{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,8]],"date-time":"2026-09-08T19:03:44Z","timestamp":1788894224303,"version":"build-2803163510"},"reference-count":48,"publisher":"Royal Society of Chemistry (RSC)","issue":"31","license":[{"start":{"date-parts":[[2022,7,8]],"date-time":"2022-07-08T00:00:00Z","timestamp":1657238400000},"content-version":"vor","delay-in-days":188,"URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2017YFA0403103"],"award-info":[{"award-number":["2017YFA0403103"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22072157, 21972146, 22121002"],"award-info":[{"award-number":["22072157, 21972146, 22121002"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002367","name":"Chinese Academy of Sciences","doi-asserted-by":"publisher","award":["QYZDY-SSW-SLH013"],"award-info":[{"award-number":["QYZDY-SSW-SLH013"]}],"id":[{"id":"10.13039\/501100002367","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004106","name":"East China Normal University","doi-asserted-by":"publisher","award":["2020ST2203"],"award-info":[{"award-number":["2020ST2203"]}],"id":[{"id":"10.13039\/501100004106","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Sci."],"abstract":"<jats:p>\n                    An earth-abundant Co-based catalyst, Co@C\u2013N(800), could efficiently catalyze the reductive amination of carbonyl compounds into primary amines at 35 \u00b0C owing to the synergistic effect of Co nanoparticles and atomically dispersed Co\u2013N\n                    <jats:sub>\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    sites.\n                  <\/jats:p>","DOI":"10.1039\/d2sc01596j","type":"journal-article","created":{"date-parts":[[2022,7,8]],"date-time":"2022-07-08T08:01:25Z","timestamp":1657267285000},"page":"9047-9055","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":49,"title":["Nanoparticles and single atoms of cobalt synergistically enabled low-temperature reductive amination of carbonyl compounds"],"prefix":"10.1039","volume":"13","author":[{"given":"Bingxiao","family":"Zheng","sequence":"first","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China"},{"name":"Institute of Eco-Chongming, Shanghai 202162, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiao","family":"Xu","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China"},{"name":"Institute of Eco-Chongming, Shanghai 202162, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9573-600X","authenticated-orcid":false,"given":"Jinliang","family":"Song","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6266-8290","authenticated-orcid":false,"given":"Haihong","family":"Wu","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China"},{"name":"Institute of Eco-Chongming, Shanghai 202162, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuelei","family":"Mei","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China"},{"name":"Institute of Eco-Chongming, Shanghai 202162, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kaili","family":"Zhang","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China"},{"name":"Institute of Eco-Chongming, Shanghai 202162, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wanying","family":"Han","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China"},{"name":"Institute of Eco-Chongming, Shanghai 202162, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Wu","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China"},{"name":"Institute of Eco-Chongming, Shanghai 202162, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingyuan","family":"He","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China"},{"name":"Institute of Eco-Chongming, Shanghai 202162, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0440-809X","authenticated-orcid":false,"given":"Buxing","family":"Han","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China"},{"name":"Institute of Eco-Chongming, Shanghai 202162, China"},{"name":"Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, CAS Research\/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"},{"name":"School of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2022]]},"reference":[{"key":"D2SC01596J\/cit1a\/1","doi-asserted-by":"crossref","first-page":"17","DOI":"10.1016\/j.apcata.2004.08.025","volume":"280","author":"Chen","year":"2005","journal-title":"Appl. Catal., A"},{"key":"D2SC01596J\/cit1b\/1","doi-asserted-by":"crossref","first-page":"1540","DOI":"10.1021\/acs.chemrev.5b00354","volume":"116","author":"Delidovich","year":"2016","journal-title":"Chem. Rev."},{"key":"D2SC01596J\/cit1c\/1","doi-asserted-by":"crossref","first-page":"1637","DOI":"10.1021\/acs.chemrev.5b00264","volume":"116","author":"Gandini","year":"2016","journal-title":"Chem. Rev."