{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T19:45:27Z","timestamp":1791402327318,"version":"4.3.3"},"reference-count":35,"publisher":"Royal Society of Chemistry (RSC)","issue":"78","license":[{"start":{"date-parts":[[2023,9,5]],"date-time":"2023-09-05T00:00:00Z","timestamp":1693872000000},"content-version":"am","delay-in-days":612,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21961016"],"award-info":[{"award-number":["21961016"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004479","name":"Natural Science Foundation of Jiangxi Province","doi-asserted-by":"publisher","award":["20202BAB203003"],"award-info":[{"award-number":["20202BAB203003"]}],"id":[{"id":"10.13039\/501100004479","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Commun."],"abstract":"<jats:p>\n                    A radical addition\/cyclization reaction of\n                    <jats:italic>o<\/jats:italic>\n                    -isocyanodiaryl amines has been developed for the efficient synthesis of potentially bioactive dibenzo[\n                    <jats:italic>b<\/jats:italic>\n                    ,\n                    <jats:italic>e<\/jats:italic>\n                    ][1,4]diazepine-11-carboxylates and dibenzo[\n                    <jats:italic>b<\/jats:italic>\n                    ,\n                    <jats:italic>e<\/jats:italic>\n                    ][1,4]diazepine-11-carboxamides.\n                  <\/jats:p>","DOI":"10.1039\/d2cc04348c","type":"journal-article","created":{"date-parts":[[2022,9,5]],"date-time":"2022-09-05T02:21:59Z","timestamp":1662344519000},"page":"10985-10988","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":21,"title":["Fe(acac)\n                    <sub>2<\/sub>\n                    \/TBHP-promoted synthesis of 11-functionalized dibenzodiazepines\n                    <i>via<\/i>\n                    alkoxycarbonylation and carboxamidation of\n                    <i>o<\/i>\n                    -isocyanodiaryl amines"],"prefix":"10.1039","volume":"58","author":[{"given":"Sitian","family":"Yuan","sequence":"first","affiliation":[{"name":"National Engineering Research Center for Carbohydrate Synthesis, Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, Key Laboratory for Green Chemistry of Jiangxi Province, Jiangxi Normal University, Nanchang, 330022, Jiangxi, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Liu","sequence":"additional","affiliation":[{"name":"National Engineering Research Center for Carbohydrate Synthesis, Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, Key Laboratory for Green Chemistry of Jiangxi Province, Jiangxi Normal University, Nanchang, 330022, Jiangxi, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengjia","family":"Ni","sequence":"additional","affiliation":[{"name":"National Engineering Research Center for Carbohydrate Synthesis, Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, Key Laboratory for Green Chemistry of Jiangxi Province, Jiangxi Normal University, Nanchang, 330022, Jiangxi, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tianxin","family":"Hao","sequence":"additional","affiliation":[{"name":"National Engineering Research Center for Carbohydrate Synthesis, Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, Key Laboratory for Green Chemistry of Jiangxi Province, Jiangxi Normal University, Nanchang, 330022, Jiangxi, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yiyuan","family":"Peng","sequence":"additional","affiliation":[{"name":"National Engineering Research Center for Carbohydrate Synthesis, Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, Key Laboratory for Green Chemistry of Jiangxi Province, Jiangxi Normal University, Nanchang, 