{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,13]],"date-time":"2026-09-13T03:50:06Z","timestamp":1789271406855,"version":"build-2803163510"},"reference-count":45,"publisher":"Royal Society of Chemistry (RSC)","issue":"19","license":[{"start":{"date-parts":[[2023,4,24]],"date-time":"2023-04-24T00:00:00Z","timestamp":1682294400000},"content-version":"vor","delay-in-days":113,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/100000181","name":"Air Force Office of Scientific Research","doi-asserted-by":"publisher","award":["FA2386-21-1-4048"],"award-info":[{"award-number":["FA2386-21-1-4048"]}],"id":[{"id":"10.13039\/100000181","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100005156","name":"Alexander von Humboldt-Stiftung","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100005156","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000923","name":"Australian Research Council","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100000923","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Sci."],"abstract":"<jats:p>\n                    The reductive tetramerisation of CO by Lewis base activated dimagnesium(\n                    <jats:sc>i<\/jats:sc>\n                    ) compounds, in the presence of Mo(CO)\n                    <jats:sub>6<\/jats:sub>\n                    , led to the competitive formation of magnesium squarate and metallo-ketene complexes (see picture).\n                  <\/jats:p>","DOI":"10.1039\/d3sc01487h","type":"journal-article","created":{"date-parts":[[2023,4,24]],"date-time":"2023-04-24T04:41:26Z","timestamp":1682311286000},"page":"5188-5195","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["Molybdenum carbonyl assisted reductive tetramerization of CO by activated magnesium(\n                    <scp>i<\/scp>\n                    ) compounds: squarate dianion\n                    <i>vs.<\/i>\n                    metallo-ketene formation"],"prefix":"10.1039","volume":"14","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3527-3423","authenticated-orcid":false,"given":"K.","family":"Yuvaraj","sequence":"first","affiliation":[{"name":"School of Chemistry, Monash University, PO Box 23, VIC, 3800, Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jeremy C.","family":"Mullins","sequence":"additional","affiliation":[{"name":"School of Chemistry, Monash University, PO Box 23, VIC, 3800, Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thayalan","family":"Rajeshkumar","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Toulouse et CNRS, INSA, UPS, LPCNO, UMR 5215, 135 Avenue de Rangueil, F-31077 Toulouse, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7482-5510","authenticated-orcid":false,"given":"Iskander","family":"Douair","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Toulouse et CNRS, INSA, UPS, LPCNO, UMR 5215, 135 Avenue de Rangueil, F-31077 Toulouse, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2653-8557","authenticated-orcid":false,"given":"Laurent","family":"Maron","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Toulouse et CNRS, INSA, UPS, LPCNO, UMR 5215, 135 Avenue de Rangueil, F-31077 Toulouse, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7269-1045","authenticated-orcid":false,"given":"Cameron","family":"Jones","sequence":"additional","affiliation":[{"name":"School of Chemistry, Monash University, PO Box 23, VIC, 3800, Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2023]]},"reference":[{"key":"D3SC01487H\/cit1a\/1","doi-asserted-by":"crossref","first-page":"2634","DOI":"10.1021\/ef9009185","volume":"24","author":"Unruh","year":"2010","journal-title":"Energy Fuels"},{"key":"D3SC01487H\/cit1b\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1186\/2192-0567-2-3","volume":"2","author":"Dahmen","year":"2012","journal-title":"Energy Sustain. Soc."},{"key":"D3SC01487H\/cit1c\/1","doi-asserted-by":"crossref","first-page":"267","DOI":"10.1016\/j.rser.2015.12.143","volume":"58","author":"Ail","year":"2016","journal-title":"Renewable Sustainable Energy Rev."},{"key":"D3SC01487H\/cit2a\/1","volume-title":"Advances in Fischer\u2013Tropsch Synthesis Catalysts and Catalysis","year":"2009","unstructured":"Advances in Fischer\u2013Tropsch Synthesis Catalysts and Catalysis , ed.  