{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T04:46:43Z","timestamp":1782881203949,"version":"3.54.5"},"reference-count":52,"publisher":"Royal Society of Chemistry (RSC)","issue":"12","license":[{"start":{"date-parts":[[2023,2,18]],"date-time":"2023-02-18T00:00:00Z","timestamp":1676678400000},"content-version":"am","delay-in-days":413,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100001852","name":"Indo-French Centre for the Promotion of Advanced Research","doi-asserted-by":"publisher","award":["5905-1"],"award-info":[{"award-number":["5905-1"]}],"id":[{"id":"10.13039\/501100001852","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<jats:p>\n                    The chemistry of Cp* based groups 5, 6 and 8 metal complexes containing a \u03ba\n                    <jats:sup>2<\/jats:sup>\n                    -\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>S<\/jats:italic>\n                    -chelated ligand has been examined with free and bulky boranes that exhibit diverse reactivity patterns.\n                  <\/jats:p>","DOI":"10.1039\/d2dt00242f","type":"journal-article","created":{"date-parts":[[2022,2,18]],"date-time":"2022-02-18T02:01:33Z","timestamp":1645149693000},"page":"4806-4813","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Cooperative B\u2013H activation by Cp* based \u03ba\n                    <sup>2<\/sup>\n                    -\n                    <i>N<\/i>\n                    ,\n                    <i>S<\/i>\n                    -chelated Ru(\n                    <scp>ii<\/scp>\n                    ) and Mo(\n                    <scp>ii<\/scp>\n                    ) complexes (Cp* = \u03b7\n                    <sup>5<\/sup>\n                    -C\n                    <sub>5<\/sub>\n                    Me\n                    <sub>5<\/sub>\n                    )"],"prefix":"10.1039","volume":"51","author":[{"given":"Suvam","family":"Saha","sequence":"first","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anagha","family":"Haridas","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Faneesha","family":"Assanar","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Charu","family":"Bansal","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"P. K.","family":"Sudhadevi Antharjanam","sequence":"additional","affiliation":[{"name":"SAIF, Indian Institute of Technology Madras, Chennai 600036, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6089-8244","authenticated-orcid":false,"given":"Sundargopal","family":"Ghosh","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2022]]},"reference":[{"key":"D2DT00242F\/cit1a\/1","doi-asserted-by":"crossref","first-page":"1696","DOI":"10.1021\/ja9516773","volume":"118","author":"He","year":"1996","journal-title":"J. Am. Chem. Soc."},{"key":"D2DT00242F\/cit1b\/1","doi-asserted-by":"crossref","first-page":"2759","DOI":"10.1002\/(SICI)1521-3773(19990917)38:18<2759::AID-ANIE2759>3.0.CO;2-P","volume":"38","author":"Hill","year":"1999","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2DT00242F\/cit1c\/1","doi-asserted-by":"crossref","first-page":"730","DOI":"10.1002\/anie.201410781","volume":"54","author":"Devillard","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2DT00242F\/cit1d\/1","doi-asserted-by":"crossref","first-page":"16899","DOI":"10.1002\/chem.201404846","volume":"20","author":"Cowie","year":"2014","journal-title":"Chem. \u2013 Eur. J."},{"key":"D2DT00242F\/cit1e\/1","doi-asserted-by":"crossref","first-page":"1260","DOI":"10.1021\/acs.accounts.0c00819","volume":"54","author":"Saha","year":"2021","journal-title":"Acc. Chem. Res."},{"key":"D2DT00242F\/cit1f\/1","doi-asserted-by":"crossref","first-page":"13238","DOI":"10.1021\/acs.chemrev.1c00255","volume":"121","author":"Bose","year":"2021","journal-title":"Chem. Rev."},{"key":"D2DT00242F\/cit1g\/1","doi-asserted-by":"crossref","first-page":"5587","DOI":"10.1021\/ja069044j","volume":"129","author":"Nagaraja","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"D2DT00242F\/cit2a\/1","doi-asserted-by":"crossref","first-page":"7569","DOI":"10.1002\/anie.201404753","volume":"53","author":"Cassen","year":"2014","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2DT00242F\/cit2b\/1","doi-asserted-by":"crossref","first-page":"921","DOI":"10.1002\/anie.200906171","volume":"49","author":"Tang","year":"2010","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2DT00242F\/cit2c\/1","doi-asserted-by":"crossref","first-page":"2538","DOI":"10.1039\/b822678d","author":"Tsoureas","year":"2009","journal-title":"Chem. Commun."