{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T21:52:25Z","timestamp":1790977945914,"version":"4.1.0"},"reference-count":38,"publisher":"Royal Society of Chemistry (RSC)","issue":"4","license":[{"start":{"date-parts":[[2025,11,27]],"date-time":"2025-11-27T00:00:00Z","timestamp":1764201600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100010190","name":"Grand \u00c9quipement National De Calcul Intensif","doi-asserted-by":"publisher","award":["AD010812434R3"],"award-info":[{"award-number":["AD010812434R3"]}],"id":[{"id":"10.13039\/501100010190","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002830","name":"Centre National d\u2019Etudes Spatiales","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100002830","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche","doi-asserted-by":"publisher","award":["ANR-21-CE49- 0008-01"],"award-info":[{"award-number":["ANR-21-CE49- 0008-01"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000271","name":"Science and Technology Facilities Council","doi-asserted-by":"publisher","award":["ST\/Y00261X\/1"],"award-info":[{"award-number":["ST\/Y00261X\/1"]}],"id":[{"id":"10.13039\/501100000271","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Phys. Chem. Chem. Phys."],"abstract":"<jats:p>\n                    The pyrolysis of CH\n                    <jats:sub>3<\/jats:sub>\n                    SH was studied from the CH\n                    <jats:sub>3<\/jats:sub>\n                    SH + SH, CH\n                    <jats:sub>3<\/jats:sub>\n                    SH + CH\n                    <jats:sub>3<\/jats:sub>\n                    , CH\n                    <jats:sub>2<\/jats:sub>\n                    S + SH, CH\n                    <jats:sub>2<\/jats:sub>\n                    S + CH\n                    <jats:sub>3<\/jats:sub>\n                    and CS + SH PES at the CCSD(T)-F12\/CBS level of theory. Reaction rates were obtained from the master equations and compared to available experimental data.\n                  <\/jats:p>","DOI":"10.1039\/d4cp04873c","type":"journal-article","created":{"date-parts":[[2025,11,27]],"date-time":"2025-11-27T15:41:09Z","timestamp":1764258069000},"page":"3055-3067","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["A theoretical study of CH\n                    <sub>3<\/sub>\n                    SH pyrolysis kinetics"],"prefix":"10.1039","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0009-0007-2485-0308","authenticated-orcid":false,"given":"Rom\u00e9o","family":"Veillet","sequence":"first","affiliation":[{"name":"Universit\u00e9 Paris Cit\u00e9 and Univ Paris Est Creteil, CNRS, LISA, F-75013 Paris, France"},{"name":"Astrophysics Group, University of Exeter, EX4 4QL Exeter, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2854-765X","authenticated-orcid":false,"given":"Olivia","family":"Venot","sequence":"additional","affiliation":[{"name":"Universit\u00e9 Paris Cit\u00e9 and Univ Paris Est Creteil, CNRS, LISA, F-75013 Paris, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0896-013X","authenticated-orcid":false,"given":"Fabiola Citrangolo","family":"Destro","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Lorraine, CNRS, LRGP, F-54000 Nancy, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Timoth\u00e9e","family":"Fages","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Lorraine, CNRS, LRGP, F-54000 Nancy, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7226-7060","authenticated-orcid":false,"given":"Ren\u00e9","family":"Fournet","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Lorraine, CNRS, LRGP, F-54000 Nancy, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pierre-Alexandre","family":"Glaude","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Lorraine, CNRS, LRGP, F-54000 Nancy, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4077-6578","authenticated-orcid":false,"given":"Roda","family":"Bounaceur","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Lorraine, CNRS, LRGP, F-54000 Nancy, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8682-5219","authenticated-orcid":false,"given":"Baptiste","family":"Sirjean","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Lorraine, CNRS, LRGP, F-54000 Nancy, France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D4CP04873C\/cit1\/1","doi-asserted-by":"crossref","first-page":"143","DOI":"10.1002\/ep.670210312","volume":"21","author":"Eow","year":"2002","journal-title":"Environ. 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