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Biomol. Chem."],"abstract":"<jats:p>A three starting material four component reaction is developed for the synthesis of \u03b1,\u03b2-unsaturated ketones and \u03b2-amino ketones. TMEDA is used a dual synthon to provide two carbons in the Selectfluor system.<\/jats:p>","DOI":"10.1039\/d1ob02043a","type":"journal-article","created":{"date-parts":[[2021,12,9]],"date-time":"2021-12-09T10:21:37Z","timestamp":1639045297000},"page":"415-419","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Synthesis of methylene-bridged \u03b1,\u03b2-unsaturated ketones: \u03b1-C\n                    <sub>\n                      sp\n                      <sup>3<\/sup>\n                    <\/sub>\n                    \u2013H methylenation of aromatic ketones using Selectfluor as a mild oxidant"],"prefix":"10.1039","volume":"20","author":[{"given":"Yuan","family":"Zhang","sequence":"first","affiliation":[{"name":"Fujian Normal University, College of Chemistry and Materials Science, Fuzhou 350007, China"},{"name":"State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiqi","family":"Liu","sequence":"additional","affiliation":[{"name":"Fujian Normal University, College of Chemistry and Materials Science, Fuzhou 350007, China"},{"name":"State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tingyu","family":"Zhu","sequence":"additional","affiliation":[{"name":"Fujian Normal University, College of Chemistry and Materials Science, Fuzhou 350007, China"},{"name":"State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ying","family":"Huang","sequence":"additional","affiliation":[{"name":"Fujian Normal University, College of Chemistry and Materials Science, Fuzhou 350007, China"},{"name":"State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weibin","family":"Fan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9034-2842","authenticated-orcid":false,"given":"Deguang","family":"Huang","sequence":"additional","affiliation":[{"name":"Fujian Normal University, College of Chemistry and Materials Science, Fuzhou 350007, China"},{"name":"State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2022]]},"reference":[{"key":"D1OB02043A\/cit1a\/1","doi-asserted-by":"crossref","first-page":"3168","DOI":"10.1002\/1521-3773(20000915)39:18<3168::AID-ANIE3168>3.0.CO;2-U","volume":"39","author":"D\u00f6mling","year":"2000","journal-title":"Angew. 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