{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T19:15:18Z","timestamp":1783451718011,"version":"3.55.0"},"reference-count":76,"publisher":"Royal Society of Chemistry (RSC)","issue":"7","license":[{"start":{"date-parts":[[2025,1,9]],"date-time":"2025-01-09T00:00:00Z","timestamp":1736380800000},"content-version":"am","delay-in-days":374,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/100019497","name":"Indian Institute of Technology Jodhpur","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100019497","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001412","name":"Council of Scientific and Industrial Research, India","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001412","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001409","name":"Department of Science & Technology, Ministry of Science and Technology, India","doi-asserted-by":"publisher","award":["SR\/FST\/CS-II\/2019\/119(C)"],"award-info":[{"award-number":["SR\/FST\/CS-II\/2019\/119(C)"]}],"id":[{"id":"10.13039\/501100001409","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001843","name":"Science and Engineering Research Board","doi-asserted-by":"publisher","award":["SRG\/2020\/001047"],"award-info":[{"award-number":["SRG\/2020\/001047"]}],"id":[{"id":"10.13039\/501100001843","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<jats:p>\n                    A quinoline-based pincer Mn catalyst for \u03b1-alkylation of methyl ketones using primary alcohols as alkyl surrogates is presented. The C\u2013C bond formation reaction proceeds\n                    <jats:italic>via<\/jats:italic>\n                    a hydrogen auto-transfer protocol, generating water as the only by-product.\n                  <\/jats:p>","DOI":"10.1039\/d3dt04321e","type":"journal-article","created":{"date-parts":[[2024,1,9]],"date-time":"2024-01-09T04:41:41Z","timestamp":1704775301000},"page":"3236-3243","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["NNN manganese complex-catalyzed \u03b1-alkylation of methyl ketones using alcohols: an experimental and computational study"],"prefix":"10.1039","volume":"53","author":[{"given":"Sachin","family":"Jalwal","sequence":"first","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology Jodhpur, Karwar, Jodhpur, 342030, Rajasthan, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anitta","family":"Regina","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology Jodhpur, Karwar, Jodhpur, 342030, Rajasthan, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vaishnavi","family":"Atreya","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology Jodhpur, Karwar, Jodhpur, 342030, Rajasthan, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4126-6206","authenticated-orcid":false,"given":"Manikandan","family":"Paranjothy","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology Jodhpur, Karwar, Jodhpur, 342030, Rajasthan, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0174-2095","authenticated-orcid":false,"given":"Subrata","family":"Chakraborty","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology Jodhpur, Karwar, Jodhpur, 342030, Rajasthan, India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2024]]},"reference":[{"key":"D3DT04321E\/cit1a\/1","doi-asserted-by":"crossref","first-page":"753","DOI":"10.1039\/B813383B","author":"Nixon","year":"2009","journal-title":"Dalton Trans."},{"key":"D3DT04321E\/cit1b\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.ccr.2016.10.002","volume":"331","author":"Chelucci","year":"2017","journal-title":"Coord. Chem. Rev."