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Chem."],"abstract":"<jats:p>\n                    Density functional theory studies have confirmed that\u00a0\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>C<\/jats:italic>\n                    -diprotonation of \u03b1,\u03b2-unsaturated nitriles, and likewise\u00a0\n                    <jats:italic>O<\/jats:italic>\n                    ,\n                    <jats:italic>C<\/jats:italic>\n                    -diprotonation of isoelectronic ketones, provide the best rationale for their electrophilic reactions with weak nucleophiles, such as benzene.\n                  <\/jats:p>","DOI":"10.1039\/d2ob01141g","type":"journal-article","created":{"date-parts":[[2022,8,6]],"date-time":"2022-08-06T05:21:48Z","timestamp":1659763308000},"page":"6799-6808","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["DFT insights into superelectrophilic activation of \u03b1,\u03b2-unsaturated nitriles and ketones in superacids"],"prefix":"10.1039","volume":"20","author":[{"given":"Alexander M.","family":"Genaev","sequence":"first","affiliation":[{"name":"Vorozhtsov Novosibirsk Institute of Organic Chemistry, Pr. 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