{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T20:12:29Z","timestamp":1791576749264,"version":"4.3.4"},"reference-count":69,"publisher":"Royal Society of Chemistry (RSC)","issue":"41","license":[{"start":{"date-parts":[[2024,10,9]],"date-time":"2024-10-09T00:00:00Z","timestamp":1728432000000},"content-version":"am","delay-in-days":647,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100001843","name":"Science and Engineering Research Board","doi-asserted-by":"publisher","award":["CRG\/2020\/003471"],"award-info":[{"award-number":["CRG\/2020\/003471"]}],"id":[{"id":"10.13039\/501100001843","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100019126","name":"Gujarat Council on Science and Technology","doi-asserted-by":"publisher","award":["GUJCOST\/2020-21\/872"],"award-info":[{"award-number":["GUJCOST\/2020-21\/872"]}],"id":[{"id":"10.13039\/100019126","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Nanoscale"],"abstract":"<jats:p>We demonstrate that some organic ligands can provide electron transport channels that facilitate hot electron extraction from a gold nanostructure leading to a huge enhancement in the rate of photocatalytic hydrogen evolution reaction.<\/jats:p>","DOI":"10.1039\/d3nr02829a","type":"journal-article","created":{"date-parts":[[2023,10,9]],"date-time":"2023-10-09T07:30:30Z","timestamp":1696836630000},"page":"16552-16560","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Ligand-mediated electron transport channels enhance photocatalytic activity of plasmonic nanoparticles"],"prefix":"10.1039","volume":"15","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-0898-2956","authenticated-orcid":false,"given":"Gayatri","family":"Joshi","sequence":"first","affiliation":[{"name":"Chemistry Discipline, Indian Institute of Technology Gandhinagar, Palaj, Gujarat-382055, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rajesh","family":"Kashyap","sequence":"additional","affiliation":[{"name":"Chemistry Discipline, Indian Institute of Technology Gandhinagar, Palaj, Gujarat-382055, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2709-3377","authenticated-orcid":false,"given":"Kalyani","family":"Patrikar","sequence":"additional","affiliation":[{"name":"Chemistry Discipline, Indian Institute of Technology Gandhinagar, Palaj, Gujarat-382055, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3029-8840","authenticated-orcid":false,"given":"Anirban","family":"Mondal","sequence":"additional","affiliation":[{"name":"Chemistry Discipline, Indian Institute of Technology Gandhinagar, Palaj, Gujarat-382055, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8088-2132","authenticated-orcid":false,"given":"Saumyakanti","family":"Khatua","sequence":"additional","affiliation":[{"name":"Chemistry Discipline, Indian Institute of Technology Gandhinagar, Palaj, Gujarat-382055, India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2023]]},"reference":[{"key":"D3NR02829A\/cit1\/1","doi-asserted-by":"crossref","first-page":"247","DOI":"10.1038\/nnano.2013.18","volume":"8","author":"Mubeen","year":"2013","journal-title":"Nat. Nanotechnol."},{"key":"D3NR02829A\/cit2\/1","doi-asserted-by":"crossref","first-page":"232","DOI":"10.1038\/s41467-017-02676-w","volume":"9","author":"Chen","year":"2018","journal-title":"Nat. Commun."