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Commun."],"abstract":"<jats:p>\n                    The mechanism of aldehyde\/ketones with M(BH\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    in aprotic solvents has been elucidated as a six-membered ring, in which hydride transfer to the C atom from the B atom, formation of L\u00b7BH\n                    <jats:sub>3<\/jats:sub>\n                    adduct, and disproportionation of BH\n                    <jats:sub>3<\/jats:sub>\n                    (OR)\n                    <jats:sup>\u2212<\/jats:sup>\n                    may be involved.\n                  <\/jats:p>","DOI":"10.1039\/d3cc06108f","type":"journal-article","created":{"date-parts":[[2024,3,14]],"date-time":"2024-03-14T06:20:40Z","timestamp":1710397240000},"page":"5486-5489","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Unravelling the underlying mechanism of the reduction of aldehydes\/ketones with metal borohydride in an aprotic solvent"],"prefix":"10.1039","volume":"60","author":[{"given":"Xinying","family":"Li","sequence":"first","affiliation":[{"name":"College of Chemistry, Zhengzhou University, Zhengzhou, Henan 450001, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1718-7409","authenticated-orcid":false,"given":"Jia-Xin","family":"Kang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang, Henan 453007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shasha","family":"Liang","sequence":"additional","affiliation":[{"name":"College of Chemistry, Zhengzhou University, Zhengzhou, Henan 450001, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xi-Hong","family":"Long","sequence":"additional","affiliation":[{"name":"College of Chemistry, Zhengzhou University, Zhengzhou, Henan 450001, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5297-1851","authenticated-orcid":false,"given":"Yan-Na","family":"Ma","sequence":"additional","affiliation":[{"name":"College of Chemistry, Zhengzhou University, Zhengzhou, Henan 450001, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9029-1777","authenticated-orcid":false,"given":"Xuenian","family":"Chen","sequence":"additional","affiliation":[{"name":"College of Chemistry, Zhengzhou University, Zhengzhou, Henan 450001, China"},{"name":"School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang, Henan 453007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2024]]},"reference":[{"key":"D3CC06108F\/cit1a\/1","doi-asserted-by":"crossref","first-page":"3421","DOI":"10.1021\/ja01869a037","volume":"62","author":"Schlesinger","year":"1940","journal-title":"J. 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