B. H. Davis  and  M. L. Occelli ,  CRC ,  Boca Raton, FL ,  2009"},{"key":"D3SC01487H\/cit2b\/1","doi-asserted-by":"crossref","first-page":"1692","DOI":"10.1021\/cr050972v","volume":"107","author":"Khodakov","year":"2007","journal-title":"Chem. Rev."},{"key":"D3SC01487H\/cit2c\/1","doi-asserted-by":"crossref","first-page":"447","DOI":"10.1021\/cr00045a002","volume":"81","author":"Rofer-DePoorter","year":"1981","journal-title":"Chem. Rev."},{"key":"D3SC01487H\/cit2d\/1","doi-asserted-by":"crossref","first-page":"61","DOI":"10.1016\/S0065-3055(08)60321-4","volume":"17","author":"Masters","year":"1979","journal-title":"Adv. Organomet. Chem."},{"key":"D3SC01487H\/cit3a\/1","doi-asserted-by":"crossref","first-page":"1059","DOI":"10.1021\/cr00089a005","volume":"88","author":"Durfee","year":"1988","journal-title":"Chem. Rev."},{"key":"D3SC01487H\/cit3b\/1","doi-asserted-by":"crossref","first-page":"103","DOI":"10.1021\/ar00099a004","volume":"17","author":"Erker","year":"1984","journal-title":"Acc. Chem. Res."},{"key":"D3SC01487H\/cit3c\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/S0065-3055(08)60519-5","volume":"20","author":"Gladysz","year":"1982","journal-title":"Adv. Organomet. Chem."},{"key":"D3SC01487H\/cit3d\/1","doi-asserted-by":"crossref","first-page":"121","DOI":"10.1021\/ar50148a004","volume":"13","author":"Wolczanski","year":"1980","journal-title":"Acc. Chem. Res."},{"key":"D3SC01487H\/cit3e\/1","doi-asserted-by":"crossref","first-page":"e202219203","DOI":"10.1002\/anie.202219203","volume":"62","author":"Parr","year":"2023","journal-title":"Angew. Chem., Int. Ed."},{"key":"D3SC01487H\/cit4\/1","doi-asserted-by":"crossref","first-page":"8981","DOI":"10.1021\/jp406200w","volume":"117","author":"Kalescky","year":"2013","journal-title":"J. Phys. Chem. A"},{"key":"D3SC01487H\/cit5a\/1","doi-asserted-by":"crossref","first-page":"16587","DOI":"10.1039\/D0DT01564D","volume":"49","author":"Kong","year":"2020","journal-title":"Dalton Trans."},{"key":"D3SC01487H\/cit5b\/1","doi-asserted-by":"crossref","first-page":"2034","DOI":"10.1021\/jacs.1c13152","volume":"144","author":"Fujimori","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"D3SC01487H\/cit6a\/1","doi-asserted-by":"crossref","first-page":"8764","DOI":"10.1021\/jacs.9b04085","volume":"141","author":"Yuvaraj","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"D3SC01487H\/cit6b\/1","doi-asserted-by":"crossref","first-page":"634","DOI":"10.1021\/jacs.0c11482","volume":"143","author":"Xu","year":"2021","journal-title":"J. Am. Chem. Soc."},{"key":"D3SC01487H\/cit7\/1","doi-asserted-by":"crossref","first-page":"8944","DOI":"10.1021\/jacs.5b06439","volume":"137","author":"Lalrempuia","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"D3SC01487H\/cit8\/1","doi-asserted-by":"crossref","first-page":"829","DOI":"10.1126\/science.1121784","volume":"311","author":"Summerscales","year":"2006","journal-title":"Science"},{"key":"D3SC01487H\/cit9a\/1","doi-asserted-by":"crossref","first-page":"9602","DOI":"10.1021\/ja063222r","volume":"128","author":"Summerscales","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"D3SC01487H\/cit9b\/1","doi-asserted-by":"crossref","first-page":"13816","DOI":"10.1021\/ja8059792","volume":"130","author":"Frey","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"D3SC01487H\/cit9c\/1","doi-asserted-by":"crossref","first-page":"77","DOI":"10.1039\/C0SC00452A","volume":"2","author":"Arnold","year":"2011","journal-title":"Chem. Sci."},{"key":"D3SC01487H\/cit9d\/1","doi-asserted-by":"crossref","first-page":"9036","DOI":"10.1021\/ja2019492","volume":"133","author":"Mansell","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"D3SC01487H\/cit9e\/1","doi-asserted-by":"crossref","first-page":"9265","DOI":"10.1073\/pnas.1203417109","volume":"109","author":"Gardner","year":"2012","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"key":"D3SC01487H\/cit9f\/1","doi-asserted-by":"crossref","first-page":"1353","DOI":"10.1021\/om301045k","volume":"32","author":"Tsoureas","year":"2013","journal-title":"Organometallics"},{"key":"D3SC01487H\/cit9g\/1","doi-asserted-by":"crossref","first-page":"11242","DOI":"10.1021\/ja053497r","volume":"127","author":"Castro-Rodriguez","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"D3SC01487H\/cit9h\/1","doi-asserted-by":"crossref","first-page":"2006","DOI":"10.1039\/C9SC05794C","volume":"11","author":"Ryan","year":"2020","journal-title":"Chem. Sci."