{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T06:28:25Z","timestamp":1782973705913,"version":"3.54.5"},"reference-count":48,"publisher":"Royal Society of Chemistry (RSC)","issue":"4","license":[{"start":{"date-parts":[[2024,12,22]],"date-time":"2024-12-22T00:00:00Z","timestamp":1734825600000},"content-version":"am","delay-in-days":356,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/100020201","name":"Indian Institute of Technology Palakkad","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100020201","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001409","name":"Department of Science and Technology, Ministry of Science and Technology, India","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001409","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100011652","name":"Indian Institute of Science Education and Research Mohali","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100011652","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Phys. Chem. Chem. Phys."],"abstract":"<jats:p>Planar hexazines are stabilized by coordinating Lewis acids at alternate positions. Stronger Lewis acids induce bond-equalization, whereas the weaker ones result in bond-alternation.<\/jats:p>","DOI":"10.1039\/d3cp05546a","type":"journal-article","created":{"date-parts":[[2023,12,22]],"date-time":"2023-12-22T12:21:50Z","timestamp":1703247710000},"page":"3569-3577","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Bond-alternated and bond-equalized hexazine derivatives"],"prefix":"10.1039","volume":"26","author":[{"given":"Kunnumma Chelladath","family":"Krishnapriya","sequence":"first","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology, Palakkad 678 557, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ashith","family":"Thayyil","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology, Palakkad 678 557, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mithu","family":"Kumari","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology, Palakkad 678 557, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4161-8651","authenticated-orcid":false,"given":"Priyakumari Chakkingal","family":"Parambil","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology, Palakkad 678 557, India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2024]]},"reference":[{"key":"D3CP05546A\/cit1\/1","doi-asserted-by":"crossref","first-page":"204","DOI":"10.1007\/BF01339530","volume":"70","author":"H\u00fcckel","year":"1931","journal-title":"Z. Phys."},{"key":"D3CP05546A\/cit2\/1","doi-asserted-by":"crossref","first-page":"1501","DOI":"10.1021\/cr990363l","volume":"101","author":"Shaik","year":"2001","journal-title":"Chem. Rev."},{"key":"D3CP05546A\/cit3\/1","doi-asserted-by":"crossref","first-page":"2253","DOI":"10.1063\/1.1732256","volume":"35","author":"Berry","year":"1961","journal-title":"J. Chem. Phys."},{"key":"D3CP05546A\/cit4\/1","doi-asserted-by":"crossref","first-page":"3089","DOI":"10.1021\/ja00297a013","volume":"107","author":"Shaik","year":"1985","journal-title":"J. Am. Chem. Soc."},{"key":"D3CP05546A\/cit5\/1","doi-asserted-by":"crossref","first-page":"209","DOI":"10.1071\/CH08043","volume":"61","author":"Pierrefixe","year":"2008","journal-title":"Aust. J. Chem."},{"key":"D3CP05546A\/cit6\/1","doi-asserted-by":"crossref","first-page":"6321","DOI":"10.1002\/chem.200700206","volume":"13","author":"Pierrefixe","year":"2007","journal-title":"Chem. \u2013 Eur. J."},{"key":"D3CP05546A\/cit7\/1","doi-asserted-by":"crossref","first-page":"363","DOI":"10.1021\/ja00236a013","volume":"109","author":"Shaik","year":"1987","journal-title":"J. Am. Chem. Soc."},{"key":"D3CP05546A\/cit8\/1","doi-asserted-by":"crossref","first-page":"1760","DOI":"10.1021\/ja00345a010","volume":"105","author":"Saxe","year":"1983","journal-title":"J. Am. Chem. Soc."},{"key":"D3CP05546A\/cit9\/1","doi-asserted-by":"crossref","first-page":"547","DOI":"10.1016\/0009-2614(92)85029-A","volume":"198","author":"Glukhovtsev","year":"1992","journal-title":"Chem. Phys. Lett."