{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T12:49:10Z","timestamp":1788439750846,"version":"build-2803163510"},"reference-count":70,"publisher":"Royal Society of Chemistry (RSC)","issue":"6","license":[{"start":{"date-parts":[[2023,12,23]],"date-time":"2023-12-23T00:00:00Z","timestamp":1703289600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2022YFA1503200"],"award-info":[{"award-number":["2022YFA1503200"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22073081"],"award-info":[{"award-number":["22073081"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004731","name":"Natural Science Foundation of Zhejiang Province","doi-asserted-by":"publisher","award":["LQ22B030011"],"award-info":[{"award-number":["LQ22B030011"]}],"id":[{"id":"10.13039\/501100004731","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Sci."],"abstract":"<jats:p>\n                    We have developed a triphos-Ru catalytic system that can switch the chemoselectivity in catalytic hydrogenation of urea derivatives (from\n                    <jats:italic>N<\/jats:italic>\n                    -formamides to\n                    <jats:italic>N<\/jats:italic>\n                    -monomethylamines and methanol) by changing only 0.5 mol% KO\n                    <jats:sup>\n                      <jats:italic>t<\/jats:italic>\n                    <\/jats:sup>\n                    Bu (2% to 1.5%).\n                  <\/jats:p>","DOI":"10.1039\/d3sc05674k","type":"journal-article","created":{"date-parts":[[2023,12,22]],"date-time":"2023-12-22T20:41:56Z","timestamp":1703277716000},"page":"2089-2099","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Switching the hydrogenation selectivity of urea derivatives\n                    <i>via<\/i>\n                    subtly tuning the amount and type of additive in the catalyst system"],"prefix":"10.1039","volume":"15","author":[{"given":"Jun","family":"Zhu","sequence":"first","affiliation":[{"name":"Department of Chemistry, ZJU-NHU United R&D Center, Zhejiang University, Hangzhou 310027, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9153-8890","authenticated-orcid":false,"given":"Yongtao","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemistry, ZJU-NHU United R&D Center, Zhejiang University, Hangzhou 310027, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7147-5973","authenticated-orcid":false,"given":"Jia","family":"Yao","sequence":"additional","affiliation":[{"name":"Department of Chemistry, ZJU-NHU United R&D Center, Zhejiang University, Hangzhou 310027, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5294-8731","authenticated-orcid":false,"given":"Haoran","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Chemistry, ZJU-NHU United R&D Center, Zhejiang University, Hangzhou 310027, China"},{"name":"State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2024]]},"reference":[{"key":"D3SC05674K\/cit1\/1","doi-asserted-by":"crossref","first-page":"5698","DOI":"10.1038\/s41467-019-13638-9","volume":"10","author":"Ye","year":"2019","journal-title":"Nat. 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