{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T05:38:30Z","timestamp":1782970710117,"version":"3.54.5"},"reference-count":60,"publisher":"Royal Society of Chemistry (RSC)","issue":"16","license":[{"start":{"date-parts":[[2023,3,24]],"date-time":"2023-03-24T00:00:00Z","timestamp":1679616000000},"content-version":"am","delay-in-days":447,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["2020R1F1A1076028"],"award-info":[{"award-number":["2020R1F1A1076028"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["2021R1F1A1063125"],"award-info":[{"award-number":["2021R1F1A1063125"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Org. Biomol. Chem."],"abstract":"<jats:p>\n                    The synthesis of \u03b1-fluoroamines was achieved\n                    <jats:italic>via<\/jats:italic>\n                    deoxygenative geminal fluorosulfonimidation of 1,2-diketones using a dealkylation-resistant phosphoramidite under mild conditions that require neither excess reagents nor transition metal catalysts.\n                  <\/jats:p>","DOI":"10.1039\/d2ob00498d","type":"journal-article","created":{"date-parts":[[2022,3,24]],"date-time":"2022-03-24T20:02:02Z","timestamp":1648152122000},"page":"3263-3267","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["\u03b1-Fluoroamine synthesis\n                    <i>via<\/i>\n                    P(\n                    <scp>iii<\/scp>\n                    )-mediated deoxygenative geminal fluorosulfonimidation of 1,2-diketones"],"prefix":"10.1039","volume":"20","author":[{"given":"Yeri","family":"Son","sequence":"first","affiliation":[{"name":"Department of Chemistry, Gwangju Institute of Science and Technology (GIST), 123 Cheomdan-gwagi-ro, Buk-gu, Gwangju 61005, Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sunjoo","family":"Hwang","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Gwangju Institute of Science and Technology (GIST), 123 Cheomdan-gwagi-ro, Buk-gu, Gwangju 61005, Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sujin","family":"Bak","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Gwangju Institute of Science and Technology (GIST), 123 Cheomdan-gwagi-ro, Buk-gu, Gwangju 61005, Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ha Eun","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Gwangju Institute of Science and Technology (GIST), 123 Cheomdan-gwagi-ro, Buk-gu, Gwangju 61005, Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5237-5566","authenticated-orcid":false,"given":"Jun-Ho","family":"Choi","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Gwangju Institute of Science and Technology (GIST), 123 Cheomdan-gwagi-ro, Buk-gu, Gwangju 61005, Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3050-4798","authenticated-orcid":false,"given":"Won-jin","family":"Chung","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Gwangju Institute of Science and Technology (GIST), 123 Cheomdan-gwagi-ro, Buk-gu, Gwangju 61005, Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2022]]},"reference":[{"key":"D2OB00498D\/cit1\/1","doi-asserted-by":"crossref","first-page":"1100","DOI":"10.1002\/cmdc.200700059","volume":"2","author":"Morgenthaler","year":"2007","journal-title":"ChemMedChem"},{"key":"D2OB00498D\/cit2a\/1","doi-asserted-by":"crossref","first-page":"957","DOI":"10.1021\/jm00125a006","volume":"32","author":"Donetti","year":"1989","journal-title":"J. Med. Chem."