},{"key":"D3NR02829A\/cit3\/1","doi-asserted-by":"crossref","first-page":"38815","DOI":"10.1021\/acsami.2c10152","volume":"14","author":"Joshi","year":"2022","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"D3NR02829A\/cit4\/1","doi-asserted-by":"crossref","first-page":"084701","DOI":"10.1063\/5.0097713","volume":"157","author":"Kim","year":"2022","journal-title":"J. Chem. Phys."},{"key":"D3NR02829A\/cit5\/1","doi-asserted-by":"crossref","first-page":"2200463","DOI":"10.1002\/adom.202200463","volume":"10","author":"Jain","year":"2022","journal-title":"Adv. Opt. Mater."},{"key":"D3NR02829A\/cit6\/1","doi-asserted-by":"crossref","first-page":"116","DOI":"10.1021\/cs400993w","volume":"4","author":"Kale","year":"2014","journal-title":"ACS Catal."},{"key":"D3NR02829A\/cit7\/1","doi-asserted-by":"crossref","first-page":"4704","DOI":"10.1021\/acsnano.6b01108","volume":"10","author":"Ng","year":"2016","journal-title":"ACS Nano"},{"key":"D3NR02829A\/cit8\/1","doi-asserted-by":"crossref","first-page":"379","DOI":"10.1146\/annurev-physchem-052516-044948","volume":"68","author":"Christopher","year":"2017","journal-title":"Annu. Rev. Phys. Chem."},{"key":"D3NR02829A\/cit9\/1","doi-asserted-by":"crossref","first-page":"25","DOI":"10.1038\/nnano.2014.311","volume":"10","author":"Brongersma","year":"2015","journal-title":"Nat. Nanotechnol."},{"key":"D3NR02829A\/cit10\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1038\/s41467-016-0009-6","volume":"8","author":"Cort\u00e9s","year":"2017","journal-title":"Nat. Commun."},{"key":"D3NR02829A\/cit11\/1","doi-asserted-by":"crossref","first-page":"5795","DOI":"10.1021\/acsanm.9b01258","volume":"2","author":"Ghosh","year":"2019","journal-title":"ACS Appl. Nano Mater."},{"key":"D3NR02829A\/cit12\/1","doi-asserted-by":"crossref","first-page":"64","DOI":"10.1021\/ja411017b","volume":"136","author":"Mukherjee","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"D3NR02829A\/cit13\/1","doi-asserted-by":"crossref","first-page":"542","DOI":"10.1021\/acsenergylett.8b02209","volume":"4","author":"Takata","year":"2019","journal-title":"ACS Energy Lett."},{"key":"D3NR02829A\/cit14\/1","doi-asserted-by":"crossref","first-page":"567","DOI":"10.1038\/nmat4281","volume":"14","author":"Linic","year":"2015","journal-title":"Nat. Mater."},{"key":"D3NR02829A\/cit15\/1","doi-asserted-by":"crossref","first-page":"1052","DOI":"10.1021\/acscatal.1c05245","author":"Joshi","year":"2022","journal-title":"ACS Catal."},{"key":"D3NR02829A\/cit16\/1","doi-asserted-by":"crossref","first-page":"2428","DOI":"10.1021\/acsenergylett.9b01683","volume":"4","author":"Mir","year":"2019","journal-title":"ACS Energy Lett."},{"key":"D3NR02829A\/cit17\/1","doi-asserted-by":"crossref","first-page":"1000","DOI":"10.1038\/nnano.2017.131","volume":"12","author":"Aslam","year":"2017","journal-title":"Nat. Nanotechnol."},{"key":"D3NR02829A\/cit18\/1","doi-asserted-by":"crossref","first-page":"16202","DOI":"10.1021\/acsnano.0c08773","volume":"14","author":"Cort\u00e9s","year":"2020","journal-title":"ACS Nano"},{"key":"D3NR02829A\/cit19\/1","doi-asserted-by":"crossref","first-page":"6689","DOI":"10.1002\/anie.201300239","volume":"52","author":"Liu","year":"2013","journal-title":"Angew. Chem., Int. Ed."