{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,16]],"date-time":"2026-08-16T18:55:24Z","timestamp":1786906524588,"version":"build-2736575974"},"reference-count":55,"publisher":"Royal Society of Chemistry (RSC)","issue":"39","license":[{"start":{"date-parts":[[2025,9,10]],"date-time":"2025-09-10T00:00:00Z","timestamp":1757462400000},"content-version":"am","delay-in-days":618,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22172100"],"award-info":[{"award-number":["22172100"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22372105"],"award-info":[{"award-number":["22372105"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012145","name":"Shenyang Normal University","doi-asserted-by":"publisher","award":["BS202208"],"award-info":[{"award-number":["BS202208"]}],"id":[{"id":"10.13039\/501100012145","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Phys. Chem. Chem. Phys."],"abstract":"<jats:p>\n                    The exposed atomic species of metal alloy support determined the performance of inverse catalyst for CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation.\n                  <\/jats:p>","DOI":"10.1039\/d4cp00927d","type":"journal-article","created":{"date-parts":[[2024,9,10]],"date-time":"2024-09-10T02:42:08Z","timestamp":1725936128000},"page":"25329-25340","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Metal substrate engineering to modulate CO\n                    <sub>2<\/sub>\n                    hydrogenation to methanol on inverse Zr\n                    <sub>3<\/sub>\n                    O\n                    <sub>6<\/sub>\n                    \/CuPd catalysts"],"prefix":"10.1039","volume":"26","author":[{"given":"Bin","family":"Qin","sequence":"first","affiliation":[{"name":"Institute of Catalysis for Energy and Environment, College of Chemistry and Chemical Engineering, Shenyang Normal University, Shenyang 110034, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"XiaoYing","family":"Sun","sequence":"additional","affiliation":[{"name":"Institute of Catalysis for Energy and Environment, College of Chemistry and Chemical Engineering, Shenyang Normal University, Shenyang 110034, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianzhuo","family":"Lu","sequence":"additional","affiliation":[{"name":"Institute of Catalysis for Energy and Environment, College of Chemistry and Chemical Engineering, Shenyang Normal University, Shenyang 110034, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0044-5512","authenticated-orcid":false,"given":"Zhen","family":"Zhao","sequence":"additional","affiliation":[{"name":"Institute of Catalysis for Energy and Environment, College of Chemistry and Chemical Engineering, Shenyang Normal University, Shenyang 110034, China"},{"name":"State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing, 102249, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8895-2054","authenticated-orcid":false,"given":"Bo","family":"Li","sequence":"additional","affiliation":[{"name":"Institute of Catalysis for Energy and Environment, College of Chemistry and Chemical Engineering, Shenyang Normal University, Shenyang 110034, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2024]]},"reference":[{"key":"D4CP00927D\/cit1\/1","doi-asserted-by":"crossref","first-page":"7984","DOI":"10.1021\/acs.chemrev.9b00723","volume":"120","author":"Jiang","year":"2020","journal-title":"Chem. Rev."},{"key":"D4CP00927D\/cit2\/1","doi-asserted-by":"crossref","first-page":"1385","DOI":"10.1039\/C9CS00614A","volume":"49","author":"Zhong","year":"2020","journal-title":"Chem. Soc. Rev."