},{"key":"D2DT00242F\/cit3a\/1","doi-asserted-by":"crossref","first-page":"11704","DOI":"10.1021\/ja990828p","volume":"121","author":"Shimoi","year":"1999","journal-title":"J. Am. Chem. Soc."},{"key":"D2DT00242F\/cit3b\/1","doi-asserted-by":"crossref","first-page":"581","DOI":"10.1002\/anie.200905185","volume":"49","author":"Chaplin","year":"2010","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2DT00242F\/cit4a\/1","doi-asserted-by":"crossref","first-page":"12236","DOI":"10.1002\/anie.201503873","volume":"54","author":"Khusnutdinova","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2DT00242F\/cit4b\/1","doi-asserted-by":"crossref","first-page":"1258","DOI":"10.1021\/acs.accounts.7b00089","volume":"50","author":"Omann","year":"2017","journal-title":"Acc. Chem. Res."},{"key":"D2DT00242F\/cit4c\/1","doi-asserted-by":"crossref","first-page":"3536","DOI":"10.1039\/C9CC00296K","volume":"55","author":"Swamy","year":"2019","journal-title":"Chem. Commun."},{"key":"D2DT00242F\/cit5a\/1","doi-asserted-by":"crossref","first-page":"12808","DOI":"10.1021\/jacs.5b08406","volume":"137","author":"Geri","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"D2DT00242F\/cit5b\/1","doi-asserted-by":"crossref","first-page":"3181","DOI":"10.1002\/anie.201511448","volume":"55","author":"Drover","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2DT00242F\/cit5c\/1","doi-asserted-by":"crossref","first-page":"13709","DOI":"10.1021\/acs.inorgchem.7b01369","volume":"56","author":"Ito","year":"2017","journal-title":"Inorg. Chem."},{"key":"D2DT00242F\/cit5d\/1","doi-asserted-by":"crossref","first-page":"14131","DOI":"10.1002\/anie.201306629","volume":"52","author":"Srimani","year":"2013","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2DT00242F\/cit6\/1","doi-asserted-by":"crossref","first-page":"4756","DOI":"10.1039\/b903420j","author":"Rankin","year":"2009","journal-title":"Dalton Trans."},{"key":"D2DT00242F\/cit7\/1","doi-asserted-by":"crossref","first-page":"10978","DOI":"10.1021\/ja405925w","volume":"135","author":"Stahl","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"D2DT00242F\/cit8\/1","doi-asserted-by":"crossref","first-page":"380","DOI":"10.1021\/acscatal.9b04455","volume":"10","author":"Hou","year":"2020","journal-title":"ACS Catal."},{"key":"D2DT00242F\/cit9\/1","doi-asserted-by":"crossref","first-page":"3439","DOI":"10.1002\/chem.201800248","volume":"24","author":"Scharf","year":"2018","journal-title":"Chem. \u2013 Eur. J."},{"key":"D2DT00242F\/cit10a\/1","doi-asserted-by":"crossref","first-page":"13537","DOI":"10.1002\/chem.201902663","volume":"25","author":"Zafar","year":"2019","journal-title":"Chem. \u2013 Eur. J."},{"key":"D2DT00242F\/cit10b\/1","doi-asserted-by":"crossref","first-page":"1183","DOI":"10.1021\/acs.inorgchem.0c03306","volume":"60","author":"Zafar","year":"2021","journal-title":"Inorg. Chem."},{"key":"D2DT00242F\/cit13\/1","doi-asserted-by":"crossref","first-page":"16317","DOI":"10.1039\/C6DT02641A","volume":"45","author":"Ramalakshmi","year":"2016","journal-title":"Dalton Trans."},{"key":"D2DT00242F\/cit15\/1","doi-asserted-by":"crossref","first-page":"2873","DOI":"10.1002\/anie.201310416","volume":"53","author":"Anju","year":"2014","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2DT00242F\/cit16\/1","doi-asserted-by":"crossref","first-page":"12878","DOI":"10.1021\/ja805164n","volume":"130","author":"Alcaraz","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"D2DT00242F\/cit17a\/1","doi-asserted-by":"crossref","first-page":"8704","DOI":"10.1021\/ja0733538","volume":"129","author":"Alcaraz","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"D2DT00242F\/cit17b\/1","doi-asserted-by":"crossref","first-page":"2431","DOI":"10.1021\/ic1022328","volume":"50","author":"Hesp","year":"2011","journal-title":"Inorg. Chem."},{"key":"D2DT00242F\/cit17c\/1","doi-asserted-by":"crossref","first-page":"7471","DOI":"10.1021\/ic801300m","volume":"47","author":"Hesp","year":"2008","journal-title":"Inorg. Chem."