330022, Jiangxi, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2162-5742","authenticated-orcid":false,"given":"Qiuping","family":"Ding","sequence":"additional","affiliation":[{"name":"National Engineering Research Center for Carbohydrate Synthesis, Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, Key Laboratory for Green Chemistry of Jiangxi Province, Jiangxi Normal University, Nanchang, 330022, Jiangxi, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2022]]},"reference":[{"key":"D2CC04348C\/cit1a\/1","doi-asserted-by":"crossref","first-page":"411","DOI":"10.1021\/ml1001163","volume":"1","author":"Binaschi","year":"2010","journal-title":"ACS Med. Chem. Lett."},{"key":"D2CC04348C\/cit1b\/1","doi-asserted-by":"crossref","first-page":"674","DOI":"10.1016\/j.ejmech.2015.12.007","volume":"108","author":"Kumar","year":"2016","journal-title":"Eur. J. Med. Chem."},{"key":"D2CC04348C\/cit2a\/1","doi-asserted-by":"crossref","first-page":"746","DOI":"10.1056\/NEJM199103143241107","volume":"324","author":"Baldessarini","year":"1991","journal-title":"N. Engl. J. Med."},{"key":"D2CC04348C\/cit2b\/1","doi-asserted-by":"crossref","first-page":"41","DOI":"10.1192\/S0007125000296918","volume":"160","author":"Kane","year":"1992","journal-title":"Br. J. Psychiatry"},{"key":"D2CC04348C\/cit3\/1","doi-asserted-by":"crossref","first-page":"977","DOI":"10.1124\/jpet.107.132456","volume":"324","author":"Zahradn\u00edk","year":"2008","journal-title":"J. Pharmacol. Exp. Ther."},{"key":"D2CC04348C\/cit4\/1","doi-asserted-by":"crossref","first-page":"1508","DOI":"10.1021\/jm00036a017","volume":"37","author":"Eyrolles","year":"1994","journal-title":"J. Med. Chem."},{"key":"D2CC04348C\/cit5a\/1","doi-asserted-by":"crossref","first-page":"1541","DOI":"10.1021\/ol050181f","volume":"7","author":"Yang","year":"2005","journal-title":"Org. Lett."},{"key":"D2CC04348C\/cit5b\/1","doi-asserted-by":"crossref","first-page":"4512","DOI":"10.1021\/jm051008s","volume":"49","author":"Smits","year":"2006","journal-title":"J. Med. Chem."},{"key":"D2CC04348C\/cit5c\/1","doi-asserted-by":"crossref","first-page":"4066","DOI":"10.1016\/j.bmcl.2007.04.069","volume":"17","author":"Joshua","year":"2007","journal-title":"Bioorg. Med. Chem. Lett."},{"key":"D2CC04348C\/cit5d\/1","first-page":"1137","volume":"12","author":"Jiang","year":"2008","journal-title":"Res. Dev."},{"key":"D2CC04348C\/cit6a\/1","doi-asserted-by":"crossref","first-page":"6895","DOI":"10.1039\/C4OB00871E","volume":"12","author":"Fang","year":"2014","journal-title":"Org. Biomol. Chem."},{"key":"D2CC04348C\/cit6b\/1","first-page":"448","author":"Yang","year":"2008","journal-title":"Synlett"},{"key":"D2CC04348C\/cit7a\/1","doi-asserted-by":"crossref","first-page":"10015","DOI":"10.1002\/slct.202002523","volume":"5","author":"Nunewar","year":"2020","journal-title":"ChemistrySelect"},{"key":"D2CC04348C\/cit7b\/1","doi-asserted-by":"crossref","first-page":"67","DOI":"10.3998\/ark.5550190.p009.512","volume":"2016","author":"\u0141ukasik","year":"2016","journal-title":"Arkivoc"},{"key":"D2CC04348C\/cit7c\/1","doi-asserted-by":"crossref","first-page":"743","DOI":"10.1016\/j.cclet.2013.04.028","volume":"24","author":"Wang","year":"2013","journal-title":"Chin. Chem. Lett."},{"key":"D2CC04348C\/cit7d\/1","doi-asserted-by":"crossref","first-page":"14228","DOI":"10.1021\/ja206229y","volume":"133","author":"Tsvelikhovsky","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"D2CC04348C\/cit8\/1","doi-asserted-by":"crossref","first-page":"6524","DOI":"10.1021\/acs.joc.9b00683","volume":"84","author":"Hu","year":"2019","journal-title":"J. Org. Chem."},{"key":"D2CC04348C\/cit9a\/1","doi-asserted-by":"crossref","first-page":"964","DOI":"10.1021\/jacs.0c11138","volume":"143","author":"Liu","year":"2021","journal-title":"J. Am. Chem. Soc."