{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,10]],"date-time":"2026-10-10T17:56:45Z","timestamp":1791655005835,"version":"4.3.4"},"reference-count":47,"publisher":"Royal Society of Chemistry (RSC)","issue":"39","license":[{"start":{"date-parts":[[2021,7,12]],"date-time":"2021-07-12T00:00:00Z","timestamp":1626048000000},"content-version":"vor","delay-in-days":192,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"crossref","award":["GM061555"],"award-info":[{"award-number":["GM061555"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"crossref","award":["GM139064"],"award-info":[{"award-number":["GM139064"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/100008113","name":"Indiana University-Purdue University Indianapolis","doi-asserted-by":"crossref","id":[{"id":"10.13039\/100008113","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/100000002","name":"National Institutes of Health","doi-asserted-by":"crossref","id":[{"id":"10.13039\/100000002","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/100006976","name":"Lilly Endowment","doi-asserted-by":"crossref","id":[{"id":"10.13039\/100006976","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["RSC Adv."],"abstract":"<p>\n                    The interligand communication between non-innocent dithiolene ligands of different oxidation states has been described in a Mo system. The fully reduced ene-dithiolate (Dt\n                    <sup>2\u2212<\/sup>\n                    ) acts as a donor moiety to the oxidized dithione (Dt\n                    <sup>0<\/sup>\n                    ) in an LL\u2032CT process.\n                  <\/p>","DOI":"10.1039\/d1ra04716g","type":"journal-article","created":{"date-parts":[[2021,7,12]],"date-time":"2021-07-12T06:05:07Z","timestamp":1626069907000},"page":"24381-24386","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Interligand communication in a metal mediated LL\u2032CT system \u2013 a case study"],"prefix":"10.1039","volume":"11","author":[{"given":"Sara A.","family":"Dille","sequence":"first","affiliation":[{"name":"Department of Chemistry and Chemical Biology"},{"name":"Indiana University \u2013 Purdue University Indianapolis"},{"name":"Indianapolis"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8037-9326","authenticated-orcid":false,"given":"Kyle J.","family":"Colston","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Biology"},{"name":"Indiana University \u2013 Purdue University Indianapolis"},{"name":"Indianapolis"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stephen C.","family":"Ratvasky","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry"},{"name":"Duquesne University"},{"name":"Pittsburgh"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingzhi","family":"Pu","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Biology"},{"name":"Indiana University \u2013 Purdue University Indianapolis"},{"name":"Indianapolis"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1232-418X","authenticated-orcid":false,"given":"Partha","family":"Basu","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Biology"},{"name":"Indiana University \u2013 Purdue University Indianapolis"},{"name":"Indianapolis"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2021]]},"reference":[{"key":"D1RA04716G-(cit1)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"12961","DOI":"10.1021\/acs.inorgchem.0c00240","volume":"59","author":"Mukherjee","year":"2020","journal-title":"Inorg. Chem."},{"key":"D1RA04716G-(cit2)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1580","DOI":"10.1016\/j.ccr.2010.01.009","volume":"254","author":"Kaim","year":"2010","journal-title":"Coord. Chem. Rev."},{"key":"D1RA04716G-(cit3)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"762","DOI":"10.1016\/S0006-3495(93)81437-1","volume":"64","author":"Whittaker","year":"1993","journal-title":"Biophys. J."},{"key":"D1RA04716G-(cit4)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"7649","DOI":"10.1002\/chem.201900733","volume":"25","author":"Oshita","year":"2019","journal-title":"Chem.\u2013Eur. J."},{"key":"D1RA04716G-(cit5)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"537","DOI":"10.1126\/science.279.5350.537","volume":"279","author":"Wang","year":"1998","journal-title":"Science"},{"key":"D1RA04716G-(cit6)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"12869","DOI":"10.1021\/ja982914f","volume":"120","author":"Donahue","year":"1998","journal-title":"J. Am. Chem. Soc."},{"key":"D1RA04716G-(cit7)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"8332","DOI":"10.1039\/C9NJ01020C","volume":"43","author":"Moula","year":"2019","journal-title":"New J. Chem."