{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T18:36:16Z","timestamp":1783017376843,"version":"3.54.6"},"reference-count":40,"publisher":"Royal Society of Chemistry (RSC)","issue":"69","license":[{"start":{"date-parts":[[2025,7,30]],"date-time":"2025-07-30T00:00:00Z","timestamp":1753833600000},"content-version":"am","delay-in-days":576,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100000038","name":"Natural Sciences and Engineering Research Council of Canada","doi-asserted-by":"publisher","award":["RGPIN-2020-04480"],"award-info":[{"award-number":["RGPIN-2020-04480"]}],"id":[{"id":"10.13039\/501100000038","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100012979","name":"Council of Ontario Universities","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100012979","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Commun."],"abstract":"<jats:p>Boraadamantanes are a privileged class of group 13 compounds having a trigonal pyramidal (non-VSEPR) ground-state. Herein, the first examples of bifunctional boraadamantanes with an appended phosphine moiety are presented.<\/jats:p>","DOI":"10.1039\/d4cc02665a","type":"journal-article","created":{"date-parts":[[2024,7,30]],"date-time":"2024-07-30T07:01:13Z","timestamp":1722322873000},"page":"9222-9225","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["2-Alkylphosphino-1-boraadamantanes"],"prefix":"10.1039","volume":"60","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5419-1741","authenticated-orcid":false,"given":"Kurt F.","family":"Hoffmann","sequence":"first","affiliation":[{"name":"Department of Chemistry, Western University, 1151 Richmond Street, London, ON, N8K 3G6, Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-9710-7573","authenticated-orcid":false,"given":"Rayni P.","family":"Noriega","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Western University, 1151 Richmond Street, London, ON, N8K 3G6, Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Paul D.","family":"Boyle","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Western University, 1151 Richmond Street, London, ON, N8K 3G6, Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2186-1040","authenticated-orcid":false,"given":"Marcus W.","family":"Drover","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Western University, 1151 Richmond Street, London, ON, N8K 3G6, Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2024]]},"reference":[{"key":"D4CC02665A\/cit1\/1","doi-asserted-by":"crossref","first-page":"8043","DOI":"10.1039\/D3CC02190D","volume":"59","author":"Oberdorf","year":"2023","journal-title":"Chem. Commun."},{"key":"D4CC02665A\/cit2\/1","doi-asserted-by":"crossref","first-page":"131","DOI":"10.1038\/s42004-020-00371-4","volume":"3","author":"Dewhurst","year":"2020","journal-title":"Commun. Chem."},{"key":"D4CC02665A\/cit3\/1","doi-asserted-by":"crossref","first-page":"306","DOI":"10.1021\/ar500375j","volume":"48","author":"Stephan","year":"2015","journal-title":"Acc. Chem. Res."},{"key":"D4CC02665A\/cit4\/1","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1038\/nature08634","volume":"463","author":"Power","year":"2010","journal-title":"Nature"},{"key":"D4CC02665A\/cit5\/1","volume-title":"Valence and the Structure of Atoms and Molecules","author":"Lewis","year":"1923","unstructured":"G. N.Lewis ,  Valence and the Structure of Atoms and Molecules ,  Chemical Catalogue Company ,  New York ,  1923"},{"key":"D4CC02665A\/cit6\/1","doi-asserted-by":"crossref","first-page":"6400","DOI":"10.1002\/anie.201409800","volume":"54","author":"Stephan","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4CC02665A\/cit7\/1","doi-asserted-by":"crossref","first-page":"1315","DOI":"10.1016\/j.ccr.2007.07.007","volume":"252","author":"Gillespie","year":"2008","journal-title":"Coord. Chem. Rev."