{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T22:03:59Z","timestamp":1787004239052,"version":"build-2736575974"},"reference-count":30,"publisher":"Royal Society of Chemistry (RSC)","issue":"32","license":[{"start":{"date-parts":[[2022,7,22]],"date-time":"2022-07-22T00:00:00Z","timestamp":1658448000000},"content-version":"vor","delay-in-days":202,"URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"funder":[{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"publisher","award":["1R35GM139613-01"],"award-info":[{"award-number":["1R35GM139613-01"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100008038","name":"Herman Frasch Foundation for Chemical Research","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100008038","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["OAC-1531128"],"award-info":[{"award-number":["OAC-1531128"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Sci."],"abstract":"<jats:p>In this work, visible light drives a contrathermodynamic isomerization of the classic Stork-Danheiser products through an energy transfer process to yield acyclic distal enone(al) isomers. This is possible because the photochemical energy is transiently captured as ring strain as a trans-, or twisted, cyclohexene.<\/jats:p>","DOI":"10.1039\/d1sc03774a","type":"journal-article","created":{"date-parts":[[2022,7,22]],"date-time":"2022-07-22T16:21:25Z","timestamp":1658506885000},"page":"9271-9276","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["A new twist for Stork-Danheiser products enabled by visible light mediated\n                    <i>trans<\/i>\n                    -cyclohexene formation; access to acyclic distal enones"],"prefix":"10.1039","volume":"13","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4613-2960","authenticated-orcid":false,"given":"Erik","family":"Lantz","sequence":"first","affiliation":[{"name":"107 Physical Science, Department of Chemistry, Oklahoma State University, Stillwater, Oklahoma 74078, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Roukaya","family":"El Mokadem","sequence":"additional","affiliation":[{"name":"Campus Box 3290, Chapel Hill, NC 27599-3290, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tim","family":"Schoch","sequence":"additional","affiliation":[{"name":"107 Physical Science, Department of Chemistry, Oklahoma State University, Stillwater, Oklahoma 74078, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tyler","family":"Fleske","sequence":"additional","affiliation":[{"name":"107 Physical Science, Department of Chemistry, Oklahoma State University, Stillwater, Oklahoma 74078, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4427-2799","authenticated-orcid":false,"given":"Jimmie D.","family":"Weaver","sequence":"additional","affiliation":[{"name":"107 Physical Science, Department of Chemistry, Oklahoma State University, Stillwater, Oklahoma 74078, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2022]]},"reference":[{"issue":"1","key":"D1SC03774A\/cit1\/1","doi-asserted-by":"crossref","first-page":"102","DOI":"10.1039\/B913880N","volume":"40","author":"Narayanam","year":"2011","journal-title":"Chem. Soc. Rev."},{"issue":"7","key":"D1SC03774A\/cit2\/1","doi-asserted-by":"crossref","first-page":"5322","DOI":"10.1021\/cr300503r","volume":"113","author":"Prier","year":"2013","journal-title":"Chem. Rev."},{"issue":"27","key":"D1SC03774A\/cit3\/1","doi-asserted-by":"crossref","first-page":"4985","DOI":"10.1039\/c0cc00981d","volume":"46","author":"Tucker","year":"2010","journal-title":"Chem. Commun."