{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T19:55:18Z","timestamp":1782935718682,"version":"3.54.5"},"reference-count":32,"publisher":"Royal Society of Chemistry (RSC)","issue":"93","license":[{"start":{"date-parts":[[2022,11,1]],"date-time":"2022-11-01T00:00:00Z","timestamp":1667260800000},"content-version":"vor","delay-in-days":304,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100001348","name":"Agency for Science, Technology and Research","doi-asserted-by":"publisher","award":["No. M21K2c0111"],"award-info":[{"award-number":["No. M21K2c0111"]}],"id":[{"id":"10.13039\/501100001348","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100018839","name":"Irish Centre for High-End Computing","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100018839","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Commun."],"abstract":"<jats:p>\n                    We isolate and characterize the gold(\n                    <jats:sc>i<\/jats:sc>\n                    )\u2013iron(0) adducts [(\n                    <jats:sup>i<\/jats:sup>\n                    Pr\n                    <jats:sub>2<\/jats:sub>\n                    -bimy)Au\u2013Fe(CO)\n                    <jats:sub>3<\/jats:sub>\n                    (PMe\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ][BAr\n                    <jats:sup>F<\/jats:sup>\n                    <jats:sub>4<\/jats:sub>\n                    ] and [Au\u2013{Fe(CO)\n                    <jats:sub>3<\/jats:sub>\n                    (PMe\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    }\n                    <jats:sub>2<\/jats:sub>\n                    ][BAr\n                    <jats:sup>F<\/jats:sup>\n                    <jats:sub>4<\/jats:sub>\n                    ] (\n                    <jats:sup>i<\/jats:sup>\n                    Pr\n                    <jats:sub>2<\/jats:sub>\n                    -bimy = 1,3-diisopropylbenzimidazolin-2-ylidene, BAr\n                    <jats:sup>F<\/jats:sup>\n                    <jats:sub>4<\/jats:sub>\n                    = tetrakis(pentafluorophenyl)borate).\n                  <\/jats:p>","DOI":"10.1039\/d2cc05041b","type":"journal-article","created":{"date-parts":[[2022,11,1]],"date-time":"2022-11-01T08:01:57Z","timestamp":1667289717000},"page":"12947-12950","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Gauging the donor strength of iron(0) complexes\n                    <i>via<\/i>\n                    their N-heterocyclic carbene gold(\n                    <scp>i<\/scp>\n                    ) adducts"],"prefix":"10.1039","volume":"58","author":[{"given":"Zhi Hao","family":"Toh","sequence":"first","affiliation":[{"name":"Department of Chemistry, National University of Singapore, 3 Science Drive 3, 117543, Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hendrik","family":"Tinnermann","sequence":"additional","affiliation":[{"name":"Department of Chemistry, National University of Singapore, 3 Science Drive 3, 117543, Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5882-8896","authenticated-orcid":false,"given":"Dinh Cao Huan","family":"Do","sequence":"additional","affiliation":[{"name":"Department of Chemistry, National University of Singapore, 3 Science Drive 3, 117543, Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4460-6066","authenticated-orcid":false,"given":"Han Vinh","family":"Huynh","sequence":"additional","affiliation":[{"name":"Department of Chemistry, National University of Singapore, 3 Science Drive 3, 117543, Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5842-9553","authenticated-orcid":false,"given":"Tobias","family":"Kr\u00e4mer","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Maynooth University, Maynooth, Co. Kildare, Ireland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7437-8944","authenticated-orcid":false,"given":"Rowan D.","family":"Young","sequence":"additional","affiliation":[{"name":"Department of Chemistry, National University of Singapore, 3 Science Drive 3, 117543, Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2022]]},"reference":[{"key":"D2CC05041B\/cit1a\/1","doi-asserted-by":"crossref","first-page":"4329","DOI":"10.1021\/cr3000048","volume":"112","author":"Bauer","year":"2012","journal-title":"Chem. Rev."},{"key":"D2CC05041B\/cit1b\/1","doi-asserted-by":"crossref","first-page":"319","DOI":"10.1007\/978-3-030-58888-5_9","volume-title":"Frustrated Lewis Pairs","author":"Hidalgo","year":"2021","unstructured":"N.Hidalgo , M. G.Alf\u00e9rez and J.Campos , Frustrated Lewis Pairs Based on Transition Metals , in Frustrated Lewis Pairs , ed. C. J. Slootweg and A. R. Jupp , Springer : Cham , 2021 , vol. 2, pp. 319\u2013359"},{"key":"D2CC05041B\/cit2a\/1","doi-asserted-by":"crossref","first-page":"49","DOI":"10.1002\/9783527699087.ch3","volume-title":"Non-noble metal catalysis molecular approaches and reactions","author":"Mankad","year":"2019","unstructured":"N. P.Mankad , Catalysis with multinuclear complexes , in Non-noble metal catalysis molecular approaches and reactions , ed. R. J. M. Klein Gebbink and M.-E. Moret , Wiley-VCH , Weinheim, Germany , 2019 , pp. 49\u201368"},{"key":"D2CC05041B\/cit2b\/1","doi-asserted-by":"crossref","first-page":"936","DOI":"10.1021\/acscatal.6b02692","volume":"7","author":"Powers","year":"2017","journal-title":"ACS Catal."},{"key":"D2CC05041B\/cit2c\/1","doi-asserted-by":"crossref","first-page":"8524","DOI":"10.1039\/D0CC02542A","volume":"56","author":"Xu","year":"2020","journal-title":"Chem. 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