},{"key":"D3CP05546A\/cit10\/1","doi-asserted-by":"crossref","first-page":"4107","DOI":"10.1021\/jp003971+","volume":"105","author":"Tobita","year":"2001","journal-title":"J. Phys. Chem. A"},{"key":"D3CP05546A\/cit11\/1","doi-asserted-by":"crossref","first-page":"38","DOI":"10.1016\/j.comptc.2011.05.035","volume":"971","author":"Raczy\u0144ska","year":"2011","journal-title":"Comput. Theor. Chem."},{"key":"D3CP05546A\/cit12\/1","doi-asserted-by":"crossref","first-page":"666","DOI":"10.1021\/ja952376w","volume":"118","author":"Shaik","year":"1996","journal-title":"J. Am. Chem. Soc."},{"key":"D3CP05546A\/cit13\/1","doi-asserted-by":"crossref","first-page":"1454","DOI":"10.1002\/anie.199514541","volume":"34","author":"B\u00fcrgi","year":"1995","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"D3CP05546A\/cit14\/1","doi-asserted-by":"crossref","first-page":"2102","DOI":"10.1021\/ja00112a028","volume":"117","author":"Frank","year":"1995","journal-title":"J. Am. Chem. Soc."},{"key":"D3CP05546A\/cit15\/1","doi-asserted-by":"crossref","first-page":"9583","DOI":"10.1021\/ja00050a043","volume":"114","author":"Baldridge","year":"1992","journal-title":"J. Am. Chem. Soc."},{"key":"D3CP05546A\/cit16\/1","doi-asserted-by":"crossref","first-page":"3150","DOI":"10.1021\/ja00271a080","volume":"108","author":"Diercks","year":"1986","journal-title":"J. Am. Chem. Soc."},{"key":"D3CP05546A\/cit17\/1","doi-asserted-by":"crossref","first-page":"1478","DOI":"10.1002\/anie.199514781","volume":"34","author":"Boese","year":"1995","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"D3CP05546A\/cit18\/1","doi-asserted-by":"crossref","first-page":"266","DOI":"10.1002\/anie.198602661","volume":"25","author":"Diercks","year":"1986","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"D3CP05546A\/cit19\/1","doi-asserted-by":"crossref","first-page":"9006","DOI":"10.1021\/jo9612842","volume":"61","author":"Jemmis","year":"1996","journal-title":"J. Org. Chem."},{"key":"D3CP05546A\/cit21\/1","doi-asserted-by":"crossref","first-page":"215","DOI":"10.1007\/s00214-007-0310-x","volume":"120","author":"Zhao","year":"2008","journal-title":"Theor. Chem. Acc."},{"key":"D3CP05546A\/cit22\/1","doi-asserted-by":"crossref","first-page":"2571","DOI":"10.1063\/1.463096","volume":"97","author":"Sch\u00e4fer","year":"1992","journal-title":"J. Chem. Phys."},{"key":"D3CP05546A\/cit23\/1","doi-asserted-by":"crossref","first-page":"5829","DOI":"10.1063\/1.467146","volume":"100","author":"Sch\u00e4fer","year":"1994","journal-title":"J. Chem. Phys."},{"key":"D3CP05546A\/cit24\/1","doi-asserted-by":"crossref","first-page":"154104","DOI":"10.1063\/1.3382344","volume":"132","author":"Grimme","year":"2010","journal-title":"J. Chem. Phys."},{"key":"D3CP05546A\/cit25\/1","doi-asserted-by":"crossref","first-page":"6615","DOI":"10.1039\/b810189b","volume":"10","author":"Chai","year":"2008","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D3CP05546A\/cit26\/1","doi-asserted-by":"crossref","first-page":"5648","DOI":"10.1063\/1.464913","volume":"98","author":"Becke","year":"1993","journal-title":"J. Chem. Phys."},{"key":"D3CP05546A\/cit27\/1","doi-asserted-by":"crossref","first-page":"6158","DOI":"10.1063\/1.478522","volume":"110","author":"Adamo","year":"1999","journal-title":"J. Chem. Phys."},{"key":"D3CP05546A\/cit28\/1","doi-asserted-by":"crossref","first-page":"146401","DOI":"10.1103\/PhysRevLett.91.146401","volume":"91","author":"Tao","year":"2003","journal-title":"Phys. Rev. Lett."},{"key":"D3CP05546A\/cit29\/1","doi-asserted-by":"crossref","first-page":"4814","DOI":"10.1021\/acs.jcim.9b00725","volume":"59","author":"Pritchard","year":"2019","journal-title":"J. Chem. Inf. Model."},{"key":"D3CP05546A\/cit30\/1","volume-title":"Gaussian NBO Version 3.1","author":"Glendening","year":"2001","unstructured":"E. D.Glendening ,  A. E.Reed ,  J. E.Carpenter  and  F.Weinhold ,  Gaussian NBO Version 3.1 ,  Gaussian Inc .,  Pittsburgh PA ,  2001"},{"key":"D3CP05546A\/cit31\/1","doi-asserted-by":"crossref","first-page":"3842","DOI":"10.1021\/cr030088+","volume":"105","author":"Chen","year":"2005","journal-title":"Chem. Rev."},{"key":"D3CP05546A\/cit32\/1","doi-asserted-by":"crossref","first-page":"6317","DOI":"10.1021\/ja960582d","volume":"118","author":"Schleyer","year":"1996","journal-title":"J. Am. Chem. Soc."