},{"key":"D2OB00498D\/cit2b\/1","doi-asserted-by":"crossref","first-page":"2087","DOI":"10.1021\/jm981133m","volume":"42","author":"van Niel","year":"1999","journal-title":"J. Med. Chem."},{"key":"D2OB00498D\/cit2c\/1","doi-asserted-by":"crossref","first-page":"570","DOI":"10.1002\/cbic.200300833","volume":"5","author":"Jeschke","year":"2004","journal-title":"ChemBioChem"},{"key":"D2OB00498D\/cit2d\/1","doi-asserted-by":"crossref","first-page":"637","DOI":"10.1002\/cbic.200301023","volume":"5","author":"B\u00f6hm","year":"2004","journal-title":"ChemBioChem"},{"key":"D2OB00498D\/cit2e\/1","doi-asserted-by":"crossref","first-page":"4359","DOI":"10.1021\/jm800219f","volume":"51","author":"Hagmann","year":"2008","journal-title":"J. Med. Chem."},{"key":"D2OB00498D\/cit2f\/1","doi-asserted-by":"crossref","first-page":"8315","DOI":"10.1021\/acs.jmedchem.5b00258","volume":"58","author":"Gillis","year":"2015","journal-title":"J. Med. Chem."},{"key":"D2OB00498D\/cit3a\/1","doi-asserted-by":"crossref","first-page":"2247","DOI":"10.1039\/cc9960002247","author":"Stavber","year":"1996","journal-title":"Chem. Commun."},{"key":"D2OB00498D\/cit3b\/1","doi-asserted-by":"crossref","first-page":"1136","DOI":"10.1016\/j.tetlet.2008.12.090","volume":"50","author":"Yadav","year":"2009","journal-title":"Tetrahedron Lett."},{"key":"D2OB00498D\/cit3c\/1","doi-asserted-by":"crossref","first-page":"16354","DOI":"10.1021\/ja9076588","volume":"131","author":"Wu","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"D2OB00498D\/cit3d\/1","doi-asserted-by":"crossref","first-page":"2856","DOI":"10.1021\/ja909716k","volume":"132","author":"Qiu","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"D2OB00498D\/cit3e\/1","doi-asserted-by":"crossref","first-page":"4620","DOI":"10.1021\/ol1019579","volume":"12","author":"Duthion","year":"2010","journal-title":"Org. Lett."},{"key":"D2OB00498D\/cit3f\/1","doi-asserted-by":"crossref","first-page":"4177","DOI":"10.1021\/jo300433a","volume":"77","author":"Kalow","year":"2012","journal-title":"J. Org. Chem."},{"key":"D2OB00498D\/cit3g\/1","doi-asserted-by":"crossref","first-page":"8566","DOI":"10.1039\/c2ob26664d","volume":"10","author":"Wang","year":"2012","journal-title":"Org. Biomol. Chem."},{"key":"D2OB00498D\/cit3h\/1","doi-asserted-by":"crossref","first-page":"2469","DOI":"10.1002\/anie.201208471","volume":"52","author":"Kong","year":"2013","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2OB00498D\/cit3i\/1","doi-asserted-by":"crossref","first-page":"2754","DOI":"10.1039\/C3SC53107D","volume":"5","author":"Suzuki","year":"2014","journal-title":"Chem. Sci."},{"key":"D2OB00498D\/cit3j\/1","doi-asserted-by":"crossref","first-page":"11079","DOI":"10.1002\/anie.201406797","volume":"53","author":"Zhang","year":"2014","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2OB00498D\/cit3k\/1","doi-asserted-by":"crossref","first-page":"4295","DOI":"10.1002\/ejoc.201500231","volume":"2015","author":"Chen","year":"2015","journal-title":"Eur. J. Org. Chem."