},{"key":"D4CC02665A\/cit8\/1","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1039\/qr9571100339","volume":"11","author":"Gillespie","year":"1957","journal-title":"Q. Rev., Chem. Soc."},{"key":"D4CC02665A\/cit9\/1","doi-asserted-by":"crossref","first-page":"764","DOI":"10.1039\/D3CS00765K","volume":"53","author":"Hannah","year":"2024","journal-title":"Chem. Soc. Rev."},{"key":"D4CC02665A\/cit10\/1","doi-asserted-by":"crossref","first-page":"e202302457","DOI":"10.1002\/chem.202302457","volume":"30","author":"Timoshkin","year":"2024","journal-title":"Chem. \u2013 Eur. J."},{"key":"D4CC02665A\/cit11\/1","doi-asserted-by":"crossref","first-page":"640","DOI":"10.1021\/ic202152h","volume":"51","author":"M\u00fcck","year":"2012","journal-title":"Inorg. Chem."},{"key":"D4CC02665A\/cit12\/1","doi-asserted-by":"crossref","first-page":"1439","DOI":"10.1351\/pac198355091439","volume":"55","author":"Mikhailov","year":"1983","journal-title":"Pure Appl. Chem."},{"key":"D4CC02665A\/cit13\/1","doi-asserted-by":"crossref","first-page":"802","DOI":"10.1007\/s11172-008-0119-3","volume":"57","author":"Gurskii","year":"2008","journal-title":"Russ. Chem. Bull."},{"key":"D4CC02665A\/cit14\/1","doi-asserted-by":"crossref","first-page":"10585","DOI":"10.1002\/chem.201200264","volume":"18","author":"Vishnevskiy","year":"2012","journal-title":"Chem. \u2013 Eur. J."},{"key":"D4CC02665A\/cit15\/1","doi-asserted-by":"crossref","first-page":"1771","DOI":"10.1007\/BF02495703","volume":"47","author":"Bubnov","year":"1998","journal-title":"Russ. Chem. Bull."},{"key":"D4CC02665A\/cit16\/1","doi-asserted-by":"crossref","first-page":"121","DOI":"10.1070\/MC2003v013n03ABEH001791","volume":"13","author":"Gurskii","year":"2003","journal-title":"Mendeleev Commun."},{"key":"D4CC02665A\/cit17\/1","doi-asserted-by":"crossref","first-page":"2823","DOI":"10.1021\/jm020326d","volume":"46","author":"Wagner","year":"2003","journal-title":"J. Med. Chem."},{"key":"D4CC02665A\/cit18\/1","first-page":"1639","author":"Chardon","year":"2020","journal-title":"Synlett"},{"key":"D4CC02665A\/cit19\/1","doi-asserted-by":"crossref","first-page":"12179","DOI":"10.1021\/ja0361291","volume":"125","author":"Wagner","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"D4CC02665A\/cit20\/1","doi-asserted-by":"crossref","first-page":"51","DOI":"10.1016\/S0022-328X(00)00746-4","volume":"620","author":"Wrackmeyer","year":"2001","journal-title":"J. Organomet. Chem."},{"key":"D4CC02665A\/cit21\/1","doi-asserted-by":"crossref","first-page":"438","DOI":"10.1007\/BF00949591","volume":"30","author":"Vorontsova","year":"1981","journal-title":"Russ. Chem. Bull."},{"key":"D4CC02665A\/cit22\/1","doi-asserted-by":"crossref","first-page":"1108","DOI":"10.1007\/BF00956395","volume":"36","author":"Bubnov","year":"1987","journal-title":"Russ. Chem. Bull."},{"key":"D4CC02665A\/cit23\/1","doi-asserted-by":"crossref","first-page":"2875","DOI":"10.1021\/ol061201w","volume":"8","author":"Wood","year":"2006","journal-title":"Org. Lett."},{"key":"D4CC02665A\/cit24\/1","doi-asserted-by":"crossref","first-page":"12402","DOI":"10.1002\/anie.202003119","volume":"59","author":"Chardon","year":"2020","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4CC02665A\/cit25\/1","doi-asserted-by":"crossref","first-page":"109","DOI":"10.1016\/0166-1280(94)04052-T","volume":"338","author":"Schulman","year":"1995","journal-title":"J. Mol. Struct.: THEOCHEM"},{"key":"D4CC02665A\/cit26\/1","doi-asserted-by":"crossref","first-page":"1065","DOI":"10.1039\/C5CS00697J","volume":"45","author":"Bouhadir","year":"2016","journal-title":"Chem. Soc. Rev."