},{"key":"D1RA04716G-(cit8)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"42","DOI":"10.1016\/j.ica.2018.10.001","volume":"485","author":"Sugimoto","year":"2019","journal-title":"Inorg. Chim. Acta"},{"key":"D1RA04716G-(cit9)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3557","DOI":"10.1021\/ic051653p","volume":"45","author":"Nemykin","year":"2006","journal-title":"Inorg. Chem."},{"key":"D1RA04716G-(cit10)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"7703","DOI":"10.1021\/acs.inorgchem.5b00531","volume":"54","author":"Mogesa","year":"2015","journal-title":"Inorg. Chem."},{"key":"D1RA04716G-(cit11)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5023","DOI":"10.1039\/b904113c","author":"Perera","year":"2009","journal-title":"Dalton Trans."},{"key":"D1RA04716G-(cit12)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"10866","DOI":"10.1039\/C6DT00942E","volume":"45","author":"Thomas","year":"2016","journal-title":"Dalton Trans."},{"key":"D1RA04716G-(cit13)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"15355","DOI":"10.1039\/D0DT03074K","volume":"49","author":"Saha","year":"2020","journal-title":"Dalton Trans."},{"key":"D1RA04716G-(cit14)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"36","DOI":"10.1021\/ic401985d","volume":"53","author":"Rajput","year":"2014","journal-title":"Inorg. Chem."},{"key":"D1RA04716G-(cit15)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"785","DOI":"10.1021\/acs.inorgchem.5b02252","volume":"55","author":"Yang","year":"2016","journal-title":"Inorg. Chem."},{"key":"D1RA04716G-(cit16)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5467","DOI":"10.1002\/ejic.201101084","volume":"2011","author":"Mtei","year":"2011","journal-title":"Eur. J. Inorg. Chem."},{"key":"D1RA04716G-(cit17)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9737","DOI":"10.1021\/ic201881k","volume":"50","author":"Chirik","year":"2011","journal-title":"Inorg. Chem."},{"key":"D1RA04716G-(cit18)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4109","DOI":"10.1039\/C5SC01140J","volume":"6","author":"Skara","year":"2015","journal-title":"Chem. Sci."},{"key":"D1RA04716G-(cit19)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9741","DOI":"10.1021\/ic2011748","volume":"50","author":"Eisenberg","year":"2011","journal-title":"Inorg. Chem."},{"key":"D1RA04716G-(cit20)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2857","DOI":"10.1016\/j.ica.2010.04.004","volume":"363","author":"Basu","year":"2010","journal-title":"Inorg. Chim. Acta"},{"key":"D1RA04716G-(cit21)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1541","DOI":"10.1039\/c39860001541","author":"Boyde","year":"1986","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"D1RA04716G-(cit22)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"607","DOI":"10.1246\/cl.1994.607","author":"Oku","year":"1994","journal-title":"Chem. Lett."},{"key":"D1RA04716G-(cit23)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4387","DOI":"10.1002\/ejic.201100331","volume":"2011","author":"Samuel","year":"2011","journal-title":"Eur. J. Inorg. Chem."},{"key":"D1RA04716G-(cit24)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Crystallogr., Sect. B: Struct. Sci., Cryst. Eng. Mater."},{"key":"D1RA04716G-(cit25)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1729","DOI":"10.1021\/ja00423a017","volume":"98","author":"Lauher","year":"1976","journal-title":"J. Am. Chem. Soc."},{"key":"D1RA04716G-(cit26)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3719","DOI":"10.1073\/pnas.0636832100","volume":"100","author":"Joshi","year":"2003","journal-title":"Proc. Natl. Acad. Sci. U. S. A."},{"key":"D1RA04716G-(cit27)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"11021","DOI":"10.1021\/ic201566n","volume":"50","author":"Wiebelhaus","year":"2011","journal-title":"Inorg. Chem."},{"key":"D1RA04716G-(cit28)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"7003","DOI":"10.1021\/ic010523n","volume":"40","author":"Marlin","year":"2001","journal-title":"Inorg. Chem."},{"key":"D1RA04716G-(cit29)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"25","DOI":"10.1107\/S0108768104029751","volume":"61","author":"Marchivie","year":"2005","journal-title":"Acta Crystallogr., Sect. B: Struct. Sci."},{"key":"D1RA04716G-(cit30)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison","year":"1984","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"D1RA04716G-(cit31)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"370","DOI":"10.1016\/j.poly.2016.01.023","volume":"114","author":"Ratvasky","year":"2016","journal-title":"Polyhedron"},{"key":"D1RA04716G-(cit32)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1552","DOI":"10.1039\/b700096k","author":"Ray","year":"2007","journal-title":"Dalton Trans."