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Chem."],"abstract":"<jats:p>TEMPO-based nitroxides with different distances between the phenyl group and the C2 carbon were synthesized and their ESR, redox potential, reduction reactivity toward ascorbate, and computational geometry were evaluated.<\/jats:p>","DOI":"10.1039\/d2ob01589g","type":"journal-article","created":{"date-parts":[[2022,10,3]],"date-time":"2022-10-03T07:50:20Z","timestamp":1664783420000},"page":"7956-7962","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Substituent effects of the phenyl ring at different positions from the \u03b1-carbon of TEMPO-type nitroxide"],"prefix":"10.1039","volume":"20","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8567-8213","authenticated-orcid":false,"given":"Toshihide","family":"Yamasaki","sequence":"first","affiliation":[{"name":"Laboratory of Biophysical Chemistry, Kobe Pharmaceutical University, 4-19-1 Motoyamakita-machi, Higashinada-ku, Kobe 658-8558, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuto","family":"Matsuda","sequence":"additional","affiliation":[{"name":"Laboratory of Biophysical Chemistry, Kobe Pharmaceutical University, 4-19-1 Motoyamakita-machi, Higashinada-ku, Kobe 658-8558, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Masayuki","family":"Munekane","sequence":"additional","affiliation":[{"name":"Laboratory of Biophysical Chemistry, Kobe Pharmaceutical University, 4-19-1 Motoyamakita-machi, Higashinada-ku, Kobe 658-8558, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8748-026X","authenticated-orcid":false,"given":"Kohei","family":"Sano","sequence":"additional","affiliation":[{"name":"Laboratory of Biophysical Chemistry, Kobe Pharmaceutical University, 4-19-1 Motoyamakita-machi, Higashinada-ku, Kobe 658-8558, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6334-4466","authenticated-orcid":false,"given":"Takahiro","family":"Mukai","sequence":"additional","affiliation":[{"name":"Laboratory of Biophysical Chemistry, Kobe Pharmaceutical University, 4-19-1 Motoyamakita-machi, Higashinada-ku, Kobe 658-8558, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2022]]},"reference":[{"key":"D2OB01589G\/cit1\/1","doi-asserted-by":"crossref","first-page":"1632","DOI":"10.1016\/j.freeradbiomed.2007.02.030","volume":"42","author":"Soule","year":"2007","journal-title":"Free Radical Biol. 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