},{"key":"D4CC02665A\/cit27\/1","first-page":"415","volume":"2","author":"Gurskii","year":"1988","journal-title":"Izv. Akad. Nauk SSSR, Ser. Khim."},{"key":"D4CC02665A\/cit29\/1","doi-asserted-by":"crossref","first-page":"1709","DOI":"10.1021\/jo802504c","volume":"74","author":"Kaszynski","year":"2009","journal-title":"J. Org. Chem."},{"key":"D4CC02665A\/cit30\/1","doi-asserted-by":"crossref","first-page":"311","DOI":"10.1016\/0022-328X(91)86075-2","volume":"412","author":"Bubnov","year":"1991","journal-title":"J. Organomet. Chem."},{"key":"D4CC02665A\/cit31\/1","doi-asserted-by":"crossref","first-page":"9382","DOI":"10.1039\/C7DT01693J","volume":"46","author":"Rinne","year":"2017","journal-title":"Dalton Trans."},{"key":"D4CC02665A\/cit33\/1","doi-asserted-by":"crossref","first-page":"1062","DOI":"10.1021\/ja00865a045","volume":"84","author":"Graybill","year":"1962","journal-title":"J. Am. Chem. Soc."},{"key":"D4CC02665A\/cit34\/1","doi-asserted-by":"crossref","first-page":"189","DOI":"10.1070\/MC2004v014n05ABEH001920","volume":"14","author":"Lyssenko","year":"2004","journal-title":"Mendeleev Commun."},{"key":"D4CC02665A\/cit35\/1","doi-asserted-by":"crossref","first-page":"331","DOI":"10.1016\/j.trechm.2022.01.007","volume":"4","author":"Zurakowski","year":"2022","journal-title":"Trends Chem."},{"key":"D4CC02665A\/cit36\/1","doi-asserted-by":"crossref","first-page":"1861","DOI":"10.1039\/D2CS00022A","volume":"51","author":"Drover","year":"2022","journal-title":"Chem. Soc. Rev."},{"key":"D4CC02665A\/cit37\/1","doi-asserted-by":"crossref","first-page":"8879","DOI":"10.1021\/jo2016218","volume":"76","author":"Oliveri","year":"2011","journal-title":"J. Org. Chem."},{"key":"D4CC02665A\/cit38\/1","doi-asserted-by":"crossref","first-page":"15084","DOI":"10.1039\/D1SC03814A","volume":"12","author":"Beucher","year":"2021","journal-title":"Chem. Sci."},{"key":"D4CC02665A\/cit39\/1","doi-asserted-by":"crossref","first-page":"5122","DOI":"10.1039\/C6DT00275G","volume":"45","author":"Simler","year":"2016","journal-title":"Dalton Trans."},{"key":"D4CC02665A\/cit40\/1","doi-asserted-by":"crossref","first-page":"841","DOI":"10.1039\/b922984a","volume":"46","author":"Clavier","year":"2010","journal-title":"Chem. Commun."},{"key":"D4CC02665A\/cit41\/1","doi-asserted-by":"crossref","first-page":"819","DOI":"10.1021\/om00066a010","volume":"1","author":"Goel","year":"1982","journal-title":"Organometallics"},{"key":"D4CC02665A\/cit42\/1","doi-asserted-by":"crossref","first-page":"119","DOI":"10.1016\/S0022-328X(00)84529-5","volume":"199","author":"Arnold","year":"1980","journal-title":"J. Organomet. Chem."}],"container-title":["Chemical Communications"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2024\/CC\/D4CC02665A","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T17:36:05Z","timestamp":1783013765000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/cc\/article\/60\/69\/9222-9225\/839456"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024]]},"references-count":40,"journal-issue":{"issue":"69","published-print":{"date-parts":[[2024,8,22]]}},"URL":"https:\/\/doi.org\/10.1039\/d4cc02665a","relation":{},"ISSN":["1359-7345","1364-548X"],"issn-type":[{"value":"1359-7345","type":"print"},{"value":"1364-548X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024]]}}}