{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T08:13:51Z","timestamp":1782893631748,"version":"3.54.5"},"reference-count":92,"publisher":"Royal Society of Chemistry (RSC)","issue":"37","license":[{"start":{"date-parts":[[2023,9,8]],"date-time":"2023-09-08T00:00:00Z","timestamp":1694131200000},"content-version":"am","delay-in-days":615,"URL":"http:\/\/rsc.li\/journals-terms-of-use#chorus"}],"funder":[{"DOI":"10.13039\/100000015","name":"U.S. Department of Energy","doi-asserted-by":"publisher","award":["DE-FG02-03ER15411"],"award-info":[{"award-number":["DE-FG02-03ER15411"]}],"id":[{"id":"10.13039\/100000015","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000015","name":"U.S. Department of Energy","doi-asserted-by":"publisher","award":["DE-FG02-04ER15570"],"award-info":[{"award-number":["DE-FG02-04ER15570"]}],"id":[{"id":"10.13039\/100000015","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Phys. Chem. Chem. Phys."],"abstract":"<jats:p>\n                    The reaction of C(\n                    <jats:sup>3<\/jats:sup>\n                    P\n                    <jats:sub>j<\/jats:sub>\n                    ) with cyclopropane leads to C\n                    <jats:sub>\n                      <jats:sub>4<\/jats:sub>\n                    <\/jats:sub>\n                    H\n                    <jats:sub>\n                      <jats:sub>5<\/jats:sub>\n                    <\/jats:sub>\n                    products 1-butyn-4-yl, 1,3-butadien-2-yl (i-C\n                    <jats:sub>\n                      <jats:sub>4<\/jats:sub>\n                    <\/jats:sub>\n                    H\n                    <jats:sub>\n                      <jats:sub>5<\/jats:sub>\n                    <\/jats:sub>\n                    ), and 1,3-butadien-1-yl (n-C\n                    <jats:sub>\n                      <jats:sub>4<\/jats:sub>\n                    <\/jats:sub>\n                    H\n                    <jats:sub>\n                      <jats:sub>5<\/jats:sub>\n                    <\/jats:sub>\n                    ) plus atomic hydrogen. The results highlight an unusual reactivity of cyclopropane's banana C\u2013C bonds showing a similarity with unsaturated C\u2013C bonds.\n                  <\/jats:p>","DOI":"10.1039\/d2cp03293g","type":"journal-article","created":{"date-parts":[[2022,9,8]],"date-time":"2022-09-08T10:41:02Z","timestamp":1662633662000},"page":"22453-22463","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["A crossed molecular beams and computational study on the unusual reactivity of banana bonds of cyclopropane (c-C\n                    <sub>3<\/sub>\n                    H\n                    <sub>6<\/sub>\n                    ; ) through insertion by ground state carbon atoms (C(\n                    <sup>3<\/sup>\n                    P\n                    <sub>\n                      <i>j<\/i>\n                    <\/sub>\n                    ))"],"prefix":"10.1039","volume":"24","author":[{"given":"Galiya R.","family":"Galimova","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biochemistry, Florida International University, Miami, FL 33199, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7233-3133","authenticated-orcid":false,"given":"Alexander M.","family":"Mebel","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry, Florida International University, Miami, FL 33199, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1796-5725","authenticated-orcid":false,"given":"Shane J.","family":"Goettl","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Hawai\u2019i at M\u0101noa, Honolulu, HI 96822, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenghai","family":"Yang","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Hawai\u2019i at M\u0101noa, Honolulu, HI 96822, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7233-7206","authenticated-orcid":false,"given":"Ralf I.","family":"Kaiser","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Hawai\u2019i at M\u0101noa, Honolulu, HI 96822, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2022]]},"reference":[{"key":"D2CP03293G\/cit1\/1","doi-asserted-by":"crossref","first-page":"565","DOI":"10.1016\/S0360-1285(00)00009-5","volume":"26","author":"Richter","year":"2000","journal-title":"Prog. 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