},{"key":"D2OB00498D\/cit3l\/1","doi-asserted-by":"crossref","first-page":"3379","DOI":"10.1039\/C4CC10162F","volume":"51","author":"Saavedra-Olavarr\u00eda","year":"2015","journal-title":"Chem. Commun."},{"key":"D2OB00498D\/cit3m\/1","doi-asserted-by":"crossref","first-page":"11360","DOI":"10.1021\/jacs.6b07221","volume":"138","author":"Lu","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"D2OB00498D\/cit3n\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.jfluchem.2016.02.010","volume":"185","author":"Serguchev","year":"2016","journal-title":"J. Fluorine Chem."},{"key":"D2OB00498D\/cit3o\/1","doi-asserted-by":"crossref","first-page":"2735","DOI":"10.1002\/anie.201913100","volume":"59","author":"Hou","year":"2020","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2OB00498D\/cit4a\/1","doi-asserted-by":"crossref","first-page":"1786","DOI":"10.1039\/C5SC04237B","volume":"7","author":"Chen","year":"2016","journal-title":"Chem. Sci."},{"key":"D2OB00498D\/cit4b\/1","doi-asserted-by":"crossref","first-page":"10444","DOI":"10.1039\/C6OB01858K","volume":"14","author":"Zhou","year":"2016","journal-title":"Org. Biomol. Chem."},{"key":"D2OB00498D\/cit4c\/1","doi-asserted-by":"crossref","first-page":"529","DOI":"10.1039\/C6QO00813E","volume":"4","author":"Huang","year":"2017","journal-title":"Org. Chem. Front."},{"key":"D2OB00498D\/cit5a\/1","doi-asserted-by":"crossref","first-page":"2651","DOI":"10.1021\/ja01495a073","volume":"82","author":"Ramirez","year":"1960","journal-title":"J. Am. Chem. Soc."},{"key":"D2OB00498D\/cit5b\/1","doi-asserted-by":"crossref","first-page":"2652","DOI":"10.1021\/ja01495a074","volume":"82","author":"Ramirez","year":"1960","journal-title":"J. Am. Chem. Soc."},{"key":"D2OB00498D\/cit5c\/1","doi-asserted-by":"crossref","first-page":"337","DOI":"10.1351\/pac196409020337","volume":"9","author":"Ramirez","year":"1964","journal-title":"Pure Appl. Chem."},{"key":"D2OB00498D\/cit5d\/1","doi-asserted-by":"crossref","first-page":"90","DOI":"10.1055\/s-1974-23249","volume":"1974","author":"Ramirez","year":"1974","journal-title":"Synthesis"},{"key":"D2OB00498D\/cit5e\/1","doi-asserted-by":"crossref","first-page":"3153","DOI":"10.1016\/S0040-4020(01)98722-8","volume":"24","author":"Ramirez","year":"1968","journal-title":"Tetrahedron"},{"key":"D2OB00498D\/cit5f\/1","doi-asserted-by":"crossref","first-page":"168","DOI":"10.1021\/ar50006a002","volume":"1","author":"Ramirez","year":"1968","journal-title":"Acc. Chem. Res."},{"key":"D2OB00498D\/cit5g\/1","doi-asserted-by":"crossref","first-page":"10605","DOI":"10.1002\/anie.201205604","volume":"51","author":"Miller","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2OB00498D\/cit5h\/1","doi-asserted-by":"crossref","first-page":"3090","DOI":"10.1021\/ol401276b","volume":"15","author":"Zhao","year":"2013","journal-title":"Org. Lett."},{"key":"D2OB00498D\/cit5i\/1","doi-asserted-by":"crossref","first-page":"3810","DOI":"10.1021\/acs.orglett.5b01784","volume":"17","author":"Wang","year":"2015","journal-title":"Org. Lett."},{"key":"D2OB00498D\/cit5j\/1","doi-asserted-by":"crossref","first-page":"4136","DOI":"10.1016\/j.tetlet.2018.10.023","volume":"59","author":"Liu","year":"2018","journal-title":"Tetrahedron Lett."