},{"issue":"7","key":"D1SC03774A\/cit4\/1","doi-asserted-by":"crossref","first-page":"983","DOI":"10.1039\/p29830000983","author":"Inoue","year":"1983","journal-title":"J. Chem. Soc., Perkin Trans. 2"},{"issue":"1","key":"D1SC03774A\/cit5\/1","doi-asserted-by":"crossref","first-page":"317","DOI":"10.1016\/1010-6030(91)85026-D","volume":"57","author":"Bunce","year":"1991","journal-title":"J. Photochem. Photobiol. A"},{"issue":"35","key":"D1SC03774A\/cit6\/1","doi-asserted-by":"crossref","first-page":"10763","DOI":"10.1021\/ja072090e","volume":"129","author":"Nikolai","year":"2007","journal-title":"J. Am. Chem. Soc."},{"issue":"2","key":"D1SC03774A\/cit7\/1","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1021\/ar50014a001","volume":"2","author":"Marshall","year":"1969","journal-title":"Acc. Chem. Res."},{"issue":"19","key":"D1SC03774A\/cit8\/1","doi-asserted-by":"crossref","first-page":"7190","DOI":"10.1039\/C8CS00054A","volume":"47","author":"Strieth-Kalthoff","year":"2018","journal-title":"Chem. Soc. Rev."},{"issue":"11","key":"D1SC03774A\/cit9\/1","doi-asserted-by":"crossref","first-page":"6796","DOI":"10.1039\/C6SC02422J","volume":"7","author":"Singh","year":"2016","journal-title":"Chem. Sci."},{"issue":"14","key":"D1SC03774A\/cit10\/1","doi-asserted-by":"crossref","first-page":"5275","DOI":"10.1021\/ja5019749","volume":"136","author":"Singh","year":"2014","journal-title":"J. Am. Chem. Soc."},{"issue":"2","key":"D1SC03774A\/cit11\/1","doi-asserted-by":"crossref","first-page":"2650","DOI":"10.1021\/acs.chemrev.1c00324","volume":"122","author":"Nevesel\u00fd","year":"2022","journal-title":"Chem. Rev."},{"issue":"1","key":"D1SC03774A\/cit12\/1","doi-asserted-by":"crossref","first-page":"124","DOI":"10.1016\/j.chempr.2017.11.007","volume":"4","author":"Singh","year":"2018","journal-title":"Chem"},{"issue":"31","key":"D1SC03774A\/cit13\/1","doi-asserted-by":"crossref","first-page":"9934","DOI":"10.1021\/jacs.8b04642","volume":"140","author":"Day","year":"2018","journal-title":"J. Am. Chem. Soc."},{"issue":"4","key":"D1SC03774A\/cit14\/1","doi-asserted-by":"crossref","first-page":"1074","DOI":"10.1021\/jo00109a047","volume":"60","author":"Johnson","year":"1995","journal-title":"J. Org. Chem."},{"issue":"19","key":"D1SC03774A\/cit15\/1","doi-asserted-by":"crossref","first-page":"6499","DOI":"10.1021\/ja0608085","volume":"128","author":"Kamijo","year":"2006","journal-title":"J. Am. Chem. Soc."},{"issue":"7","key":"D1SC03774A\/cit16\/1","doi-asserted-by":"crossref","first-page":"1854","DOI":"10.1039\/C8OB01273C","volume":"17","author":"Singh","year":"2019","journal-title":"Org. Biomol. Chem."},{"issue":"29","key":"D1SC03774A\/cit17\/1","doi-asserted-by":"crossref","first-page":"5330","DOI":"10.1002\/anie.200901220","volume":"48","author":"Wang","year":"2009","journal-title":"Angew. Chem., Int. Ed."},{"issue":"12","key":"D1SC03774A\/cit19\/1","doi-asserted-by":"crossref","first-page":"5050","DOI":"10.1021\/ja00065a014","volume":"115","author":"Cozens","year":"1993","journal-title":"J. Am. Chem. Soc."},{"issue":"33","key":"D1SC03774A\/cit20\/1","doi-asserted-by":"crossref","first-page":"11365","DOI":"10.1021\/jacs.7b07128","volume":"139","author":"Jin","year":"2017","journal-title":"J. Am. Chem. Soc."},{"issue":"14","key":"D1SC03774A\/cit21\/1","doi-asserted-by":"crossref","first-page":"4329","DOI":"10.1021\/ja00430a062","volume":"98","author":"Bonneau","year":"1976","journal-title":"J. Am. Chem. Soc."},{"issue":"7","key":"D1SC03774A\/cit22\/1","doi-asserted-by":"crossref","first-page":"1901","DOI":"10.1021\/ja00501a056","volume":"101","author":"Dauben","year":"1979","journal-title":"J. Am. Chem. Soc."