},{"key":"D4CP00927D\/cit3\/1","doi-asserted-by":"crossref","first-page":"19998","DOI":"10.1039\/C8TA06649C","volume":"6","author":"Liu","year":"2018","journal-title":"J. Mater. Chem. A"},{"key":"D4CP00927D\/cit4\/1","doi-asserted-by":"crossref","first-page":"143","DOI":"10.1016\/j.jechem.2020.05.006","volume":"54","author":"Chen","year":"2021","journal-title":"J. Energy Chem."},{"key":"D4CP00927D\/cit5\/1","doi-asserted-by":"crossref","first-page":"2208132","DOI":"10.1002\/adma.202208132","volume":"35","author":"Xie","year":"2023","journal-title":"Adv. Mater."},{"key":"D4CP00927D\/cit6\/1","doi-asserted-by":"crossref","first-page":"966","DOI":"10.1021\/acs.accounts.1c00676","volume":"55","author":"Yoshino","year":"2022","journal-title":"Acc. Chem. Res."},{"key":"D4CP00927D\/cit7\/1","doi-asserted-by":"crossref","first-page":"434","DOI":"10.1021\/acs.chemrev.7b00435","volume":"118","author":"Artz","year":"2018","journal-title":"Chem. Rev."},{"key":"D4CP00927D\/cit8\/1","doi-asserted-by":"crossref","first-page":"87","DOI":"10.1038\/s41586-019-1681-6","volume":"575","author":"Hepburn","year":"2019","journal-title":"Nature"},{"key":"D4CP00927D\/cit9\/1","doi-asserted-by":"crossref","first-page":"122176","DOI":"10.1016\/j.apcatb.2022.122176","volume":"326","author":"Dong","year":"2023","journal-title":"Appl. Catal., B"},{"key":"D4CP00927D\/cit10\/1","doi-asserted-by":"crossref","first-page":"122045","DOI":"10.1016\/j.apcatb.2022.122045","volume":"321","author":"Onrubia-Calvo","year":"2023","journal-title":"Appl. Catal., B"},{"key":"D4CP00927D\/cit11\/1","doi-asserted-by":"crossref","first-page":"122022","DOI":"10.1016\/j.apcatb.2022.122022","volume":"320","author":"Mori","year":"2023","journal-title":"Appl. Catal., B"},{"key":"D4CP00927D\/cit12\/1","doi-asserted-by":"crossref","first-page":"214","DOI":"10.1016\/S1872-2067(22)64202-5","volume":"47","author":"Kim","year":"2023","journal-title":"Chin. J. Catal."},{"key":"D4CP00927D\/cit13\/1","doi-asserted-by":"crossref","first-page":"438","DOI":"10.1038\/s41560-022-01019-4","volume":"7","author":"Wei","year":"2022","journal-title":"Nat. Energy"},{"key":"D4CP00927D\/cit14\/1","doi-asserted-by":"crossref","first-page":"124503","DOI":"10.1016\/j.fuel.2022.124503","volume":"324","author":"Yang","year":"2022","journal-title":"Fuel"},{"key":"D4CP00927D\/cit15\/1","doi-asserted-by":"crossref","first-page":"12440","DOI":"10.1021\/jacs.6b05791","volume":"138","author":"Kattel","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"D4CP00927D\/cit16\/1","doi-asserted-by":"crossref","first-page":"2318","DOI":"10.1002\/anie.201610166","volume":"56","author":"Larmier","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4CP00927D\/cit17\/1","doi-asserted-by":"crossref","first-page":"4544","DOI":"10.1002\/anie.201411581","volume":"54","author":"Lunkenbein","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4CP00927D\/cit18\/1","doi-asserted-by":"crossref","first-page":"6696","DOI":"10.1021\/acscatal.5b01755","volume":"5","author":"Rodriguez","year":"2015","journal-title":"ACS Catal."},{"key":"D4CP00927D\/cit19\/1","doi-asserted-by":"crossref","first-page":"12440","DOI":"10.1021\/jacs.6b05791","volume":"138","author":"Kattel","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"D4CP00927D\/cit20\/1","doi-asserted-by":"crossref","DOI":"10.1002\/9783527627806","volume-title":"Beyond Oil and Gas: The Methanol Economy, Wiley","author":"Olah","year":"2009","unstructured":"G. A.Olah ,  A.Goeppert  and  G. K. S.Prakash ,  Beyond Oil and Gas: The Methanol Economy, Wiley , 1st edn,  2009"},{"key":"D4CP00927D\/cit21\/1","doi-asserted-by":"crossref","first-page":"2636","DOI":"10.1002\/anie.200462121","volume":"44","author":"Olah","year":"2005","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4CP00927D\/cit22\/1","doi-asserted-by":"crossref","first-page":"893","DOI":"10.1126\/science.1219831","volume":"336","author":"Behrens","year":"2012","journal-title":"Science"},{"key":"D4CP00927D\/cit23\/1","doi-asserted-by":"crossref","first-page":"148974","DOI":"10.1016\/j.apsusc.2021.148974","volume":"544","author":"Qiu","year":"2021","journal-title":"Appl. Surf. Sci."