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Phys."],"abstract":"<jats:p>\n                    Imine hydroboration catalyzed by pincer-phosphorus (P) compounds occurs\n                    <jats:italic>via<\/jats:italic>\n                    the P-ligand cooperative function. The resting state is largely suppressed by introducing planar ligand framework with steric-demanding substituents, and thus improves the reaction efficiency.\n                  <\/jats:p>","DOI":"10.1039\/d3cp01709e","type":"journal-article","created":{"date-parts":[[2023,5,19]],"date-time":"2023-05-19T04:41:26Z","timestamp":1684471286000},"page":"18056-18061","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Metal-free catalytic hydroboration of imine with pinacolborane using a pincer-type phosphorus compound: mechanistic insight and improvement of the reaction"],"prefix":"10.1039","volume":"25","author":[{"given":"Deshuai","family":"Yang","sequence":"first","affiliation":[{"name":"Institute of Theoretical and Computational Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, People's Republic of China"},{"name":"Kuang Yaming Honors School, Nanjing University, Nanjing 210023, People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0371-6835","authenticated-orcid":false,"given":"Shuoqi","family":"Zhang","sequence":"additional","affiliation":[{"name":"Kuang Yaming Honors School, Nanjing University, Nanjing 210023, People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5519-7611","authenticated-orcid":false,"given":"Guixiang","family":"Zeng","sequence":"additional","affiliation":[{"name":"Kuang Yaming Honors School, Nanjing University, Nanjing 210023, People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5444-776X","authenticated-orcid":false,"given":"Zhao-Xu","family":"Chen","sequence":"additional","affiliation":[{"name":"Institute of Theoretical and Computational Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2023]]},"reference":[{"key":"D3CP01709E\/cit1a\/1","doi-asserted-by":"crossref","first-page":"2457","DOI":"10.1021\/cr00039a007","volume":"95","author":"Miyaura","year":"1995","journal-title":"Chem. 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