{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,31]],"date-time":"2026-07-31T22:48:22Z","timestamp":1785538102888,"version":"3.56.0"},"reference-count":78,"publisher":"Royal Society of Chemistry (RSC)","issue":"36","license":[{"start":{"date-parts":[[2022,8,18]],"date-time":"2022-08-18T00:00:00Z","timestamp":1660780800000},"content-version":"vor","delay-in-days":229,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/100008605","name":"Indian National Science Academy","doi-asserted-by":"publisher","award":["very limited funding because of retirement"],"award-info":[{"award-number":["very limited funding because of retirement"]}],"id":[{"id":"10.13039\/100008605","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["RSC Adv."],"abstract":"<jats:p>\n                    Structurally similar enediynes showed decrease in interior proximal bond angles (\n                    <jats:italic>P<\/jats:italic>\n                    <jats:sub>a<\/jats:sub>\n                    and\n                    <jats:italic>P<\/jats:italic>\n                    <jats:sub>b<\/jats:sub>\n                    ) with increase in reactivity. Enediynes with average interior proximal angles [(\n                    <jats:italic>P<\/jats:italic>\n                    <jats:sub>a<\/jats:sub>\n                    +\n                    <jats:italic>P<\/jats:italic>\n                    <jats:sub>b<\/jats:sub>\n                    )\/2] less than 166\u00b0 undergo cyclization under ambient conditions.\n                  <\/jats:p>","DOI":"10.1039\/d2ra03193k","type":"journal-article","created":{"date-parts":[[2022,8,18]],"date-time":"2022-08-18T05:14:32Z","timestamp":1660799672000},"page":"23552-23565","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Angle distortion model for predicting enediyne activation towards Bergman cyclization: an alternate to the distance theory"],"prefix":"10.1039","volume":"12","author":[{"given":"Prabuddha","family":"Bhattacharya","sequence":"first","affiliation":[{"name":"Department of Chemistry, Mrinalini Datta Mahavidyapith, Kolkata 700 051, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Soham","family":"Chakraborty","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology (Indian School of Mines), Dhanbad 826 004, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ashwin","family":"Balaji","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology, Kharagpur 721 302, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4041-2846","authenticated-orcid":false,"given":"Amit","family":"Basak","sequence":"additional","affiliation":[{"name":"Division of Chemical Science, Indian Institute of Science Education and Research, Kolkata 741 246, India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2022]]},"reference":[{"key":"D2RA03193K\/cit1a\/1","doi-asserted-by":"crossref","first-page":"660","DOI":"10.1021\/ja00757a071","volume":"94","author":"Jones","year":"1972","journal-title":"J. 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