},{"key":"D2OB00498D\/cit6a\/1","doi-asserted-by":"crossref","first-page":"6029","DOI":"10.1021\/acs.orglett.9b02182","volume":"21","author":"Tan","year":"2019","journal-title":"Org. Lett."},{"key":"D2OB00498D\/cit6b\/1","doi-asserted-by":"crossref","first-page":"10251","DOI":"10.1039\/D0CC04086J","volume":"56","author":"Zhang","year":"2020","journal-title":"Chem. Commun."},{"key":"D2OB00498D\/cit6c\/1","doi-asserted-by":"crossref","first-page":"6922","DOI":"10.1021\/acs.orglett.0c02453","volume":"22","author":"Liu","year":"2020","journal-title":"Org. Lett."},{"key":"D2OB00498D\/cit6d\/1","doi-asserted-by":"crossref","first-page":"8376","DOI":"10.1021\/acs.orglett.0c02998","volume":"22","author":"Deng","year":"2020","journal-title":"Org. Lett."},{"key":"D2OB00498D\/cit6e\/1","doi-asserted-by":"crossref","first-page":"9101","DOI":"10.1039\/D0SC03118F","volume":"11","author":"Jin","year":"2020","journal-title":"Chem. Sci."},{"key":"D2OB00498D\/cit6f\/1","doi-asserted-by":"crossref","first-page":"2590","DOI":"10.1021\/acs.orglett.1c00498","volume":"23","author":"Tan","year":"2021","journal-title":"Org. Lett."},{"key":"D2OB00498D\/cit6g\/1","doi-asserted-by":"crossref","first-page":"1880","DOI":"10.1021\/acs.orglett.1c00286","volume":"23","author":"Zhang","year":"2021","journal-title":"Org. Lett."},{"key":"D2OB00498D\/cit7\/1","doi-asserted-by":"crossref","first-page":"4190","DOI":"10.1021\/acs.orglett.0c01258","volume":"22","author":"Choi","year":"2020","journal-title":"Org. Lett."},{"key":"D2OB00498D\/cit8\/1","doi-asserted-by":"crossref","first-page":"6385","DOI":"10.1002\/ejoc.201402919","volume":"2014","author":"Chen","year":"2014","journal-title":"Eur. J. Org. Chem."},{"key":"D2OB00498D\/cit11a\/1","doi-asserted-by":"crossref","first-page":"96","DOI":"10.1021\/ja01280a022","volume":"59","author":"Hammett","year":"1937","journal-title":"J. Am. Chem. Soc."},{"key":"D2OB00498D\/cit11b\/1","doi-asserted-by":"crossref","first-page":"125","DOI":"10.1021\/cr60056a010","volume":"17","author":"Hammett","year":"1935","journal-title":"Chem. Rev."},{"key":"D2OB00498D\/cit11c\/1","doi-asserted-by":"crossref","first-page":"165","DOI":"10.1021\/cr00002a004","volume":"91","author":"Hansch","year":"1991","journal-title":"Chem. Rev."},{"key":"D2OB00498D\/cit13\/1","volume-title":"Gaussian 16, Revision C.01","author":"Frisch","year":"2019","unstructured":"M. J.Frisch ,  G. W.Trucks ,  H. B.Schlegel ,  G. E.Scuseria ,  M. A.Robb ,  J. R.Cheeseman ,  G.Scalmani ,  V.Barone ,  G. A.Petersson ,  H.Nakatsuji ,  X.Li ,  M.Caricato ,  A. V.Marenich ,  J.Bloino ,  B. G.Janesko ,  R.Gomperts ,  B.Mennucci ,  H. P.Hratchian ,  J. V.Ortiz ,  A. F.Izmaylov ,  J. L.Sonnenberg ,  D.Williams-Young ,  F.Ding ,  F.Lipparini ,  F.Egidi ,  J.Goings ,  B.Peng ,  A.Petrone ,  T.Henderson ,  D.Ranasinghe ,  V. G.Zakrzewski ,  J.Gao ,  N.Rega ,  G.Zheng ,  W.Liang ,  M.Hada ,  M.Ehara ,  K.Toyota ,  R.Fukuda ,  J.Hasegawa ,  M.Ishida ,  T.Nakajima ,  Y.Honda ,  O.Kitao ,  H.Nakai ,  T.Vreven ,  K.Throssell ,  J. A.Montgomery, Jr. ,  J. E.Peralta ,  F.Ogliaro ,  M. J.Bearpark ,  J. J.Heyd ,  E. N.Brothers ,  K. N.Kudin ,  V. N.Staroverov ,  T. A.Keith ,  R.Kobayashi ,  J.Normand ,  K.Raghavachari ,  A. P.Rendell ,  J. C.Burant ,  S. S.Iyengar ,  J.Tomasi ,  M.Cossi ,  