},{"key":"D2DT00242F\/cit17d\/1","doi-asserted-by":"crossref","first-page":"2964","DOI":"10.1002\/anie.200806178","volume":"48","author":"Gloaguen","year":"2009","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2DT00242F\/cit19\/1","doi-asserted-by":"crossref","first-page":"17191","DOI":"10.1002\/chem.201503404","volume":"21","author":"Ramalakshmi","year":"2015","journal-title":"Chem. \u2013 Eur. J."},{"key":"D2DT00242F\/cit20\/1","doi-asserted-by":"crossref","first-page":"4036","DOI":"10.1039\/D0DT04362A","volume":"50","author":"Prakash","year":"2021","journal-title":"Dalton Trans."},{"key":"D2DT00242F\/cit21\/1","doi-asserted-by":"crossref","first-page":"5166","DOI":"10.1021\/ja00169a026","volume":"112","author":"Chinn","year":"1990","journal-title":"J. Am. Chem. Soc."},{"key":"D2DT00242F\/cit22\/1","doi-asserted-by":"crossref","first-page":"353","DOI":"10.1016\/0022-328X(88)87028-1","volume":"349","author":"Asdar","year":"1988","journal-title":"J. Organomet. Chem."},{"key":"D2DT00242F\/cit23\/1","doi-asserted-by":"crossref","first-page":"340","DOI":"10.1016\/S0020-1693(02)01276-8","volume":"345","author":"Tonzetich","year":"2003","journal-title":"Inorg. Chim. Acta"},{"key":"D2DT00242F\/cit24a\/1","doi-asserted-by":"crossref","first-page":"851","DOI":"10.1002\/anie.199408511","volume":"33","author":"Smith","year":"1994","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"D2DT00242F\/cit24b\/1","doi-asserted-by":"crossref","first-page":"12323","DOI":"10.1039\/D0CC05503D","volume":"56","author":"MacNeil","year":"2020","journal-title":"Chem. Commun."},{"key":"D2DT00242F\/cit25\/1","first-page":"113","volume":"15","author":"Ryschkewitsch","year":"1974","journal-title":"Inorg. Synth."},{"key":"D2DT00242F\/cit26a\/1","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Crystallogr., Sect. A: Found. Adv."},{"key":"D2DT00242F\/cit27\/1","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Crystallogr., Sect. C: Struct. Chem."},{"key":"D2DT00242F\/cit28\/1","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Crystallogr."},{"key":"D2DT00242F\/cit29a\/1","doi-asserted-by":"crossref","first-page":"9624","DOI":"10.1063\/1.476438","volume":"108","author":"Schmider","year":"1998","journal-title":"J. Chem. Phys."},{"key":"D2DT00242F\/cit29b\/1","doi-asserted-by":"crossref","first-page":"8822","DOI":"10.1103\/PhysRevB.33.8822","volume":"33","author":"Perdew","year":"1986","journal-title":"Phys. Rev. B: Condens. Matter Mater. Phys."},{"key":"D2DT00242F\/cit31\/1","unstructured":"Basis Set Exchange Library,  https:\/\/www.basissetexchange.org\/"},{"key":"D2DT00242F\/cit32a\/1","doi-asserted-by":"crossref","first-page":"397","DOI":"10.1051\/jphysrad:01937008010039700","volume":"8","author":"London","year":"1937","journal-title":"J. Phys. Radium"},{"key":"D2DT00242F\/cit32b\/1","doi-asserted-by":"crossref","first-page":"789","DOI":"10.1080\/00268977400100711","volume":"27","author":"Ditchfield","year":"1974","journal-title":"Mol. Phys."},{"key":"D2DT00242F\/cit32c\/1","doi-asserted-by":"crossref","first-page":"8251","DOI":"10.1021\/ja00179a005","volume":"112","author":"Wolinski","year":"1990","journal-title":"J. Am. Chem. Soc."},{"key":"D2DT00242F\/cit33\/1","doi-asserted-by":"crossref","first-page":"1533","DOI":"10.1021\/j150579a601","volume":"63","author":"Onak","year":"1959","journal-title":"J. Phys. Chem."},{"key":"D2DT00242F\/cit35\/1","doi-asserted-by":"crossref","first-page":"1083","DOI":"10.1016\/0040-4020(68)88057-3","volume":"24","author":"Wiberg","year":"1968","journal-title":"Tetrahedron"},{"key":"D2DT00242F\/cit36\/1","doi-asserted-by":"crossref","first-page":"580","DOI":"10.1002\/jcc.22885","volume":"33","author":"Lu","year":"2012","journal-title":"J. Comput. Chem."}],"container-title":["Dalton Transactions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2022\/DT\/D2DT00242F","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T03:45:55Z","timestamp":1782877555000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/dt\/article\/51\/12\/4806-4813\/764995"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022]]},"references-count":52,"journal-issue":{"issue":"12","published-print":{"date-parts":[[2022,3,22]]}},"URL":"https:\/\/doi.org\/10.1039\/d2dt00242f","relation":{},"ISSN":["1477-9226","1477-9234"],"issn-type":[{"value":"1477-9226","type":"print"},{"value":"1477-9234","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022]]}}}