},{"issue":"9","key":"D1SC03774A\/cit23\/1","doi-asserted-by":"crossref","first-page":"1775","DOI":"10.1021\/jo00949a048","volume":"38","author":"Stork","year":"1973","journal-title":"J. Org. Chem."},{"issue":"26","key":"D1SC03774A\/cit24\/1","doi-asserted-by":"crossref","first-page":"3519","DOI":"10.1016\/j.tetlet.2009.03.041","volume":"50","author":"Mehta","year":"2009","journal-title":"Tetrahedron Lett."},{"issue":"1","key":"D1SC03774A\/cit25\/1","doi-asserted-by":"crossref","first-page":"56","DOI":"10.1039\/C1OB06189E","volume":"10","author":"Bennett","year":"2012","journal-title":"Org. Biomol. Chem."},{"issue":"1","key":"D1SC03774A\/cit26\/1","doi-asserted-by":"crossref","first-page":"141","DOI":"10.1021\/jo00966a041","volume":"37","author":"Rosenberg","year":"1972","journal-title":"J. Org. Chem."},{"key":"D1SC03774A\/cit28\/1","volume-title":"Encyclopedia of Reagents for Organic Synthesis","author":"Hamilton","year":"2021","unstructured":"M.Hamilton ;  R.Walderbach  and  J.Weaver ,  Ir(dFppy)3 , in  Encyclopedia of Reagents for Organic Synthesis ,  2021"},{"key":"D1SC03774A\/cit29\/1","doi-asserted-by":"crossref","first-page":"51","DOI":"10.1016\/j.jorganchem.2014.10.037","volume":"776","author":"Singh","year":"2015","journal-title":"J. Organomet. Chem."},{"issue":"20","key":"D1SC03774A\/cit30\/1","doi-asserted-by":"crossref","first-page":"5199","DOI":"10.1021\/ja00996a021","volume":"89","author":"Kropp","year":"1967","journal-title":"J. Am. Chem. Soc."},{"issue":"5","key":"D1SC03774A\/cit31\/1","doi-asserted-by":"crossref","first-page":"836","DOI":"10.1063\/1.1699044","volume":"21","author":"Dexter","year":"1953","journal-title":"J. Chem. Phys."},{"key":"D1SC03774A\/cit33\/1","volume-title":"Gaussian 09, Revision C.01","author":"Frisch","year":"2009","unstructured":"M. J. T.Frisch ,  G. W.Trucks ,  H. B.Schlegel ,  G. E.Scuseria ,  M. A.Robb ,  J. R.Cheeseman ,  G.Scalmani ,  V.Barone ,  B.Mennucci ,  G. A.Petersson ,  H.Nakatsuji ,  M.Caricato ,  X.Li ,  H. P.Hratchian ,  A. F.Izmaylov ,  J.Bloino ,  G.Zheng ,  J. L.Sonnenberg ,  M.Hada ,  M.Ehara ,  K.Toyota ,  R.Fukuda ,  J.Hasegawa ,  M.Ishida ,  T.Nakajima ,  Y.Honda ,  O.Kitao ,  H.Nakai ,  T.Vreven ,  J. A.Montgomery Jr ,  J. E.Peralta ,  F.Ogliaro ,  M.Bearpark ,  J. J.Heyd ,  E.Brothers ;  K. N.Kudin ;  V. N.Staroverov ;  R.Kobayashi ;  J.Normand ;  K.Raghavachari ;  A.Rendell ,  J. C.Burant ,  S. S.Iyengar ,  J.Tomasi ,  M.Cossi ,  N.Rega ,  J. M.Millam ,  M.Klene ,  J. E.Knox ,  J. B.Cross ,  V.Bakken ,  C.Adamo ,  J.Jaramillo ,  R.Gomperts ,  R. E.Stratmann ,  O.Yazyev ,  A. J.Austin ,  R.Cammi ,  C.Pomelli ,  J. W.Ochterski ,  R. L.Martin ,  K.Morokuma ,  V. G.Zakrzewski ,  G. A.Voth ,  P.Salvador ,  J. J.Dannenberg ,  S.Dapprich ,  A. D.Daniels ,  \u00d6.Farkas ;  J. B.Foresman ,  J. V.Ortiz ,  J.Cioslowski  and  D. J.Fox ,  Gaussian 09, Revision C.01 ,  Gaussian, Inc ,  Wallingford, CT ,  2009"}],"container-title":["Chemical Science"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2022\/SC\/D1SC03774A","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2022\/SC\/D1SC03774A","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T18:36:35Z","timestamp":1783449395000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/sc\/article\/13\/32\/9271-9276\/746547"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022]]},"references-count":30,"journal-issue":{"issue":"32","published-print":{"date-parts":[[2022,8,17]]}},"URL":"https:\/\/doi.org\/10.1039\/d1sc03774a","relation":{},"ISSN":["2041-6520","2041-6539"],"issn-type":[{"value":"2041-6520","type":"print"},{"value":"2041-6539","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022]]}}}