J. M.Millam ,  M.Klene ,  C.Adamo ,  R.Cammi ,  J. W.Ochterski ,  R. L.Martin ,  K.Morokuma ,  O.Farkas ,  J. B.Foresman  and  D. J.Fox ,  Gaussian 16, Revision C.01 ,  Gaussian, Inc. ,  Wallingford CT ,  2019"},{"key":"D2OB00498D\/cit15\/1","volume-title":"Stewart Computational Chemistry","author":"Stewart","unstructured":"J. J. P.Stewart ,  Stewart Computational Chemistry ,  Colorado Springs ,  CO, USA"},{"key":"D2OB00498D\/cit16a\/1","doi-asserted-by":"crossref","first-page":"215","DOI":"10.1007\/s00214-007-0310-x","volume":"120","author":"Zhao","year":"2008","journal-title":"Theor. Chem. Acc."},{"key":"D2OB00498D\/cit16b\/1","doi-asserted-by":"crossref","first-page":"157","DOI":"10.1021\/ar700111a","volume":"41","author":"Zhao","year":"2008","journal-title":"Acc. Chem. Res."},{"key":"D2OB00498D\/cit17a\/1","doi-asserted-by":"crossref","first-page":"154104","DOI":"10.1063\/1.3382344","volume":"132","author":"Grimme","year":"2010","journal-title":"J. Chem. Phys."},{"key":"D2OB00498D\/cit17b\/1","doi-asserted-by":"crossref","first-page":"2030","DOI":"10.1021\/ct800252z","volume":"4","author":"Peverati","year":"2008","journal-title":"J. Chem. Theory Comput."},{"key":"D2OB00498D\/cit18a\/1","doi-asserted-by":"crossref","first-page":"117","DOI":"10.1016\/0301-0104(81)85090-2","volume":"55","author":"Miertu\u0161","year":"1981","journal-title":"Chem. Phys."},{"key":"D2OB00498D\/cit18b\/1","doi-asserted-by":"crossref","first-page":"1127","DOI":"10.1002\/jcc.540151009","volume":"15","author":"Pascual-Ahuir","year":"1994","journal-title":"J. Comput. Chem."},{"key":"D2OB00498D\/cit18c\/1","doi-asserted-by":"crossref","first-page":"1995","DOI":"10.1021\/jp9716997","volume":"102","author":"Barone","year":"1998","journal-title":"J. Phys. Chem. A"},{"key":"D2OB00498D\/cit19a\/1","doi-asserted-by":"crossref","first-page":"2571","DOI":"10.1063\/1.463096","volume":"97","author":"Sch\u00e4fer","year":"1992","journal-title":"J. Chem. Phys."},{"key":"D2OB00498D\/cit19b\/1","doi-asserted-by":"crossref","first-page":"5829","DOI":"10.1063\/1.467146","volume":"100","author":"Sch\u00e4fer","year":"1994","journal-title":"J. Chem. Phys."},{"key":"D2OB00498D\/cit19c\/1","doi-asserted-by":"crossref","first-page":"12753","DOI":"10.1063\/1.1627293","volume":"119","author":"Weigend","year":"2003","journal-title":"J. Chem. Phys."},{"key":"D2OB00498D\/cit19d\/1","doi-asserted-by":"crossref","first-page":"3297","DOI":"10.1039\/b508541a","volume":"7","author":"Weigend","year":"2005","journal-title":"Phys. Chem. Chem. Phys."}],"container-title":["Organic &amp; Biomolecular Chemistry"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2022\/OB\/D2OB00498D","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T04:25:48Z","timestamp":1782966348000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/ob\/article\/20\/16\/3263-3267\/778417"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022]]},"references-count":60,"journal-issue":{"issue":"16","published-print":{"date-parts":[[2022,4,20]]}},"URL":"https:\/\/doi.org\/10.1039\/d2ob00498d","relation":{},"ISSN":["1477-0520","1477-0539"],"issn-type":[{"value":"1477-0520","type":"print"},{"value":"1477-0539","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022]]}}}