},{"key":"D1RA04716G-(cit33)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3558","DOI":"10.1039\/b503828f","author":"Sugimoto","year":"2005","journal-title":"Dalton Trans."},{"key":"D1RA04716G-(cit34)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3985","DOI":"10.1039\/a703682e","author":"Davies","year":"1997","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"D1RA04716G-(cit35)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2655","DOI":"10.1021\/cr990413m","volume":"101","author":"Demadis","year":"2001","journal-title":"Chem. Rev."},{"key":"D1RA04716G-(cit36)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"7830","DOI":"10.1021\/ja100220x","volume":"132","author":"Matz","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"D1RA04716G-(cit37)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9804","DOI":"10.1021\/ic200783a","volume":"50","author":"Matz","year":"2011","journal-title":"Inorg. Chem."},{"key":"D1RA04716G-(cit38)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"914","DOI":"10.1002\/ejic.202001155","volume":"2021","author":"Dille","year":"2021","journal-title":"Eur. J. Inorg. Chem."},{"key":"D1RA04716G-(cit39)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6027","DOI":"10.1021\/ja00460a031","volume":"99","author":"Kamlet","year":"1977","journal-title":"J. Am. Chem. Soc."},{"key":"D1RA04716G-(cit40)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"377","DOI":"10.1021\/ja00418a009","volume":"98","author":"Kamlet","year":"1976","journal-title":"J. Am. Chem. Soc."},{"key":"D1RA04716G-(cit41)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"820","DOI":"10.1021\/ac00159a018","volume":"60","author":"Cheong","year":"1988","journal-title":"Anal. Chem."},{"key":"D1RA04716G-(cit42)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"7077","DOI":"10.1021\/ic500873y","volume":"53","author":"Dong","year":"2014","journal-title":"Inorg. Chem."},{"key":"D1RA04716G-(cit43)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1016","DOI":"10.1016\/j.ccr.2011.02.010","volume":"255","author":"Basu","year":"2011","journal-title":"Coord. Chem. Rev."},{"key":"D1RA04716G-(cit44)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"373","DOI":"10.1007\/s00775-014-1228-0","volume":"20","author":"Basu","year":"2015","journal-title":"J. Biol. Inorg Chem."},{"key":"D1RA04716G-(cit45)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"453","DOI":"10.1002\/cbic.201600004","volume":"17","author":"Lee","year":"2016","journal-title":"ChemBioChem"},{"key":"D1RA04716G-(cit46)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"14773","DOI":"10.1073\/pnas.1200671109","volume":"109","author":"Rothery","year":"2012","journal-title":"Proc. Natl. Acad. Sci. U. S. A."},{"key":"D1RA04716G-(cit47)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3963","DOI":"10.1021\/cr400443z","volume":"114","author":"Hille","year":"2014","journal-title":"Chem. Rev."}],"container-title":["RSC Advances"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2021\/RA\/D1RA04716G","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T17:49:14Z","timestamp":1782928154000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/ra\/article\/11\/39\/24381-24386\/743532"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021]]},"references-count":47,"journal-issue":{"issue":"39","published-print":{"date-parts":[[2021,7,12]]}},"URL":"https:\/\/doi.org\/10.1039\/d1ra04716g","relation":{},"ISSN":["2046-2069"],"issn-type":[{"value":"2046-2069","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021]]},"assertion":[{"value":"This document is Similarity Check deposited","name":"similarity_check","explanation":{"URL":"https:\/\/www.crossref.org\/services\/similarity-check\/"},"group":{"name":"similarity_check","label":"SIMILARITY CHECK"}},{"value":"Supplementary Information","URL":"https:\/\/doi.org\/10.1039\/D1RA04716G","name":"related_data","group":{"name":"related_data","label":"RELATED DATA"}},{"value":"Crystal Structure Data","URL":"http:\/\/xlink.rsc.org?ccdc=true&msid=D1RA04716G","name":"related_data"},{"value":"Kyle J. Colston (ORCID)","URL":"http:\/\/orcid.org\/0000-0002-8037-9326","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Partha Basu (ORCID)","URL":"http:\/\/orcid.org\/0000-0002-1232-418X","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Single-blind","order":2,"name":"peer_review_method","group":{"name":"peer_review_method","label":"PEER REVIEW METHOD"}},{"value":"Received 17 June 2021; Accepted 6 July 2021;  Version of Record published 12 July 2021","order":1,"name":"history","group":{"name":"publication_history","label":"PUBLICATION HISTORY"}}]}}