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Sci."],"abstract":"<jats:p>\n                    Ferrous bridging mono-chalcogenide ate complexes K\n                    <jats:sub>2<\/jats:sub>\n                    [(\n                    <jats:sup>\n                      <jats:italic>t<\/jats:italic>\n                      Bu\n                    <\/jats:sup>\n                    pyrpyrr\n                    <jats:sub>2<\/jats:sub>\n                    )Fe\n                    <jats:sub>2<\/jats:sub>\n                    (\u03bc-E)] (2-E) (E = O, S, Se, and Te) are prepared and show a Fe\u2013E\u2013Fe bridge from linear (E = O) to acute for E = Te, with lesser antiferromagnetic coupling going down the series.\n                  <\/jats:p>","DOI":"10.1039\/d3sc01094e","type":"journal-article","created":{"date-parts":[[2023,5,27]],"date-time":"2023-05-27T08:01:36Z","timestamp":1685174496000},"page":"6770-6779","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Isostructural bridging diferrous chalcogenide cores [Fe\n                    <sup>II<\/sup>\n                    (\u03bc-E)Fe\n                    <sup>II<\/sup>\n                    ] (E = O, S, Se, Te) with decreasing antiferromagnetic coupling down the chalcogenide series"],"prefix":"10.1039","volume":"14","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-0619-3443","authenticated-orcid":false,"given":"Ethan","family":"Zars","sequence":"first","affiliation":[{"name":"Department of Chemistry, University of Pennsylvania, 231 S 34th St, Philadelphia, PA, 19104, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4241-153X","authenticated-orcid":false,"given":"Lisa","family":"Gravogl","sequence":"additional","affiliation":[{"name":"Department of Chemistry & Pharmacy, Friedrich-Alexander-Universit\u00e4t Erlangen \u2013 N\u00fcrnberg (FAU), Egerlandstr. 1, 91058 Erlangen, Bavaria, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael R.","family":"Gau","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Pennsylvania, 231 S 34th St, Philadelphia, PA, 19104, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Patrick J.","family":"Carroll","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Pennsylvania, 231 S 34th St, Philadelphia, PA, 19104, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7844-2998","authenticated-orcid":false,"given":"Karsten","family":"Meyer","sequence":"additional","affiliation":[{"name":"Department of Chemistry & Pharmacy, Friedrich-Alexander-Universit\u00e4t Erlangen \u2013 N\u00fcrnberg (FAU), Egerlandstr. 1, 91058 Erlangen, Bavaria, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8205-7868","authenticated-orcid":false,"given":"Daniel J.","family":"Mindiola","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Pennsylvania, 231 S 34th St, Philadelphia, PA, 19104, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2023]]},"reference":[{"key":"D3SC01094E\/cit1\/1","doi-asserted-by":"crossref","first-page":"235","DOI":"10.1021\/cr9900275","volume":"100","author":"Solomon","year":"2000","journal-title":"Chem. 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