},{"key":"D2SC01596J\/cit1d\/1","doi-asserted-by":"crossref","first-page":"11857","DOI":"10.1021\/acs.chemrev.9b00383","volume":"119","author":"Afanasyev","year":"2019","journal-title":"Chem. Rev."},{"key":"D2SC01596J\/cit1e\/1","doi-asserted-by":"crossref","first-page":"4775","DOI":"10.1039\/C9SC00595A","volume":"10","author":"Qiu","year":"2019","journal-title":"Chem. Sci."},{"key":"D2SC01596J\/cit2\/1","doi-asserted-by":"crossref","first-page":"5988","DOI":"10.1016\/j.tet.2016.07.021","volume":"72","author":"Jung","year":"2016","journal-title":"Tetrahedron"},{"key":"D2SC01596J\/cit3\/1","doi-asserted-by":"crossref","first-page":"7599","DOI":"10.1002\/anie.201103199","volume":"50","author":"Imm","year":"2011","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2SC01596J\/cit4\/1","doi-asserted-by":"crossref","first-page":"8661","DOI":"10.1002\/anie.200803229","volume":"47","author":"Gunanathan","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2SC01596J\/cit5\/1","doi-asserted-by":"crossref","first-page":"150","DOI":"10.1002\/anie.201106737","volume":"51","author":"Das","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2SC01596J\/cit6\/1","doi-asserted-by":"crossref","first-page":"355","DOI":"10.1021\/jacs.7b10496","volume":"140","author":"Gallardo-Donaire","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"D2SC01596J\/cit7\/1","doi-asserted-by":"crossref","first-page":"699","DOI":"10.1038\/s41467-019-08577-4","volume":"10","author":"Li","year":"2019","journal-title":"Nat. Commun."},{"key":"D2SC01596J\/cit8\/1","doi-asserted-by":"crossref","first-page":"2024","DOI":"10.1021\/jacs.7b12898","volume":"140","author":"Tan","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"D2SC01596J\/cit9\/1","doi-asserted-by":"crossref","first-page":"4123","DOI":"10.1038\/s41467-018-06416-6","volume":"9","author":"Senthamarai","year":"2018","journal-title":"Nat. Commun."},{"key":"D2SC01596J\/cit10\/1","doi-asserted-by":"crossref","first-page":"2149","DOI":"10.1007\/s10562-016-1822-6","volume":"146","author":"Kumari","year":"2016","journal-title":"Catal. Lett."},{"key":"D2SC01596J\/cit11\/1","doi-asserted-by":"crossref","first-page":"1662","DOI":"10.1002\/anie.201108155","volume":"51","author":"Das","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2SC01596J\/cit12\/1","doi-asserted-by":"crossref","first-page":"842","DOI":"10.1002\/cssc.201601843","volume":"10","author":"Adam","year":"2017","journal-title":"ChemSusChem"},{"key":"D2SC01596J\/cit13\/1","doi-asserted-by":"crossref","first-page":"794","DOI":"10.2174\/1385272820666160525123907","volume":"21","author":"Goksu","year":"2017","journal-title":"Curr. Org. Chem."},{"key":"D2SC01596J\/cit14\/1","doi-asserted-by":"crossref","first-page":"321","DOI":"10.1039\/C1GC16200D","volume":"14","author":"Vitasari","year":"2012","journal-title":"Green Chem."},{"key":"D2SC01596J\/cit15\/1","doi-asserted-by":"crossref","first-page":"1026","DOI":"10.1002\/cssc.201403385","volume":"8","author":"Cantero","year":"2015","journal-title":"ChemSusChem"},{"key":"D2SC01596J\/cit16\/1","doi-asserted-by":"crossref","first-page":"1306","DOI":"10.1002\/cssc.201500115","volume":"8","author":"Venderbosch","year":"2015","journal-title":"ChemSusChem"},{"key":"D2SC01596J\/cit17\/1","doi-asserted-by":"crossref","first-page":"2231","DOI":"10.1007\/s10570-015-0674-3","volume":"22","author":"Mart\u0131\u00ednez","year":"2015","journal-title":"Cellulose"},{"key":"D2SC01596J\/cit18\/1","doi-asserted-by":"crossref","first-page":"1403","DOI":"10.1021\/ar500426g","volume":"48","author":"Villa","year":"2015","journal-title":"Acc. Chem. Res."},{"key":"D2SC01596J\/cit19\/1","doi-asserted-by":"crossref","first-page":"14190","DOI":"10.1038\/ncomms14190","volume":"8","author":"Meng","year":"2017","journal-title":"Nat. Commun."},{"key":"D2SC01596J\/cit20\/1","doi-asserted-by":"crossref","first-page":"4865","DOI":"10.1039\/C8GC02659A","volume":"20","author":"Zhang","year":"2018","journal-title":"Green Chem."},{"key":"D2SC01596J\/cit21\/1","doi-asserted-by":"crossref","first-page":"358","DOI":"10.1002\/adsc.201500968","volume":"358","author":"Gallardo-Donaire","year":"2016","journal-title":"Adv. Synth. Catal."},{"key":"D2SC01596J\/cit22\/1","doi-asserted-by":"crossref","first-page":"11493","DOI":"10.1021\/jacs.7b04481","volume":"139","author":"Komanoya","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"D2SC01596J\/cit23\/1","doi-asserted-by":"crossref","first-page":"2258","DOI":"10.3390\/catal5042258","volume":"5","author":"Dong","year":"2015","journal-title":"Catalysts"},{"key":"D2SC01596J\/cit24\/1","doi-asserted-by":"crossref","first-page":"7763","DOI":"10.1021\/acscatal.0c01872","volume":"10","author":"Xie","year":"2020","journal-title":"ACS Catal."