},{"key":"D4CP00927D\/cit24\/1","doi-asserted-by":"crossref","first-page":"18306","DOI":"10.1021\/acs.jpcc.2c04921","volume":"126","author":"Mravak","year":"2022","journal-title":"J. Phys. Chem. C"},{"key":"D4CP00927D\/cit25\/1","doi-asserted-by":"crossref","first-page":"101542","DOI":"10.1016\/j.jcou.2021.101542","volume":"49","author":"Wang","year":"2021","journal-title":"J. CO2 Util."},{"key":"D4CP00927D\/cit26\/1","doi-asserted-by":"crossref","first-page":"17","DOI":"10.1016\/j.jcat.2017.12.029","volume":"359","author":"Hu","year":"2018","journal-title":"J. Catal."},{"key":"D4CP00927D\/cit27\/1","doi-asserted-by":"crossref","first-page":"7672","DOI":"10.1021\/acs.jpclett.0c02011","volume":"11","author":"Brix","year":"2020","journal-title":"J. Phys. Chem. Lett."},{"key":"D4CP00927D\/cit28\/1","doi-asserted-by":"crossref","first-page":"122064","DOI":"10.1016\/j.apcatb.2022.122064","volume":"321","author":"Quilis","year":"2023","journal-title":"Appl. Catal., B"},{"key":"D4CP00927D\/cit29\/1","doi-asserted-by":"crossref","first-page":"7840","DOI":"10.1021\/acscatal.9b01943","volume":"9","author":"Li","year":"2019","journal-title":"ACS Catal."},{"key":"D4CP00927D\/cit30\/1","doi-asserted-by":"crossref","first-page":"7968","DOI":"10.1002\/anie.201601661","volume":"55","author":"Kattel","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4CP00927D\/cit31\/1","doi-asserted-by":"crossref","first-page":"5767","DOI":"10.1038\/s41467-020-19634-8","volume":"11","author":"Wu","year":"2020","journal-title":"Nat. Commun."},{"key":"D4CP00927D\/cit32\/1","doi-asserted-by":"crossref","first-page":"1778","DOI":"10.1021\/acs.jpcc.5b12012","volume":"120","author":"Senanayake","year":"2016","journal-title":"J. Phys. Chem. C"},{"key":"D4CP00927D\/cit33\/1","doi-asserted-by":"crossref","first-page":"794","DOI":"10.1021\/acs.jpcb.7b06901","volume":"122","author":"Palomino","year":"2018","journal-title":"J. Phys. Chem. B"},{"key":"D4CP00927D\/cit34\/1","doi-asserted-by":"crossref","first-page":"7229","DOI":"10.1021\/acs.jpclett.3c01692","volume":"14","author":"Xiong","year":"2023","journal-title":"J. Phys. Chem. Lett."},{"key":"D4CP00927D\/cit35\/1","doi-asserted-by":"crossref","first-page":"15","DOI":"10.1016\/0927-0256(96)00008-0","volume":"6","author":"Kresse","year":"1996","journal-title":"Comput. Mater. Sci."},{"key":"D4CP00927D\/cit36\/1","doi-asserted-by":"crossref","first-page":"11169","DOI":"10.1103\/PhysRevB.54.11169","volume":"54","author":"Kresse","year":"1996","journal-title":"Phys. Rev. B: Condens. Matter Mater. Phys."},{"key":"D4CP00927D\/cit37\/1","doi-asserted-by":"crossref","first-page":"1758","DOI":"10.1103\/PhysRevB.59.1758","volume":"59","author":"Kresse","year":"1999","journal-title":"Phys. Rev. B: Condens. Matter Mater. Phys."},{"key":"D4CP00927D\/cit38\/1","doi-asserted-by":"crossref","first-page":"17953","DOI":"10.1103\/PhysRevB.50.17953","volume":"50","author":"Bl\u00f6chl","year":"1994","journal-title":"Phys. Rev. B: Condens. Matter Mater. Phys."},{"key":"D4CP00927D\/cit39\/1","doi-asserted-by":"crossref","first-page":"3865","DOI":"10.1103\/PhysRevLett.77.3865","volume":"77","author":"Perdew","year":"1996","journal-title":"Phys. Rev. Lett."