},{"key":"D3SC01487H\/cit10\/1","doi-asserted-by":"crossref","first-page":"3516","DOI":"10.1039\/D0SC00836B","volume":"11","author":"Yuvaraj","year":"2020","journal-title":"Chem. Sci."},{"key":"D3SC01487H\/cit11\/1","doi-asserted-by":"crossref","first-page":"17851","DOI":"10.1021\/jacs.1c09467","volume":"143","author":"Liu","year":"2021","journal-title":"J. Am. Chem. Soc."},{"key":"D3SC01487H\/cit12\/1","doi-asserted-by":"crossref","first-page":"630","DOI":"10.1002\/anie.202009523","volume":"60","author":"Paparo","year":"2021","journal-title":"Angew. Chem., Int. Ed."},{"key":"D3SC01487H\/cit13a\/1","doi-asserted-by":"crossref","first-page":"182","DOI":"10.1002\/jlac.18340110206","volume":"11","author":"Liebig","year":"1834","journal-title":"Ann. Chem. Pharmacie"},{"key":"D3SC01487H\/cit13b\/1","doi-asserted-by":"crossref","first-page":"14507","DOI":"10.1002\/chem.202001947","volume":"26","author":"Rosenthal","year":"2020","journal-title":"Chem. Eur. J."},{"key":"D3SC01487H\/cit14\/1","doi-asserted-by":"crossref","first-page":"9499","DOI":"10.1039\/D0OB01994A","volume":"18","author":"Jestil\u00e4","year":"2020","journal-title":"Org. Biomol. Chem."},{"key":"D3SC01487H\/cit15a\/1","doi-asserted-by":"crossref","first-page":"9079","DOI":"10.1002\/anie.200803960","volume":"47","author":"Green","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"D3SC01487H\/cit15b\/1","doi-asserted-by":"crossref","first-page":"9239","DOI":"10.1002\/anie.201604362","volume":"55","author":"Boutland","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"D3SC01487H\/cit16\/1","doi-asserted-by":"crossref","first-page":"1754","DOI":"10.1126\/science.1150856","volume":"318","author":"Green","year":"2007","journal-title":"Science"},{"key":"D3SC01487H\/cit18a\/1","doi-asserted-by":"crossref","first-page":"7449","DOI":"10.1039\/D2SC01798A","volume":"13","author":"Simler","year":"2022","journal-title":"Chem. Sci."},{"key":"D3SC01487H\/cit18b\/1","doi-asserted-by":"crossref","first-page":"3728","DOI":"10.1021\/ja00298a060","volume":"107","author":"Evans","year":"1985","journal-title":"J. Am. Chem. Soc."},{"key":"D3SC01487H\/cit18c\/1","doi-asserted-by":"crossref","first-page":"14176","DOI":"10.1021\/ja0640851","volume":"128","author":"Evans","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"D3SC01487H\/cit18d\/1","doi-asserted-by":"crossref","first-page":"2024","DOI":"10.1039\/D2SC06375A","volume":"14","author":"Ward","year":"2023","journal-title":"Chem. Sci."},{"key":"D3SC01487H\/cit19\/1","doi-asserted-by":"crossref","first-page":"13614","DOI":"10.1021\/jacs.8b09761","volume":"140","author":"Kong","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"D3SC01487H\/cit20\/1","volume-title":"As determined from a survey of the Cambridge Crystallographic Database","year":"2023","unstructured":"As determined from a survey of the Cambridge Crystallographic Database , March,  2023"},{"key":"D3SC01487H\/cit21\/1","doi-asserted-by":"crossref","first-page":"159","DOI":"10.1002\/celc.201700866","volume":"5","author":"Gosh","year":"2018","journal-title":"ChemElectroChem"},{"key":"D3SC01487H\/cit22a\/1","doi-asserted-by":"crossref","first-page":"1331","DOI":"10.1126\/science.ade4563","volume":"378","author":"Jorges","year":"2022","journal-title":"Science"},{"key":"D3SC01487H\/cit22b\/1","doi-asserted-by":"crossref","first-page":"e202219211","DOI":"10.1002\/anie.202219211","volume":"62","author":"Wei","year":"2023","journal-title":"Angew. Chem., Int. Ed."}],"container-title":["Chemical Science"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2023\/SC\/D3SC01487H","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2023\/SC\/D3SC01487H","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T17:35:17Z","timestamp":1782927317000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/sc\/article\/14\/19\/5188-5195\/826948"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023]]},"references-count":45,"journal-issue":{"issue":"19","published-print":{"date-parts":[[2023,5,17]]}},"URL":"https:\/\/doi.org\/10.1039\/d3sc01487h","relation":{"has-preprint":[{"id-type":"doi","id":"10.26434\/chemrxiv-2023-jn9ph","asserted-by":"object"}]},"ISSN":["2041-6520","2041-6539"],"issn-type":[{"value":"2041-6520","type":"print"},{"value":"2041-6539","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023]]}}}