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Commun."],"abstract":"<jats:p>\n                    The reaction of a phosphinine-Cr(CO)\n                    <jats:sub>3<\/jats:sub>\n                    -\u03c0-complex with [Rh(COD)\n                    <jats:sub>2<\/jats:sub>\n                    ]BF\n                    <jats:sub>4<\/jats:sub>\n                    leads to an unusual Rh\n                    <jats:sup>0<\/jats:sup>\n                    -dimer, that contains two phosphinine-\u03c0-complexes acting each as a bridging 2e\n                    <jats:sup>\u2212<\/jats:sup>\n                    ligand towards the Rh\n                    <jats:sub>2<\/jats:sub>\n                    (CO)\n                    <jats:sub>2<\/jats:sub>\n                    core. This compound represents a missing coordination mode of the aromatic phosphorus heterocycle.\n                  <\/jats:p>","DOI":"10.1039\/d2cc01817a","type":"journal-article","created":{"date-parts":[[2022,4,13]],"date-time":"2022-04-13T05:05:16Z","timestamp":1649826316000},"page":"6184-6187","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Highly flexible phosphabenzenes: a missing coordination mode of 2,4,6-triaryl-\u03bb\n                    <sup>3<\/sup>\n                    -phosphinines"],"prefix":"10.1039","volume":"58","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1161-1953","authenticated-orcid":false,"given":"Erlin","family":"Yue","sequence":"first","affiliation":[{"name":"Freie Universit\u00e4t Berlin, Institute of Chemistry and Biochemistry, Fabeckstr. 34\/36, 14195 Berlin, Germany"},{"name":"Shaanxi Key Laboratory of Chemical Reaction Engineering, Key Laboratory of New Energy & New Functional Materials, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrey","family":"Petrov","sequence":"additional","affiliation":[{"name":"Freie Universit\u00e4t Berlin, Institute of Chemistry and Biochemistry, Fabeckstr. 34\/36, 14195 Berlin, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6437-3995","authenticated-orcid":false,"given":"Daniel S.","family":"Frost","sequence":"additional","affiliation":[{"name":"Freie Universit\u00e4t Berlin, Institute of Chemistry and Biochemistry, Fabeckstr. 34\/36, 14195 Berlin, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4003-7292","authenticated-orcid":false,"given":"Lea","family":"Dettling","sequence":"additional","affiliation":[{"name":"Freie Universit\u00e4t Berlin, Institute of Chemistry and Biochemistry, Fabeckstr. 34\/36, 14195 Berlin, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lawrence","family":"Conrad","sequence":"additional","affiliation":[{"name":"Freie Universit\u00e4t Berlin, Institute of Chemistry and Biochemistry, Fabeckstr. 34\/36, 14195 Berlin, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Friedrich","family":"Wossidlo","sequence":"additional","affiliation":[{"name":"Freie Universit\u00e4t Berlin, Institute of Chemistry and Biochemistry, Fabeckstr. 34\/36, 14195 Berlin, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nathan T.","family":"Coles","sequence":"additional","affiliation":[{"name":"Freie Universit\u00e4t Berlin, Institute of Chemistry and Biochemistry, Fabeckstr. 34\/36, 14195 Berlin, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manuela","family":"Weber","sequence":"additional","affiliation":[{"name":"Freie Universit\u00e4t Berlin, Institute of Chemistry and Biochemistry, Fabeckstr. 34\/36, 14195 Berlin, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4700-0502","authenticated-orcid":false,"given":"Christian","family":"M\u00fcller","sequence":"additional","affiliation":[{"name":"Freie Universit\u00e4t Berlin, Institute of Chemistry and Biochemistry, Fabeckstr. 34\/36, 14195 Berlin, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2022]]},"reference":[{"key":"D2CC01817A\/cit1a\/1","doi-asserted-by":"crossref","first-page":"771","DOI":"10.1016\/S0010-8545(97)00080-5","volume":"178-180","author":"Le Floch","year":"1998","journal-title":"Coord. 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