},{"key":"D2SC01596J\/cit25\/1","doi-asserted-by":"crossref","first-page":"3050","DOI":"10.1002\/anie.201610964","volume":"56","author":"Liang","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2SC01596J\/cit26\/1","doi-asserted-by":"crossref","first-page":"4130","DOI":"10.1002\/cctc.201900335","volume":"11","author":"Guo","year":"2019","journal-title":"ChemCatChem"},{"key":"D2SC01596J\/cit27\/1","doi-asserted-by":"crossref","first-page":"3045","DOI":"10.1021\/cs500757k","volume":"4","author":"Touchy","year":"2014","journal-title":"ACS Catal."},{"key":"D2SC01596J\/cit28\/1","doi-asserted-by":"crossref","first-page":"4699","DOI":"10.1002\/adsc.201801457","volume":"360","author":"Laroche","year":"2018","journal-title":"Adv. Synth. Catal."},{"key":"D2SC01596J\/cit29\/1","doi-asserted-by":"crossref","first-page":"2055","DOI":"10.1021\/ol0200605","volume":"4","author":"Gross","year":"2002","journal-title":"Org. Lett."},{"key":"D2SC01596J\/cit30\/1","doi-asserted-by":"crossref","first-page":"487","DOI":"10.1039\/C5GC01352F","volume":"18","author":"Chatterjee","year":"2016","journal-title":"Green Chem."},{"key":"D2SC01596J\/cit31\/1","doi-asserted-by":"crossref","first-page":"1618","DOI":"10.1021\/acssuschemeng.9b06464","volume":"8","author":"Jv","year":"2020","journal-title":"ACS Sustainable Chem. Eng."},{"key":"D2SC01596J\/cit32\/1","doi-asserted-by":"crossref","first-page":"75","DOI":"10.1016\/j.catcom.2007.05.016","volume":"9","author":"Chary","year":"2008","journal-title":"Catal. Commun."},{"key":"D2SC01596J\/cit33\/1","doi-asserted-by":"crossref","first-page":"7318","DOI":"10.1021\/acssuschemeng.1c01456","volume":"9","author":"Dong","year":"2021","journal-title":"ACS Sustainable Chem. Eng."},{"key":"D2SC01596J\/cit34\/1","doi-asserted-by":"crossref","first-page":"5064","DOI":"10.1002\/anie.201812100","volume":"58","author":"Murugesan","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2SC01596J\/cit35\/1","doi-asserted-by":"crossref","first-page":"71","DOI":"10.1038\/s41929-018-0202-6","volume":"2","author":"Hahn","year":"2019","journal-title":"Nat. Catal."},{"key":"D2SC01596J\/cit36\/1","doi-asserted-by":"crossref","first-page":"4144","DOI":"10.1021\/acsami.1c21157","volume":"14","author":"Bhunia","year":"2022","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"D2SC01596J\/cit37\/1","doi-asserted-by":"crossref","first-page":"326","DOI":"10.1126\/science.aan6245","volume":"358","author":"Jagadeesh","year":"2017","journal-title":"Science"},{"key":"D2SC01596J\/cit38\/1","doi-asserted-by":"crossref","first-page":"347","DOI":"10.1016\/j.jcat.2019.01.004","volume":"370","author":"Yuan","year":"2019","journal-title":"J. Catal."},{"key":"D2SC01596J\/cit39\/1","doi-asserted-by":"crossref","first-page":"2360","DOI":"10.1002\/cssc.202100553","volume":"14","author":"Elfinger","year":"2021","journal-title":"ChemSusChem"},{"key":"D2SC01596J\/cit40\/1","doi-asserted-by":"crossref","first-page":"1850","DOI":"10.1021\/cs502101c","volume":"5","author":"Zhong","year":"2015","journal-title":"ACS Catal."},{"key":"D2SC01596J\/cit41\/1","doi-asserted-by":"crossref","first-page":"178","DOI":"10.1016\/j.checat.2021.12.009","volume":"2","author":"Gao","year":"2022","journal-title":"Chem Catalysis"},{"key":"D2SC01596J\/cit42\/1","doi-asserted-by":"crossref","first-page":"6060","DOI":"10.1002\/anie.201200963","volume":"51","author":"Yu","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"key":"D2SC01596J\/cit43\/1","doi-asserted-by":"crossref","first-page":"6967","DOI":"10.1021\/ja9021683","volume":"131","author":"Li","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"D2SC01596J\/cit44\/1","doi-asserted-by":"crossref","first-page":"87","DOI":"10.1016\/j.mcat.2018.05.017","volume":"454","author":"Song","year":"2018","journal-title":"Mol. Catal."}],"container-title":["Chemical Science"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2022\/SC\/D2SC01596J","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T18:17:22Z","timestamp":1782929842000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/sc\/article\/13\/31\/9047-9055\/786080"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022]]},"references-count":48,"journal-issue":{"issue":"31","published-print":{"date-parts":[[2022,8,10]]}},"URL":"https:\/\/doi.org\/10.1039\/d2sc01596j","relation":{},"ISSN":["2041-6520","2041-6539"],"issn-type":[{"value":"2041-6520","type":"print"},{"value":"2041-6539","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022]]}}}