},{"key":"D2CC04348C\/cit9b\/1","doi-asserted-by":"crossref","first-page":"2240","DOI":"10.1039\/C7CC09302K","volume":"54","author":"L\u00fcbbesmeyer","year":"2018","journal-title":"Chem. Commun."},{"key":"D2CC04348C\/cit9c\/1","doi-asserted-by":"crossref","first-page":"1103","DOI":"10.1039\/C6CS00384B","volume":"46","author":"Song","year":"2017","journal-title":"Chem. Soc. Rev."},{"key":"D2CC04348C\/cit9d\/1","doi-asserted-by":"crossref","first-page":"2743","DOI":"10.1002\/anie.201510533","volume":"55","author":"Rong","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2CC04348C\/cit9e\/1","doi-asserted-by":"crossref","first-page":"3505","DOI":"10.1039\/C5CS00083A","volume":"44","author":"Zhang","year":"2015","journal-title":"Chem. Soc. Rev."},{"key":"D2CC04348C\/cit11a\/1","doi-asserted-by":"crossref","first-page":"471","DOI":"10.1038\/nature10702","volume":"480","author":"Pattabiraman","year":"2011","journal-title":"Nature"},{"key":"D2CC04348C\/cit11b\/1","doi-asserted-by":"crossref","first-page":"3405","DOI":"10.1039\/c0cs00196a","volume":"40","author":"Allen","year":"2011","journal-title":"Chem. Soc. Rev."},{"key":"D2CC04348C\/cit11c\/1","doi-asserted-by":"crossref","first-page":"606","DOI":"10.1039\/B701677H","volume":"38","author":"Valeur","year":"2009","journal-title":"Chem. Soc. Rev."},{"key":"D2CC04348C\/cit12a\/1","doi-asserted-by":"crossref","first-page":"17316","DOI":"10.1021\/jacs.8b11827","volume":"140","author":"Trost","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"D2CC04348C\/cit12b\/1","doi-asserted-by":"crossref","first-page":"10776","DOI":"10.1021\/ja403615c","volume":"135","author":"Jagadeesh","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"D2CC04348C\/cit12c\/1","doi-asserted-by":"crossref","first-page":"1140","DOI":"10.1126\/science.290.5494.1140","volume":"290","author":"Ishihara","year":"2000","journal-title":"Science"},{"key":"D2CC04348C\/cit13a\/1","doi-asserted-by":"crossref","first-page":"9067","DOI":"10.1021\/acs.joc.1c01031","volume":"86","author":"Wang","year":"2021","journal-title":"J. Org. Chem."},{"key":"D2CC04348C\/cit13b\/1","first-page":"462","volume":"62","author":"Xe","year":"2019","journal-title":"Sci. China: Chem."},{"key":"D2CC04348C\/cit13c\/1","doi-asserted-by":"crossref","first-page":"5374","DOI":"10.1021\/jo500842e","volume":"79","author":"Pan","year":"2014","journal-title":"J. Org. Chem."},{"key":"D2CC04348C\/cit14a\/1","doi-asserted-by":"crossref","first-page":"8128","DOI":"10.1021\/acscatal.9b02635","volume":"9","author":"Shen","year":"2019","journal-title":"ACS Catal."},{"key":"D2CC04348C\/cit14b\/1","doi-asserted-by":"crossref","first-page":"12830","DOI":"10.1039\/C7CC08074C","volume":"53","author":"Cheng","year":"2017","journal-title":"Chem. Commun."},{"key":"D2CC04348C\/cit14c\/1","doi-asserted-by":"crossref","first-page":"364","DOI":"10.1039\/C2CC37643A","volume":"49","author":"Li","year":"2013","journal-title":"Chem. Commun."},{"key":"D2CC04348C\/cit15\/1","doi-asserted-by":"crossref","first-page":"12143","DOI":"10.1016\/0040-4020(95)00769-5","volume":"51","author":"Leardini","year":"1995","journal-title":"Tetrahedron"}],"container-title":["Chemical Communications"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2022\/CC\/D2CC04348C","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T21:35:20Z","timestamp":1782941720000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/cc\/article\/58\/78\/10985-10988\/758267"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022]]},"references-count":35,"journal-issue":{"issue":"78","published-print":{"date-parts":[[2022,9,29]]}},"URL":"https:\/\/doi.org\/10.1039\/d2cc04348c","relation":{},"ISSN":["1359-7345","1364-548X"],"issn-type":[{"value":"1359-7345","type":"print"},{"value":"1364-548X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022]]}}}