},{"key":"D3DT04321E\/cit1c\/1","doi-asserted-by":"crossref","first-page":"259","DOI":"10.1002\/anie.199502591","volume":"34","author":"Trost","year":"1995","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"D3DT04321E\/cit2a\/1","doi-asserted-by":"crossref","first-page":"96","DOI":"10.1002\/anie.198200961","volume":"21","author":"Reetz","year":"1982","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"D3DT04321E\/cit2b\/1","doi-asserted-by":"crossref","first-page":"1215","DOI":"10.1021\/cr100280d","volume":"111","author":"Yeung","year":"2011","journal-title":"Chem. Rev."},{"key":"D3DT04321E\/cit3\/1","doi-asserted-by":"crossref","first-page":"862","DOI":"10.1002\/anie.201507521","volume":"55","author":"Huang","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"D3DT04321E\/cit4a\/1","doi-asserted-by":"crossref","first-page":"11","DOI":"10.1007\/s41061-016-0012-8","volume":"374","author":"Obora","year":"2016","journal-title":"Top. Curr. Chem."},{"key":"D3DT04321E\/cit4b\/1","doi-asserted-by":"crossref","first-page":"3972","DOI":"10.1021\/cs501269d","volume":"4","author":"Obora","year":"2014","journal-title":"ACS Catal."},{"key":"D3DT04321E\/cit5a\/1","doi-asserted-by":"crossref","first-page":"1555","DOI":"10.1002\/adsc.200600638","volume":"349","author":"Hamid","year":"2007","journal-title":"Adv. Synth. Catal."},{"key":"D3DT04321E\/cit5b\/1","doi-asserted-by":"crossref","first-page":"681","DOI":"10.1021\/cr900202j","volume":"110","author":"Dobereiner","year":"2010","journal-title":"Chem. Rev."},{"key":"D3DT04321E\/cit6a\/1","doi-asserted-by":"crossref","first-page":"1229712","DOI":"10.1126\/science.1229712","volume":"341","author":"Gunanathan","year":"2013","journal-title":"Science"},{"key":"D3DT04321E\/cit6b\/1","doi-asserted-by":"crossref","first-page":"570","DOI":"10.1021\/acscentsci.1c00125","volume":"7","author":"Reed-Berendt","year":"2021","journal-title":"ACS Cent. Sci."},{"key":"D3DT04321E\/cit6c\/1","doi-asserted-by":"crossref","first-page":"635","DOI":"10.1126\/science.1191843","volume":"329","author":"Watson","year":"2010","journal-title":"Science"},{"key":"D3DT04321E\/cit7a\/1","doi-asserted-by":"crossref","first-page":"3100","DOI":"10.1002\/adsc.202200474","volume":"364","author":"Yang","year":"2022","journal-title":"Adv. Synth. Catal."},{"key":"D3DT04321E\/cit7b\/1","doi-asserted-by":"crossref","first-page":"7998","DOI":"10.1039\/D2OB01323A","volume":"20","author":"Sharma","year":"2022","journal-title":"Org. Biomol. Chem."},{"key":"D3DT04321E\/cit7c\/1","doi-asserted-by":"crossref","first-page":"464","DOI":"10.1002\/ajoc.202000634","volume":"10","author":"Donthireddy","year":"2021","journal-title":"Asian J. Org. Chem."},{"key":"D3DT04321E\/cit8a\/1","doi-asserted-by":"crossref","first-page":"2495","DOI":"10.1021\/acs.accounts.5b00385","volume":"48","author":"Chirik","year":"2015","journal-title":"Acc. Chem. Res."},{"key":"D3DT04321E\/cit8b\/1","doi-asserted-by":"crossref","first-page":"5619","DOI":"10.1021\/om5010379","volume":"33","author":"Albrecht","year":"2014","journal-title":"Organometallics"},{"key":"D3DT04321E\/cit9a\/1","doi-asserted-by":"crossref","first-page":"1459","DOI":"10.1039\/C7CS00334J","volume":"47","author":"Filonenko","year":"2018","journal-title":"Chem. Soc. Rev."},{"key":"D3DT04321E\/cit9b\/1","doi-asserted-by":"crossref","first-page":"2524","DOI":"10.1021\/acs.chemrev.8b00306","volume":"119","author":"Irrgang","year":"2018","journal-title":"Chem. Rev."},{"key":"D3DT04321E\/cit9c\/1","doi-asserted-by":"crossref","first-page":"2681","DOI":"10.1021\/acs.chemrev.8b00555","volume":"119","author":"Alig","year":"2018","journal-title":"Chem. Rev."},{"key":"D3DT04321E\/cit9d\/1","doi-asserted-by":"crossref","first-page":"1595","DOI":"10.1039\/C8OB01895B","volume":"17","author":"Reed-Berendt","year":"2019","journal-title":"Org. Biomol. Chem."