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Phys."],"abstract":"<jats:p>\n                    The reactive phenylethynyl radical, a key to PAHs in the ISM, was detected and spectroscopically characterized along with its singlet and triplet cations, and thermal products revealing a complex puzzle containing C\n                    <jats:sub>8<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    , C\n                    <jats:sub>8<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    , and C\n                    <jats:sub>8<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    species.\n                  <\/jats:p>","DOI":"10.1039\/d4cp02129k","type":"journal-article","created":{"date-parts":[[2024,6,21]],"date-time":"2024-06-21T08:56:34Z","timestamp":1718960194000},"page":"18256-18265","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["The elusive phenylethynyl radical and its cation: synthesis, electronic structure, and reactivity"],"prefix":"10.1039","volume":"26","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8896-9454","authenticated-orcid":false,"given":"Ginny","family":"Karir","sequence":"first","affiliation":[{"name":"Lehrstuhl f\u00fcr Organische Chemie II, Ruhr-Universit\u00e4t Bochum, Bochum 44780, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5833-8520","authenticated-orcid":false,"given":"Enrique","family":"Mendez-Vega","sequence":"additional","affiliation":[{"name":"Lehrstuhl f\u00fcr Organische Chemie II, Ruhr-Universit\u00e4t Bochum, Bochum 44780, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9859-4043","authenticated-orcid":false,"given":"Adrian","family":"Portela-Gonzalez","sequence":"additional","affiliation":[{"name":"Lehrstuhl f\u00fcr Organische Chemie II, Ruhr-Universit\u00e4t Bochum, Bochum 44780, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1614-0262","authenticated-orcid":false,"given":"Mayank","family":"Saraswat","sequence":"additional","affiliation":[{"name":"Lehrstuhl f\u00fcr Organische Chemie II, Ruhr-Universit\u00e4t Bochum, Bochum 44780, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1640-7505","authenticated-orcid":false,"given":"Wolfram","family":"Sander","sequence":"additional","affiliation":[{"name":"Lehrstuhl f\u00fcr Organische Chemie II, Ruhr-Universit\u00e4t Bochum, Bochum 44780, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1251-4549","authenticated-orcid":false,"given":"Patrick","family":"Hemberger","sequence":"additional","affiliation":[{"name":"Laboratory for Synchrotron Radiation and Femtochemistry, Paul Scherrer Institute (PSI), Villigen CH-5232, Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2024]]},"reference":[{"key":"D4CP02129K\/cit1\/1","doi-asserted-by":"crossref","first-page":"203","DOI":"10.1002\/9783527615278.ch07","volume-title":"Modern Acetylene Chemistry","author":"Nicolaou","year":"1995","unstructured":"K. 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