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Sci."],"abstract":"<jats:p>While low-valent \u03b2-diketiminate complexes with a Mg\u2013Mg bond are well-established, similar Ca\u2013Ca bound complexes were hitherto too reactive to be isolated. Herein we discuss the possible formation of low-valent heterobimetallic Mg\u2013Ca complexes.<\/jats:p>","DOI":"10.1039\/d3sc00909b","type":"journal-article","created":{"date-parts":[[2023,4,13]],"date-time":"2023-04-13T02:02:46Z","timestamp":1681351366000},"page":"4724-4734","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":34,"title":["On the existence of low-valent magnesium\u2013calcium complexes"],"prefix":"10.1039","volume":"14","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0766-3918","authenticated-orcid":false,"given":"Jonathan","family":"Mai","sequence":"first","affiliation":[{"name":"Inorganic and Organometallic Chemistry, Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg, Egerlandstra\u00dfe 1, Erlangen 91058, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bastian","family":"R\u00f6sch","sequence":"additional","affiliation":[{"name":"Inorganic and Organometallic Chemistry, Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg, Egerlandstra\u00dfe 1, Erlangen 91058, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Neha","family":"Patel","sequence":"additional","affiliation":[{"name":"Inorganic and Organometallic Chemistry, Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg, Egerlandstra\u00dfe 1, Erlangen 91058, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2895-4979","authenticated-orcid":false,"given":"Jens","family":"Langer","sequence":"additional","affiliation":[{"name":"Inorganic and Organometallic Chemistry, Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg, Egerlandstra\u00dfe 1, Erlangen 91058, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3997-1440","authenticated-orcid":false,"given":"Sjoerd","family":"Harder","sequence":"additional","affiliation":[{"name":"Inorganic and Organometallic Chemistry, Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg, Egerlandstra\u00dfe 1, Erlangen 91058, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2023]]},"reference":[{"key":"D3SC00909B\/cit1\/1","doi-asserted-by":"crossref","first-page":"1754","DOI":"10.1126\/science.1150856","volume":"318","author":"Green","year":"2007","journal-title":"Science"},{"key":"D3SC00909B\/cit2\/1","doi-asserted-by":"crossref","first-page":"197","DOI":"10.1002\/ejic.200900966","author":"Krieck","year":"2010","journal-title":"Eur. 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