},{"key":"D3CP05546A\/cit34\/1","doi-asserted-by":"crossref","first-page":"2951","DOI":"10.1021\/acs.organomet.0c00449","volume":"39","author":"Parambil","year":"2020","journal-title":"Organometallics"},{"key":"D3CP05546A\/cit35\/1","doi-asserted-by":"crossref","first-page":"38","DOI":"10.1016\/j.comptc.2011.05.035","volume":"971","author":"Raczy\u0144ska","year":"2011","journal-title":"Comput. Theor. Chem."},{"key":"D3CP05546A\/cit36\/1","doi-asserted-by":"crossref","first-page":"7693","DOI":"10.1021\/jp010783q","volume":"105","author":"Wilson","year":"2001","journal-title":"J. Phys. Chem. A"},{"key":"D3CP05546A\/cit37\/1","doi-asserted-by":"crossref","first-page":"11800","DOI":"10.1002\/chem.201402921","volume":"20","author":"Reii\u00df","year":"2014","journal-title":"Chem. \u2013 Eur. J."},{"key":"D3CP05546A\/cit38\/1","first-page":"47","volume-title":"Pauling's Legacy","author":"Maksi\u0107","year":"1999","unstructured":"Z. B.Maksi\u0107 ,  M.Eckert-Maksi\u0107 ,  O.M\u00f3  and  M.Y\u00e1\u00f1ez , in  Pauling's Legacy , ed.  Z. Maksi\u0107  and  W. Orville-Thomas ,  Elsevier ,  1999 , vol. 6,  pp. 47\u2013101"},{"key":"D3CP05546A\/cit39\/1","doi-asserted-by":"crossref","first-page":"2510","DOI":"10.1039\/JR9300002510","author":"Mills","year":"1930","journal-title":"J. Chem. Soc."},{"key":"D3CP05546A\/cit40\/1","doi-asserted-by":"crossref","first-page":"1197","DOI":"10.1038\/s41467-018-02998-3","volume":"9","author":"B\u00f6hnke","year":"2018","journal-title":"Nat. Commun."},{"key":"D3CP05546A\/cit41\/1","doi-asserted-by":"crossref","first-page":"4963","DOI":"10.1002\/ejoc.201700750","author":"Voronin","year":"2017","journal-title":"Eur. J. Org. Chem."},{"key":"D3CP05546A\/cit42\/1","first-page":"1","volume-title":"J. Phys. Chem. Ref. Data, Monograph 9","author":"Chase, Jr.","year":"1998","unstructured":"M. W.Chase, Jr. ,  NIST-JANAF Thermochemical Tables , Fourth Edition,  J. Phys. Chem. Ref. Data, Monograph 9 ,  1998 ,  11951"},{"key":"D3CP05546A\/cit43\/1","doi-asserted-by":"crossref","first-page":"2837","DOI":"10.1021\/ja00296a002","volume":"107","author":"Bach","year":"1985","journal-title":"J. Am. Chem. Soc."},{"key":"D3CP05546A\/cit44\/1","doi-asserted-by":"crossref","first-page":"781","DOI":"10.1002\/anie.196907811","volume":"8","author":"Woodward","year":"1969","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"D3CP05546A\/cit45\/1","doi-asserted-by":"crossref","first-page":"641","DOI":"10.1038\/s41557-023-01148-7","volume":"15","author":"Laniel","year":"2023","journal-title":"Nat. Chem."},{"key":"D3CP05546A\/cit46\/1","doi-asserted-by":"crossref","first-page":"13446","DOI":"10.1039\/C8RA01263F","volume":"8","author":"B\u00e1ez-Grez","year":"2018","journal-title":"RSC Adv."},{"key":"D3CP05546A\/cit47\/1","doi-asserted-by":"crossref","first-page":"11240","DOI":"10.1039\/D1CP00784J","volume":"23","author":"Radenkovi\u0107","year":"2021","journal-title":"Phys. Chem. Chem. Phys"},{"key":"D3CP05546A\/cit48\/1","doi-asserted-by":"crossref","first-page":"S68","DOI":"10.1002\/mrc.1445","volume":"42","author":"Fowler","year":"2004","journal-title":"Magn. Reson. Chem."},{"key":"D3CP05546A\/cit49\/1","doi-asserted-by":"crossref","first-page":"9553","DOI":"10.1021\/jp011955m","volume":"105","author":"Steiner","year":"2001","journal-title":"J. Phys. Chem. A"},{"key":"D3CP05546A\/cit50\/1","doi-asserted-by":"crossref","first-page":"6597","DOI":"10.1039\/C5CS00114E","volume":"44","author":"Gershoni-Poranne","year":"2015","journal-title":"Chem. Soc. Rev."}],"container-title":["Physical Chemistry Chemical Physics"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2024\/CP\/D3CP05546A","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T05:05:29Z","timestamp":1782968729000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/cp\/article\/26\/4\/3569-3577\/803181"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024]]},"references-count":48,"journal-issue":{"issue":"4","published-print":{"date-parts":[[2024,1,24]]}},"URL":"https:\/\/doi.org\/10.1039\/d3cp05546a","relation":{},"ISSN":["1463-9076","1463-9084"],"issn-type":[{"value":"1463-9076","type":"print"},{"value":"1463-9084","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024]]}}}