},{"key":"D3NR02829A\/cit20\/1","doi-asserted-by":"crossref","first-page":"469","DOI":"10.1016\/j.nanoen.2017.02.006","volume":"33","author":"Yu","year":"2017","journal-title":"Nano Energy"},{"key":"D3NR02829A\/cit21\/1","doi-asserted-by":"crossref","first-page":"1771","DOI":"10.1007\/s10562-015-1568-6","volume":"145","author":"Yang","year":"2015","journal-title":"Catal. Lett."},{"key":"D3NR02829A\/cit22\/1","doi-asserted-by":"crossref","first-page":"1333","DOI":"10.1021\/acsenergylett.1c00366","volume":"6","author":"Song","year":"2021","journal-title":"ACS Energy Lett."},{"key":"D3NR02829A\/cit23\/1","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1016\/j.jmat.2016.11.005","volume":"3","author":"Zhang","year":"2017","journal-title":"J. Materiomics"},{"key":"D3NR02829A\/cit24\/1","doi-asserted-by":"crossref","first-page":"9361","DOI":"10.1021\/jacs.6b04175","volume":"138","author":"Hao","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"D3NR02829A\/cit25\/1","doi-asserted-by":"crossref","first-page":"5202","DOI":"10.1021\/ja200086g","volume":"133","author":"Ingram","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"D3NR02829A\/cit26\/1","doi-asserted-by":"crossref","first-page":"7630","DOI":"10.1021\/nn502445f","volume":"8","author":"Manjavacas","year":"2014","journal-title":"ACS Nano"},{"key":"D3NR02829A\/cit27\/1","doi-asserted-by":"crossref","first-page":"210","DOI":"10.1021\/jp1074048","volume":"115","author":"Chen","year":"2011","journal-title":"J. Phys. Chem. C"},{"key":"D3NR02829A\/cit28\/1","doi-asserted-by":"crossref","first-page":"9173","DOI":"10.1021\/jp101633u","volume":"114","author":"Christopher","year":"2010","journal-title":"J. Phys. Chem. C"},{"key":"D3NR02829A\/cit29\/1","doi-asserted-by":"crossref","first-page":"53","DOI":"10.1016\/j.jmst.2021.11.067","volume":"119","author":"Guo","year":"2022","journal-title":"J. Mater. Sci. Technol."},{"key":"D3NR02829A\/cit30\/1","doi-asserted-by":"crossref","first-page":"95","DOI":"10.1038\/nphoton.2013.238","volume":"8","author":"Clavero","year":"2014","journal-title":"Nat. Photonics"},{"key":"D3NR02829A\/cit31\/1","doi-asserted-by":"crossref","first-page":"6870","DOI":"10.1021\/ja502704n","volume":"136","author":"Zheng","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"D3NR02829A\/cit32\/1","doi-asserted-by":"crossref","first-page":"3881","DOI":"10.1021\/acsenergylett.0c02110","volume":"5","author":"Lee","year":"2020","journal-title":"ACS Energy Lett."},{"key":"D3NR02829A\/cit33\/1","doi-asserted-by":"crossref","first-page":"27","DOI":"10.1038\/s41467-017-00055-z","volume":"8","author":"Robatjazi","year":"2017","journal-title":"Nat. Commun."},{"key":"D3NR02829A\/cit34\/1","doi-asserted-by":"crossref","first-page":"628","DOI":"10.3762\/bjnano.9.59","volume":"9","author":"Leong","year":"2018","journal-title":"Beilstein J. Nanotechnol."},{"key":"D3NR02829A\/cit35\/1","doi-asserted-by":"crossref","first-page":"911","DOI":"10.1038\/nmat3151","volume":"10","author":"Linic","year":"2011","journal-title":"Nat. Mater."},{"key":"D3NR02829A\/cit36\/1","doi-asserted-by":"crossref","first-page":"11588","DOI":"10.1021\/acs.jpcc.5b01177","volume":"119","author":"Arefi","year":"2015","journal-title":"J. Phys. Chem. C"},{"key":"D3NR02829A\/cit37\/1","doi-asserted-by":"crossref","first-page":"5863","DOI":"10.1021\/nn500897c","volume":"8","author":"Brown","year":"2014","journal-title":"ACS Nano"},{"key":"D3NR02829A\/cit38\/1","doi-asserted-by":"crossref","first-page":"25443","DOI":"10.1039\/C6CP02205G","volume":"18","author":"Cirri","year":"2016","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D3NR02829A\/cit39\/1","doi-asserted-by":"crossref","first-page":"6252","DOI":"10.1021\/acsnano.7b02449","volume":"11","author":"Hollerer","year":"2017","journal-title":"ACS Nano"},{"key":"D3NR02829A\/cit40\/1","doi-asserted-by":"crossref","first-page":"8135","DOI":"10.1021\/acsanm.3c01117","volume":"6","author":"Homma","year":"2023","journal-title":"ACS Appl. Nano Mater."