{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T22:32:16Z","timestamp":1789165936514,"version":"build-2803163510"},"reference-count":70,"publisher":"Royal Society of Chemistry (RSC)","issue":"11","license":[{"start":{"date-parts":[[2025,2,20]],"date-time":"2025-02-20T00:00:00Z","timestamp":1740009600000},"content-version":"am","delay-in-days":416,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100008131","name":"Rheinische Friedrich-Wilhelms-Universit\u00e4t Bonn","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100008131","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<jats:p>The first doubly P-bridged rigid, bent bis(NHCs) were generated and shown to be good building blocks in main group adducts and metal complexes with selective thermal retro-[4 + 2] cycloaddition chemistry.<\/jats:p>","DOI":"10.1039\/d4dt00378k","type":"journal-article","created":{"date-parts":[[2024,2,20]],"date-time":"2024-02-20T02:41:25Z","timestamp":1708396885000},"page":"5043-5050","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Application of phosphorus-bridged rigid, bent bis(NHCs) as dipodal ligands in main group and transition metal chemistry"],"prefix":"10.1039","volume":"53","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0143-724X","authenticated-orcid":false,"given":"Tatjana","family":"Tersch\u00fcren","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry, Rheinische Friedrich-Wilhelms-Universit\u00e4t Bonn, Gerhard-Domagk-Stra\u00dfe 1, 53121 Bonn, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6489-2106","authenticated-orcid":false,"given":"Gregor","family":"Schnakenburg","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry, Rheinische Friedrich-Wilhelms-Universit\u00e4t Bonn, Gerhard-Domagk-Stra\u00dfe 1, 53121 Bonn, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5661-8502","authenticated-orcid":false,"given":"Rainer","family":"Streubel","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry, Rheinische Friedrich-Wilhelms-Universit\u00e4t Bonn, Gerhard-Domagk-Stra\u00dfe 1, 53121 Bonn, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2024]]},"reference":[{"key":"D4DT00378K\/cit1\/1","doi-asserted-by":"crossref","first-page":"6463","DOI":"10.1021\/ja00227a028","volume":"110","author":"Igau","year":"1988","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT00378K\/cit2\/1","doi-asserted-by":"crossref","first-page":"361","DOI":"10.1021\/ja00001a054","volume":"113","author":"Arduengo","year":"1991","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT00378K\/cit3a\/1","doi-asserted-by":"crossref","first-page":"2162","DOI":"10.1002\/anie.199721621","volume":"36","author":"Herrmann","year":"1997","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"D4DT00378K\/cit3b\/1","doi-asserted-by":"crossref","first-page":"39","DOI":"10.1021\/cr940472u","volume":"100","author":"Bourissou","year":"2000","journal-title":"Chem. Rev."},{"key":"D4DT00378K\/cit3c\/1","doi-asserted-by":"crossref","first-page":"862","DOI":"10.1016\/j.ccr.2008.05.018","volume":"253","author":"de Fr\u00e9mont","year":"2009","journal-title":"Coord. Chem. Rev."},{"key":"D4DT00378K\/cit4\/1","doi-asserted-by":"crossref","first-page":"485","DOI":"10.1038\/nature13384","volume":"510","author":"Hopkinson","year":"2014","journal-title":"Nature"},{"key":"D4DT00378K\/cit5a\/1","doi-asserted-by":"crossref","first-page":"3122","DOI":"10.1002\/anie.200703883","volume":"47","author":"Hahn","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4DT00378K\/cit5b\/1","doi-asserted-by":"crossref","first-page":"3561","DOI":"10.1021\/cr8005153","volume":"109","author":"Lin","year":"2009","journal-title":"Chem. Rev."},{"key":"D4DT00378K\/cit5c\/1","doi-asserted-by":"crossref","first-page":"2247","DOI":"10.1016\/j.ccr.2004.05.013","volume":"248","author":"Crudden","year":"2004","journal-title":"Coord. Chem. Rev."},{"key":"D4DT00378K\/cit6a\/1","doi-asserted-by":"crossref","first-page":"9678","DOI":"10.1021\/acs.chemrev.8b00079","volume":"118","author":"Nesterov","year":"2018","journal-title":"Chem. Rev."},{"key":"D4DT00378K\/cit6b\/1","doi-asserted-by":"crossref","first-page":"6994","DOI":"10.1021\/acs.chemrev.8b00791","volume":"119","author":"Doddi","year":"2019","journal-title":"Chem. Rev."},{"key":"D4DT00378K\/cit7a\/1","doi-asserted-by":"crossref","first-page":"275","DOI":"10.1021\/acs.organomet.7b00720","volume":"37","author":"Munz","year":"2018","journal-title":"Organometallics"},{"key":"D4DT00378K\/cit7b\/1","doi-asserted-by":"crossref","first-page":"6723","DOI":"10.1039\/c3cs60146c","volume":"42","author":"Nelson","year":"2013","journal-title":"Chem. Soc. Rev."},{"key":"D4DT00378K\/cit7c\/1","doi-asserted-by":"crossref","first-page":"9457","DOI":"10.1021\/acs.chemrev.8b00067","volume":"118","author":"Huynh","year":"2018","journal-title":"Chem. Rev."},{"key":"D4DT00378K\/cit8\/1","doi-asserted-by":"crossref","first-page":"9988","DOI":"10.1021\/acs.chemrev.6b00695","volume":"118","author":"Peris","year":"2018","journal-title":"Chem. Rev."