},{"key":"D4CP00927D\/cit40\/1","doi-asserted-by":"crossref","first-page":"5188","DOI":"10.1103\/PhysRevB.13.5188","volume":"13","author":"Monkhorst","year":"1976","journal-title":"Phys. Rev. B: Solid State"},{"key":"D4CP00927D\/cit41\/1","doi-asserted-by":"crossref","first-page":"154104","DOI":"10.1063\/1.3382344","volume":"132","author":"Grimme","year":"2010","journal-title":"J. Chem. Phys."},{"key":"D4CP00927D\/cit42\/1","doi-asserted-by":"crossref","first-page":"146900","DOI":"10.1016\/j.apsusc.2020.146900","volume":"528","author":"Liu","year":"2020","journal-title":"Appl. Surf. Sci."},{"key":"D4CP00927D\/cit43\/1","doi-asserted-by":"crossref","first-page":"1095","DOI":"10.3866\/PKU.WHXB20110440","volume":"27","author":"Zhao","year":"2011","journal-title":"Acta Phys.-Chim. Sin."},{"key":"D4CP00927D\/cit44\/1","doi-asserted-by":"crossref","first-page":"7010","DOI":"10.1063\/1.480097","volume":"111","author":"Henkelman","year":"1999","journal-title":"J. Chem. Phys."},{"key":"D4CP00927D\/cit45\/1","doi-asserted-by":"crossref","first-page":"7959","DOI":"10.1021\/acs.jpcc.1c00718","volume":"125","author":"M\u00fcller","year":"2021","journal-title":"J. Phys. Chem. C"},{"key":"D4CP00927D\/cit46\/1","doi-asserted-by":"crossref","first-page":"1931","DOI":"10.1002\/jcc.26353","volume":"41","author":"Nelson","year":"2020","journal-title":"J. Comput. Chem."},{"key":"D4CP00927D\/cit47\/1","doi-asserted-by":"crossref","first-page":"354","DOI":"10.1016\/j.commatsci.2005.04.010","volume":"36","author":"Henkelman","year":"2006","journal-title":"Comput. Mater. Sci."},{"key":"D4CP00927D\/cit48\/1","doi-asserted-by":"crossref","first-page":"794","DOI":"10.1007\/s10562-015-1495-6","volume":"145","author":"Medford","year":"2015","journal-title":"Catal. Lett."},{"key":"D4CP00927D\/cit49\/1","doi-asserted-by":"crossref","first-page":"10148","DOI":"10.1021\/acscatal.8b01596","volume":"8","author":"Cao","year":"2018","journal-title":"ACS Catal."},{"key":"D4CP00927D\/cit50\/1","doi-asserted-by":"crossref","first-page":"18529","DOI":"10.1021\/acs.jpcc.6b02970","volume":"120","author":"Garcia-Pintos","year":"2016","journal-title":"J. Phys. Chem. C"},{"key":"D4CP00927D\/cit51\/1","doi-asserted-by":"crossref","first-page":"6102","DOI":"10.1039\/C9CY01242G","volume":"9","author":"Wu","year":"2019","journal-title":"Catal. Sci. Technol."},{"key":"D4CP00927D\/cit52\/1","doi-asserted-by":"crossref","first-page":"13615","DOI":"10.1021\/acs.jpcc.9b01847","volume":"123","author":"Wu","year":"2019","journal-title":"J. Phys. Chem. C"},{"key":"D4CP00927D\/cit53\/1","doi-asserted-by":"crossref","first-page":"2770","DOI":"10.1021\/acscatal.7b00115","volume":"7","author":"Campbell","year":"2017","journal-title":"ACS Catal."},{"key":"D4CP00927D\/cit54\/1","doi-asserted-by":"crossref","first-page":"1761","DOI":"10.1021\/acs.jpcc.1c08098","volume":"126","author":"Wang","year":"2022","journal-title":"J. Phys. Chem. C"},{"key":"D4CP00927D\/cit55\/1","doi-asserted-by":"crossref","first-page":"e202303939","DOI":"10.1002\/anie.202303939","volume":"62","author":"Meunier","year":"2023","journal-title":"Angew. Chem., Int. Ed."}],"container-title":["Physical Chemistry Chemical Physics"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2024\/CP\/D4CP00927D","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T18:43:14Z","timestamp":1783449794000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/cp\/article\/26\/39\/25329-25340\/842834"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024]]},"references-count":55,"journal-issue":{"issue":"39","published-print":{"date-parts":[[2024,10,9]]}},"URL":"https:\/\/doi.org\/10.1039\/d4cp00927d","relation":{},"ISSN":["1463-9076","1463-9084"],"issn-type":[{"value":"1463-9076","type":"print"},{"value":"1463-9084","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024]]}}}