{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T05:56:30Z","timestamp":1782885390735,"version":"3.54.5"},"reference-count":48,"publisher":"Royal Society of Chemistry (RSC)","issue":"45","license":[{"start":{"date-parts":[[2023,10,12]],"date-time":"2023-10-12T00:00:00Z","timestamp":1697068800000},"content-version":"am","delay-in-days":649,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100004794","name":"Centre National de la Recherche Scientifique","doi-asserted-by":"publisher","award":["PCMI"],"award-info":[{"award-number":["PCMI"]}],"id":[{"id":"10.13039\/501100004794","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002830","name":"Centre National d\u2019Etudes Spatiales","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100002830","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100017584","name":"SRM Institute of Science and Technology","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100017584","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001843","name":"Science and Engineering Research Board","doi-asserted-by":"publisher","award":["ECR\/2017\/000891"],"award-info":[{"award-number":["ECR\/2017\/000891"]}],"id":[{"id":"10.13039\/501100001843","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Phys. Chem. Chem. Phys."],"abstract":"<jats:p>\n                    We use advanced theoretical treatments and energetic ion collision induced fragmentation to investigate the unimolecular decomposition dynamics of CH\n                    <jats:sub>3<\/jats:sub>\n                    Cl\n                    <jats:sup>\n                      <jats:italic>q<\/jats:italic>\n                      +\n                    <\/jats:sup>\n                    (\n                    <jats:italic>q<\/jats:italic>\n                    = 2,3) ions, where both obvious bond breaking and bond rearrangement products are observed.\n                  <\/jats:p>","DOI":"10.1039\/d2cp02194c","type":"journal-article","created":{"date-parts":[[2022,10,12]],"date-time":"2022-10-12T11:08:37Z","timestamp":1665572917000},"page":"27619-27630","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Fragmentation dynamics of CH\n                    <sub>3<\/sub>\n                    Cl\n                    <sup>\n                      <i>q<\/i>\n                      +\n                    <\/sup>\n                    (\n                    <i>q<\/i>\n                    = 2,3): theory and experiment"],"prefix":"10.1039","volume":"24","author":[{"given":"Pragya","family":"Bhatt","sequence":"first","affiliation":[{"name":"Inter University Accelerator Centre, Aruna Asaf Ali Marg, New Delhi \u2013 110067, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9704-9139","authenticated-orcid":false,"given":"K. R.","family":"Maiyelvaganan","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Faculty of Engineering and Technology, SRM Institute of Science and Technology, SRM Nagar, Kattankulathur-603203, Chennai, TN, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1886-7708","authenticated-orcid":false,"given":"M.","family":"Prakash","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Faculty of Engineering and Technology, SRM Institute of Science and Technology, SRM Nagar, Kattankulathur-603203, Chennai, TN, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"J.","family":"Palaudoux","sequence":"additional","affiliation":[{"name":"Sorbonne Universit\u00e9, CNRS, Laboratoire de Chimie Physique \u2013 Mati\u00e8re et Rayonnement, LCP-MR, F-75005, Paris, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8429-8956","authenticated-orcid":false,"given":"C. P.","family":"Safvan","sequence":"additional","affiliation":[{"name":"Inter University Accelerator Centre, Aruna Asaf Ali Marg, New Delhi \u2013 110067, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4737-7978","authenticated-orcid":false,"given":"M.","family":"Hochlaf","sequence":"additional","affiliation":[{"name":"Universit\u00e9 Gustave Eiffel, COSYS\/IMSE, 5 Bd Descartes 77454, Champs sur Marne, France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2022]]},"reference":[{"key":"D2CP02194C\/cit1\/1","doi-asserted-by":"crossref","first-page":"471","DOI":"10.1016\/0020-7381(69)80044-6","volume":"2","author":"Eland","year":"1969","journal-title":"Int. J. Mass Spectrom. Ion Phys."},{"key":"D2CP02194C\/cit2\/1","doi-asserted-by":"crossref","first-page":"175","DOI":"10.1016\/0168-1176(90)85058-A","volume":"97","author":"Ruhl","year":"1990","journal-title":"Int. J. 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