doi-asserted-by":"crossref","first-page":"8332","DOI":"10.1002\/chem.201901061","volume":"25","author":"R\u00f6dl","year":"2019","journal-title":"Chem. \u2013 Eur. J."}],"container-title":["Dalton Transactions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2021\/DT\/D1DT02621F","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T03:15:12Z","timestamp":1782875712000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/dt\/article\/50\/39\/13985-13992\/725701"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021]]},"references-count":78,"journal-issue":{"issue":"39","published-print":{"date-parts":[[2021,10,12]]}},"URL":"https:\/\/doi.org\/10.1039\/d1dt02621f","relation":{},"ISSN":["1477-9226","1477-9234"],"issn-type":[{"value":"1477-9226","type":"print"},{"value":"1477-9234","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021]]}}}