},{"key":"D3NR02829A\/cit41\/1","doi-asserted-by":"crossref","first-page":"2200463","DOI":"10.1002\/adom.202200463","volume":"10","author":"Jain","year":"2022","journal-title":"Adv. Opt. Mater."},{"key":"D3NR02829A\/cit42\/1","doi-asserted-by":"crossref","first-page":"7579","DOI":"10.1021\/acs.chemmater.2c01941","volume":"34","author":"Jain","year":"2022","journal-title":"Chem. Mater."},{"key":"D3NR02829A\/cit43\/1","doi-asserted-by":"crossref","first-page":"890","DOI":"10.1021\/acs.jpclett.7b00106","volume":"8","author":"Kafle","year":"2017","journal-title":"J. Phys. Chem. Lett."},{"key":"D3NR02829A\/cit44\/1","doi-asserted-by":"crossref","first-page":"13705","DOI":"10.1021\/acs.jpcc.2c03879","volume":"126","author":"Langer","year":"2022","journal-title":"J. Phys. Chem. C"},{"key":"D3NR02829A\/cit45\/1","doi-asserted-by":"crossref","first-page":"192","DOI":"10.1021\/acs.nanolett.9b03588","volume":"20","author":"Liyanage","year":"2020","journal-title":"Nano Lett."},{"key":"D3NR02829A\/cit46\/1","doi-asserted-by":"crossref","first-page":"7487","DOI":"10.1021\/jp111900g","volume":"115","author":"Malicki","year":"2011","journal-title":"J. Phys. Chem. C"},{"key":"D3NR02829A\/cit47\/1","doi-asserted-by":"crossref","first-page":"7165","DOI":"10.1021\/acs.jpclett.8b03283","volume":"9","author":"Volk","year":"2018","journal-title":"J. Phys. Chem. Lett."},{"key":"D3NR02829A\/cit48\/1","doi-asserted-by":"crossref","first-page":"4360","DOI":"10.1021\/acscatal.7b01318","volume":"7","author":"Kim","year":"2017","journal-title":"ACS Catal."},{"key":"D3NR02829A\/cit49\/1","doi-asserted-by":"crossref","first-page":"3153","DOI":"10.1021\/acs.jpclett.9b00848","volume":"10","author":"Sch\u00fcrmann","year":"2019","journal-title":"J. Phys. Chem. Lett."},{"key":"D3NR02829A\/cit50\/1","doi-asserted-by":"crossref","first-page":"1599","DOI":"10.1039\/D1NA00737H","volume":"4","author":"Sch\u00fcrmann","year":"2022","journal-title":"Nanoscale Adv."},{"key":"D3NR02829A\/cit51\/1","doi-asserted-by":"crossref","first-page":"1951","DOI":"10.1039\/C6NR08695K","volume":"9","author":"Sch\u00fcrmann","year":"2017","journal-title":"Nanoscale"},{"key":"D3NR02829A\/cit52\/1","doi-asserted-by":"crossref","first-page":"1950","DOI":"10.1021\/acs.accounts.0c00872","volume":"54","author":"Lee","year":"2021","journal-title":"Acc. Chem. Res."},{"key":"D3NR02829A\/cit53\/1","doi-asserted-by":"crossref","first-page":"eaav0704","DOI":"10.1126\/sciadv.aav0704","volume":"5","author":"Foerster","year":"2019","journal-title":"Sci. Adv."},{"key":"D3NR02829A\/cit54\/1","doi-asserted-by":"crossref","first-page":"38302","DOI":"10.1021\/acsami.2c08327","volume":"14","author":"Li","year":"2022","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"D3NR02829A\/cit55\/1","doi-asserted-by":"crossref","first-page":"5522","DOI":"10.1021\/acscatal.0c01478","volume":"10","author":"Roy","year":"2020","journal-title":"ACS Catal."