},{"key":"D3DT04321E\/cit9e\/1","doi-asserted-by":"crossref","first-page":"132451","DOI":"10.1016\/j.tet.2021.132451","volume":"99","author":"Ding","year":"2021","journal-title":"Tetrahedron"},{"key":"D3DT04321E\/cit9f\/1","doi-asserted-by":"crossref","first-page":"11435","DOI":"10.1021\/acscatal.8b02869","volume":"8","author":"Mukherjee","year":"2018","journal-title":"ACS Catal."},{"key":"D3DT04321E\/cit9g\/1","doi-asserted-by":"crossref","first-page":"1979","DOI":"10.1021\/acs.accounts.5b00027","volume":"48","author":"Zell","year":"2015","journal-title":"Acc. Chem. Res."},{"key":"D3DT04321E\/cit10a\/1","doi-asserted-by":"crossref","first-page":"14483","DOI":"10.1002\/anie.201506698","volume":"48","author":"Elangovan","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"D3DT04321E\/cit10b\/1","doi-asserted-by":"crossref","first-page":"2064","DOI":"10.1021\/acs.orglett.0c00549","volume":"22","author":"Bettoni","year":"2020","journal-title":"Org. Lett."},{"key":"D3DT04321E\/cit10c\/1","doi-asserted-by":"crossref","first-page":"4410","DOI":"10.1002\/cctc.201701241","volume":"23","author":"Seck","year":"2017","journal-title":"ChemCatChem"},{"key":"D3DT04321E\/cit10d\/1","doi-asserted-by":"crossref","first-page":"5584","DOI":"10.1021\/acs.orglett.2c02233","volume":"30","author":"Abdallah","year":"2022","journal-title":"Org. Lett."},{"key":"D3DT04321E\/cit11a\/1","doi-asserted-by":"crossref","first-page":"1080","DOI":"10.1021\/acs.orglett.7b00106","volume":"5","author":"Zhang","year":"2017","journal-title":"Org. Lett."},{"key":"D3DT04321E\/cit11b\/1","doi-asserted-by":"crossref","first-page":"3463","DOI":"10.1002\/cssc.201900990","volume":"15","author":"Chakraborty","year":"2019","journal-title":"ChemSusChem"},{"key":"D3DT04321E\/cit12a\/1","doi-asserted-by":"crossref","first-page":"3911","DOI":"10.1002\/cssc.201801443","volume":"22","author":"Midya","year":"2018","journal-title":"ChemSusChem"},{"key":"D3DT04321E\/cit12b\/1","doi-asserted-by":"crossref","first-page":"e6493","DOI":"10.1002\/aoc.6493","volume":"2","author":"Wu","year":"2022","journal-title":"Appl. Organomet. Chem."},{"key":"D3DT04321E\/cit12c\/1","doi-asserted-by":"crossref","first-page":"9753","DOI":"10.1039\/D2OB01787C","volume":"48","author":"Gen\u00e7","year":"2022","journal-title":"Org. Biomol. Chem."},{"key":"D3DT04321E\/cit13a\/1","doi-asserted-by":"crossref","first-page":"46","DOI":"10.1002\/anie.201709010","volume":"57","author":"Kallmeier","year":"2018","journal-title":"Angew. Chem., Int. Ed."},{"key":"D3DT04321E\/cit13b\/1","doi-asserted-by":"crossref","first-page":"4344","DOI":"10.1002\/ejoc.201700376","author":"Garbe","year":"2017","journal-title":"Eur. J. Org. Chem."},{"key":"D3DT04321E\/cit13c\/1","doi-asserted-by":"crossref","first-page":"1930","DOI":"10.1002\/cctc.201701722","volume":"10","author":"Zell","year":"2018","journal-title":"ChemCatChem"},{"key":"D3DT04321E\/cit13d\/1","first-page":"3377","author":"Maji","year":"2017","journal-title":"Synthesis"},{"key":"D3DT04321E\/cit13e\/1","doi-asserted-by":"crossref","first-page":"213241","DOI":"10.1016\/j.ccr.2020.213241","volume":"411","author":"Chandra","year":"2020","journal-title":"Coord. Chem. Rev."},{"key":"D3DT04321E\/cit14a\/1","doi-asserted-by":"crossref","first-page":"1180","DOI":"10.1016\/j.chempr.2020.11.013","volume":"7","author":"Wang","year":"2021","journal-title":"Chem"},{"key":"D3DT04321E\/cit14b\/1","doi-asserted-by":"crossref","first-page":"1958","DOI":"10.1002\/ajoc.202100249","volume":"10","author":"Nad","year":"2021","journal-title":"Asian J. Org. Chem."