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Here, we investigate the effect of stoichiometry variations and defects on the structural and optoelectronic properties of monocrystalline Zn\n                    <jats:sub>3<\/jats:sub>\n                    P\n                    <jats:sub>2<\/jats:sub>\n                    .\n                  <\/jats:p>","DOI":"10.1039\/d2fd00055e","type":"journal-article","created":{"date-parts":[[2022,4,11]],"date-time":"2022-04-11T14:21:19Z","timestamp":1649686879000},"page":"202-218","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["Stoichiometry modulates the optoelectronic functionality of zinc phosphide (Zn\n                    <sub>\n                      3\u2212\n                      <i>x<\/i>\n                    <\/sub>\n                    P\n                    <sub>\n                      2+\n                      <i>x<\/i>\n                    <\/sub>\n                    )"],"prefix":"10.1039","volume":"239","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1079-8063","authenticated-orcid":false,"given":"Elias Z.","family":"Stutz","sequence":"first","affiliation":[{"name":"Laboratory of Semiconductor Materials, Institute of Materials, Faculty of Engineering, Ecole Polytechnique F\u00e9d\u00e9rale de Lausanne, 1015 Lausanne, Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Santhanu P.","family":"Ramanandan","sequence":"additional","affiliation":[{"name":"Laboratory of Semiconductor Materials, Institute of Materials, Faculty of Engineering, Ecole Polytechnique F\u00e9d\u00e9rale de Lausanne, 1015 Lausanne, Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9871-4746","authenticated-orcid":false,"given":"Mischa","family":"Fl\u00f3r","sequence":"additional","affiliation":[{"name":"Laboratory of Semiconductor Materials, Institute of Materials, Faculty of Engineering, Ecole Polytechnique F\u00e9d\u00e9rale de Lausanne, 1015 Lausanne, Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rajrupa","family":"Paul","sequence":"additional","affiliation":[{"name":"Laboratory of Semiconductor Materials, Institute of Materials, Faculty of Engineering, Ecole Polytechnique F\u00e9d\u00e9rale de Lausanne, 1015 Lausanne, Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mahdi","family":"Zamani","sequence":"additional","affiliation":[{"name":"Laboratory of Semiconductor Materials, Institute of Materials, Faculty of Engineering, Ecole Polytechnique F\u00e9d\u00e9rale de Lausanne, 1015 Lausanne, Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4993-2979","authenticated-orcid":false,"given":"Simon","family":"Escobar Steinvall","sequence":"additional","affiliation":[{"name":"Laboratory of Semiconductor Materials, Institute of Materials, Faculty of Engineering, Ecole Polytechnique F\u00e9d\u00e9rale de Lausanne, 1015 Lausanne, Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Diego Armando","family":"Sandoval Salaiza","sequence":"additional","affiliation":[{"name":"Laboratory of Semiconductor Materials, Institute of Materials, Faculty of Engineering, Ecole Polytechnique F\u00e9d\u00e9rale de Lausanne, 1015 Lausanne, Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cl\u00e0udia","family":"Xifra Montesinos","sequence":"additional","affiliation":[{"name":"Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, BIST, Campus UAB, Bellaterra, Barcelona, Catalonia, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6540-0377","authenticated-orcid":false,"given":"Maria Chiara","family":"Spadaro","sequence":"additional","affiliation":[{"name":"Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, BIST, Campus UAB, Bellaterra, Barcelona, Catalonia, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jean-Baptiste","family":"Leran","sequence":"additional","affiliation":[{"name":"Laboratory of Semiconductor Materials, Institute of Materials, Faculty of Engineering, Ecole Polytechnique F\u00e9d\u00e9rale de Lausanne, 1015 Lausanne, Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander P.","family":"Litvinchuk","sequence":"additional","affiliation":[{"name":"Texas Center for Superconductivity and Department of Physics, University of Houston, Houston, Texas 77204-5002, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jordi","family":"Arbiol","sequence":"additional","affiliation":[{"name":"Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, BIST, Campus UAB, Bellaterra, Barcelona, Catalonia, Spain"},{"name":"ICREA, Pg. 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