},{"key":"D3NR02829A\/cit56\/1","doi-asserted-by":"crossref","first-page":"8415","DOI":"10.1021\/acs.chemmater.8b03108","volume":"30","author":"Roy","year":"2018","journal-title":"Chem. Mater."},{"key":"D3NR02829A\/cit57\/1","doi-asserted-by":"crossref","first-page":"1542","DOI":"10.1021\/acs.jpclett.0c03732","volume":"12","author":"Zhang","year":"2021","journal-title":"J. Phys. Chem. Lett."},{"key":"D3NR02829A\/cit58\/1","doi-asserted-by":"crossref","first-page":"084708","DOI":"10.1063\/5.0098110","volume":"157","author":"Sch\u00fcrmann","year":"2022","journal-title":"J. Chem. Phys."},{"key":"D3NR02829A\/cit59\/1","doi-asserted-by":"crossref","first-page":"2938","DOI":"10.1021\/acscatal.1c05499","volume":"12","author":"Chen","year":"2022","journal-title":"ACS Catal."},{"key":"D3NR02829A\/cit60\/1","doi-asserted-by":"crossref","first-page":"192","DOI":"10.1021\/acs.nanolett.9b03588","volume":"20","author":"Liyanage","year":"2020","journal-title":"Nano Lett."},{"key":"D3NR02829A\/cit61\/1","doi-asserted-by":"crossref","first-page":"084708","DOI":"10.1063\/5.0098110","volume":"157","author":"Sch\u00fcrmann","year":"2022","journal-title":"J. Chem. Phys."},{"key":"D3NR02829A\/cit62\/1","doi-asserted-by":"crossref","first-page":"4360","DOI":"10.1021\/acscatal.7b01318","volume":"7","author":"Kim","year":"2017","journal-title":"ACS Catal."},{"key":"D3NR02829A\/cit63\/1","doi-asserted-by":"crossref","first-page":"7579","DOI":"10.1021\/acs.chemmater.2c01941","volume":"34","author":"Jain","year":"2022","journal-title":"Chem. Mater."},{"key":"D3NR02829A\/cit64\/1","doi-asserted-by":"crossref","first-page":"5522","DOI":"10.1021\/acscatal.0c01478","volume":"10","author":"Roy","year":"2020","journal-title":"ACS Catal."},{"key":"D3NR02829A\/cit65\/1","doi-asserted-by":"crossref","first-page":"8415","DOI":"10.1021\/acs.chemmater.8b03108","volume":"30","author":"Roy","year":"2018","journal-title":"Chem. Mater."},{"key":"D3NR02829A\/cit66\/1","doi-asserted-by":"crossref","first-page":"621","DOI":"10.1002\/adma.200401216","volume":"17","author":"de Boer","year":"2005","journal-title":"Adv. Mater."},{"key":"D3NR02829A\/cit67\/1","doi-asserted-by":"crossref","first-page":"1932","DOI":"10.1109\/TED.2017.2650216","volume":"64","author":"Xu","year":"2017","journal-title":"IEEE Trans. Electron Devices"},{"key":"D3NR02829A\/cit68\/1","doi-asserted-by":"crossref","first-page":"1805878","DOI":"10.1002\/adfm.201805878","volume":"29","author":"Patrikar","year":"2019","journal-title":"Adv. Funct. Mater."},{"key":"D3NR02829A\/cit69\/1","doi-asserted-by":"crossref","first-page":"13484","DOI":"10.1021\/acs.jpcc.3c01454","volume":"127","author":"Kumar","year":"2023","journal-title":"J. Phys. Chem. C"}],"container-title":["Nanoscale"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2023\/NR\/D3NR02829A","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T17:51:38Z","timestamp":1782928298000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/nr\/article\/15\/41\/16552-16560\/818021"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023]]},"references-count":69,"journal-issue":{"issue":"41","published-print":{"date-parts":[[2023,10,26]]}},"URL":"https:\/\/doi.org\/10.1039\/d3nr02829a","relation":{},"ISSN":["2040-3364","2040-3372"],"issn-type":[{"value":"2040-3364","type":"print"},{"value":"2040-3372","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023]]}}}