},{"key":"D3DT04321E\/cit14c\/1","doi-asserted-by":"crossref","first-page":"4386","DOI":"10.1039\/D2CS00093H","volume":"51","author":"Das","year":"2022","journal-title":"Chem. Soc. Rev."},{"key":"D3DT04321E\/cit15a\/1","doi-asserted-by":"crossref","first-page":"7261","DOI":"10.1002\/anie.201702543","volume":"56","author":"Kallmeier","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"D3DT04321E\/cit15b\/1","doi-asserted-by":"crossref","first-page":"8812","DOI":"10.1021\/jacs.7b05253","volume":"139","author":"Mastalir","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"D3DT04321E\/cit15c\/1","doi-asserted-by":"crossref","first-page":"3099","DOI":"10.1002\/cssc.201801660","volume":"12","author":"El-Sepelgy","year":"2019","journal-title":"ChemSusChem"},{"key":"D3DT04321E\/cit15d\/1","doi-asserted-by":"crossref","first-page":"7779","DOI":"10.1021\/acs.orglett.8b03184","volume":"20","author":"Jang","year":"2018","journal-title":"Org. Lett."},{"key":"D3DT04321E\/cit15e\/1","doi-asserted-by":"crossref","first-page":"1485","DOI":"10.1002\/anie.201912055","volume":"59","author":"Schlagbauer","year":"2020","journal-title":"Angew. Chem., Int. Ed."},{"key":"D3DT04321E\/cit15f\/1","doi-asserted-by":"crossref","first-page":"215","DOI":"10.1002\/anie.201909035","volume":"59","author":"Kaithal","year":"2020","journal-title":"Angew. Chem., Int. Ed."},{"key":"D3DT04321E\/cit15g\/1","doi-asserted-by":"crossref","first-page":"3026","DOI":"10.1039\/D1CC00181G","volume":"57","author":"Jana","year":"2021","journal-title":"Chem. Commun."},{"key":"D3DT04321E\/cit15h\/1","doi-asserted-by":"crossref","first-page":"785","DOI":"10.1002\/ange.201810885","volume":"3","author":"Sklyaruk","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"D3DT04321E\/cit15i\/1","doi-asserted-by":"crossref","first-page":"314","DOI":"10.1039\/C8CC08064J","volume":"3","author":"Bruneau-Voisine","year":"2019","journal-title":"Chem. Commun."},{"key":"D3DT04321E\/cit15j\/1","doi-asserted-by":"crossref","first-page":"9226","DOI":"10.1021\/acscatal.8b02998","volume":"10","author":"Jana","year":"2018","journal-title":"ACS Catal."},{"key":"D3DT04321E\/cit16\/1","doi-asserted-by":"crossref","first-page":"14967","DOI":"10.1002\/anie.201607072","volume":"55","author":"Pe\u00f1a-L\u00f3pez","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"D3DT04321E\/cit17\/1","doi-asserted-by":"crossref","first-page":"10300","DOI":"10.1021\/acscatal.8b03720","volume":"8","author":"Chakraborty","year":"2018","journal-title":"ACS Catal."},{"key":"D3DT04321E\/cit18a\/1","doi-asserted-by":"crossref","first-page":"17487","DOI":"10.1021\/jacs.9b08832","volume":"141","author":"Kaithal","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"D3DT04321E\/cit18b\/1","doi-asserted-by":"crossref","first-page":"2615","DOI":"10.1021\/acscatal.9b05567","volume":"10","author":"Jana","year":"2020","journal-title":"ACS Catal."},{"key":"D3DT04321E\/cit19a\/1","doi-asserted-by":"crossref","first-page":"8065","DOI":"10.1021\/acs.orglett.9b03030","volume":"21","author":"Lan","year":"2019","journal-title":"Org. Lett."},{"key":"D3DT04321E\/cit19b\/1","doi-asserted-by":"crossref","first-page":"12444","DOI":"10.1021\/acscatal.2c04131","volume":"12","author":"Ganguli","year":"2022","journal-title":"ACS Catal."},{"key":"D3DT04321E\/cit19c\/1","doi-asserted-by":"crossref","first-page":"10741","DOI":"10.1021\/acsomega.9b01246","volume":"4","author":"Gawali","year":"2019","journal-title":"ACS Omega"},{"key":"D3DT04321E\/cit20a\/1","doi-asserted-by":"crossref","first-page":"3233","DOI":"10.1002\/adsc.201800380","volume":"360","author":"Barman","year":"2018","journal-title":"Adv. Synth. Catal."},{"key":"D3DT04321E\/cit20b\/1","doi-asserted-by":"crossref","first-page":"10363","DOI":"10.1039\/D1CC03529K","volume":"57","author":"Mondal","year":"2021","journal-title":"Chem. Commun."