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Chem. Chem. Phys."],"abstract":"<jats:p>\n                    This study explores photocatalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction on nanorod-Cu\/TiO\n                    <jats:sub>2<\/jats:sub>\n                    , identifying H\n                    <jats:sub>2<\/jats:sub>\n                    COOH as a key species for C\u2013O bond cleavage. Both CO and CH\n                    <jats:sub>3<\/jats:sub>\n                    OH share the H\n                    <jats:sub>2<\/jats:sub>\n                    CO intermediate, with CH\n                    <jats:sub>3<\/jats:sub>\n                    OH formation being favored over CO\n                    <jats:italic>via<\/jats:italic>\n                    a forth-back mechanism.\n                  <\/jats:p>","DOI":"10.1039\/d4cp04088k","type":"journal-article","created":{"date-parts":[[2024,12,30]],"date-time":"2024-12-30T07:40:50Z","timestamp":1735544450000},"page":"2536-2544","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Insight into photocatalytic CO\n                    <sub>2<\/sub>\n                    reduction on TiO\n                    <sub>2<\/sub>\n                    -supported Cu nanorods: a DFT study on the reaction mechanism and selectivity"],"prefix":"10.1039","volume":"27","author":[{"given":"Ying","family":"Liu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Center for Computational Chemistry and Research Institute of Industrial Catalysis, School of Chemistry & Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinyang","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Center for Computational Chemistry and Research Institute of Industrial Catalysis, School of Chemistry & Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiamin","family":"Jin","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Center for Computational Chemistry and Research Institute of Industrial Catalysis, School of Chemistry & Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huihui","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Center for Computational Chemistry and Research Institute of Industrial Catalysis, School of Chemistry & Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guanhua","family":"Ren","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Center for Computational Chemistry and Research Institute of Industrial Catalysis, School of Chemistry & Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6318-1051","authenticated-orcid":false,"given":"Peijun","family":"Hu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Center for Computational Chemistry and Research Institute of Industrial Catalysis, School of Chemistry & Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China"},{"name":"School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China"},{"name":"School of Chemistry and Chemical Engineering, The Queen's University of Belfast, Belfast BT9 5AG, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6138-5800","authenticated-orcid":false,"given":"Haifeng","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Center for Computational Chemistry and Research Institute of Industrial Catalysis, School of Chemistry & Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D4CP04088K\/cit1\/1","first-page":"9217","volume":"44","author":"Dhakshinamoorthy","year":"2012","journal-title":"Chem. 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