},{"key":"D3DT04321E\/cit21a\/1","doi-asserted-by":"crossref","first-page":"e202201148","DOI":"10.1002\/asia.202201148","volume":"18","author":"Saini","year":"2023","journal-title":"Chem. \u2013 Asian J."},{"key":"D3DT04321E\/cit21b\/1","doi-asserted-by":"crossref","first-page":"4753","DOI":"10.1039\/D2CY00759B","volume":"12","author":"Narjinari","year":"2022","journal-title":"Catal. Sci. Technol."},{"key":"D3DT04321E\/cit21c\/1","doi-asserted-by":"crossref","first-page":"1818","DOI":"10.1021\/acs.organomet.3c00132","volume":"42","author":"Bisarya","year":"2023","journal-title":"Organometallics"},{"key":"D3DT04321E\/cit21d\/1","doi-asserted-by":"crossref","first-page":"627","DOI":"10.1021\/acs.organomet.1c00009","volume":"40","author":"Rana","year":"2021","journal-title":"Organometallics"},{"key":"D3DT04321E\/cit22a\/1","doi-asserted-by":"crossref","first-page":"1814","DOI":"10.1002\/anie.200704654","volume":"47","author":"Gr\u00fctzmacher","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"D3DT04321E\/cit22b\/1","doi-asserted-by":"crossref","first-page":"12236","DOI":"10.1002\/anie.201503873","volume":"54","author":"Khusnutdinova","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"D3DT04321E\/cit22c\/1","doi-asserted-by":"crossref","first-page":"8933","DOI":"10.1039\/D0CS00509F","volume":"49","author":"Elsby","year":"2020","journal-title":"Chem. Soc. Rev."},{"key":"D3DT04321E\/cit22d\/1","doi-asserted-by":"crossref","first-page":"1881","DOI":"10.1039\/D1CS01171E","volume":"51","author":"Stevens","year":"2022","journal-title":"Chem. Soc. Rev."},{"key":"D3DT04321E\/cit22e\/1","doi-asserted-by":"crossref","first-page":"588","DOI":"10.1021\/ar2000265","volume":"44","author":"Gunanathan","year":"2011","journal-title":"Acc. Chem. Res."},{"key":"D3DT04321E\/cit23\/1","doi-asserted-by":"crossref","first-page":"2760","DOI":"10.1039\/C8DT04564J","volume":"48","author":"Maiti","year":"2019","journal-title":"Dalton Trans."},{"key":"D3DT04321E\/cit24\/1","doi-asserted-by":"crossref","first-page":"479","DOI":"10.1021\/acscatal.8b04585","volume":"9","author":"Das","year":"2019","journal-title":"ACS Catal."},{"key":"D3DT04321E\/cit25\/1","doi-asserted-by":"crossref","first-page":"224108","DOI":"10.1063\/5.0004608","volume":"152","author":"Neese","year":"2020","journal-title":"J. Chem. Phys."},{"key":"D3DT04321E\/cit26\/1","doi-asserted-by":"crossref","first-page":"869","DOI":"10.1021\/acs.orglett.0c04098","volume":"23","author":"Bhattacharyya","year":"2021","journal-title":"Org. Lett."},{"key":"D3DT04321E\/cit27a\/1","doi-asserted-by":"crossref","first-page":"e202300183","DOI":"10.1002\/ejic.202300183","volume":"26","author":"Zhang","year":"2023","journal-title":"Eur. J. Inorg. Chem."},{"key":"D3DT04321E\/cit27b\/1","doi-asserted-by":"crossref","first-page":"6908","DOI":"10.1073\/pnas.0610747104","volume":"104","author":"Brookhart","year":"2007","journal-title":"Proc. Natl. Acad. Sci. U. S. A."}],"container-title":["Dalton Transactions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2024\/DT\/D3DT04321E","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T18:14:24Z","timestamp":1783448064000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/dt\/article\/53\/7\/3236-3243\/806955"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024]]},"references-count":76,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2024,2,13]]}},"URL":"https:\/\/doi.org\/10.1039\/d3dt04321e","relation":{},"ISSN":["1477-9226","1477-9234"],"issn-type":[{"value":"1477-9226","type":"print"},{"value":"1477-9234","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024]]}}}