},{"key":"D4DT00378K\/cit9a\/1","doi-asserted-by":"crossref","first-page":"3612","DOI":"10.1021\/cr900074m","volume":"109","author":"D\u00edez-Gonz\u00e1lez","year":"2009","journal-title":"Chem. Rev."},{"key":"D4DT00378K\/cit9b\/1","doi-asserted-by":"crossref","first-page":"2805","DOI":"10.1002\/anie.199628051","volume":"35","author":"Herrmann","year":"1996","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"D4DT00378K\/cit10a\/1","doi-asserted-by":"crossref","first-page":"2142","DOI":"10.1039\/c2cs35383k","volume":"42","author":"F\u00e8vre","year":"2013","journal-title":"Chem. Soc. Rev."},{"key":"D4DT00378K\/cit10b\/1","doi-asserted-by":"crossref","first-page":"5606","DOI":"10.1021\/cr068372z","volume":"107","author":"Enders","year":"2007","journal-title":"Chem. Rev."},{"key":"D4DT00378K\/cit11a\/1","doi-asserted-by":"crossref","first-page":"1903","DOI":"10.1039\/b902238b","volume":"39","author":"Mercs","year":"2010","journal-title":"Chem. Soc. Rev."},{"key":"D4DT00378K\/cit11b\/1","doi-asserted-by":"crossref","first-page":"7168","DOI":"10.1039\/b907018d","author":"Mercs","year":"2009","journal-title":"Dalton Trans."},{"key":"D4DT00378K\/cit12\/1","doi-asserted-by":"crossref","first-page":"2371","DOI":"10.1002\/anie.199523711","volume":"34","author":"Herrmann","year":"1995","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"D4DT00378K\/cit13\/1","doi-asserted-by":"crossref","first-page":"1376","DOI":"10.1039\/b202814j","author":"Danopoulos","year":"2002","journal-title":"Chem. Commun."},{"key":"D4DT00378K\/cit14a\/1","doi-asserted-by":"crossref","first-page":"2020","DOI":"10.1039\/b815739a","author":"Morgan","year":"2009","journal-title":"Dalton Trans."},{"key":"D4DT00378K\/cit14b\/1","doi-asserted-by":"crossref","first-page":"7253","DOI":"10.1039\/b908696j","author":"Varnado","year":"2009","journal-title":"Dalton Trans."},{"key":"D4DT00378K\/cit14c\/1","doi-asserted-by":"crossref","first-page":"1017","DOI":"10.1016\/j.tetlet.2006.11.179","volume":"48","author":"Dallas","year":"2007","journal-title":"Tetrahedron Lett."},{"key":"D4DT00378K\/cit14d\/1","doi-asserted-by":"crossref","first-page":"653","DOI":"10.1016\/j.jorganchem.2004.10.019","volume":"690","author":"Coleman","year":"2005","journal-title":"J. Organomet. Chem."},{"key":"D4DT00378K\/cit15\/1","doi-asserted-by":"crossref","first-page":"6668","DOI":"10.1021\/ja964191a","volume":"119","author":"Guerret","year":"1997","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT00378K\/cit16\/1","doi-asserted-by":"crossref","first-page":"3729","DOI":"10.1002\/anie.200700535","volume":"46","author":"Mas-Marz\u00e1","year":"2007","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4DT00378K\/cit17\/1","doi-asserted-by":"crossref","first-page":"6186","DOI":"10.1002\/anie.200601583","volume":"45","author":"Khramov","year":"2006","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4DT00378K\/cit18\/1","doi-asserted-by":"crossref","first-page":"4623","DOI":"10.1021\/om3003834","volume":"31","author":"Prades","year":"2012","journal-title":"Organometallics"},{"key":"D4DT00378K\/cit19\/1","doi-asserted-by":"crossref","first-page":"12748","DOI":"10.1039\/D1DT02035H","volume":"50","author":"Poyatos","year":"2021","journal-title":"Dalton Trans."},{"key":"D4DT00378K\/cit20\/1","doi-asserted-by":"crossref","first-page":"12496","DOI":"10.1021\/ja054029k","volume":"127","author":"Boydston","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT00378K\/cit21a\/1","doi-asserted-by":"crossref","first-page":"3677","DOI":"10.1021\/cr800501s","volume":"109","author":"Poyatos","year":"2009","journal-title":"Chem. Rev."},{"key":"D4DT00378K\/cit21b\/1","doi-asserted-by":"crossref","first-page":"729","DOI":"10.1039\/b601574n","volume":"36","author":"Williams","year":"2007","journal-title":"Chem. Soc. Rev."},{"key":"D4DT00378K\/cit21c\/1","doi-asserted-by":"crossref","first-page":"1401","DOI":"10.1021\/acs.accounts.0c00312","volume":"53","author":"Ib\u00e1\u00f1ez","year":"2020","journal-title":"Acc. Chem. Res."},{"key":"D4DT00378K\/cit21d\/1","doi-asserted-by":"crossref","first-page":"2167","DOI":"10.1021\/acs.accounts.7b00158","volume":"50","author":"Sinha","year":"2017","journal-title":"Acc. Chem. Res."},{"key":"D4DT00378K\/cit21e\/1","doi-asserted-by":"crossref","first-page":"9587","DOI":"10.1021\/acs.chemrev.8b00119","volume":"118","author":"Gan","year":"2018","journal-title":"Chem. Rev."},{"key":"D4DT00378K\/cit21f\/1","doi-asserted-by":"crossref","first-page":"373","DOI":"10.1016\/j.ccr.2018.02.003","volume":"375","author":"Gardiner","year":"2018","journal-title":"Coord. Chem. Rev."},{"key":"D4DT00378K\/cit21g\/1","doi-asserted-by":"crossref","first-page":"2001936","DOI":"10.1002\/adom.202001936","volume":"9","author":"Luo","year":"2021","journal-title":"Adv. Opt. Mater."},{"key":"D4DT00378K\/cit21h\/1","doi-asserted-by":"crossref","first-page":"1723","DOI":"10.1039\/C3SC53126K","volume":"5","author":"Mata","year":"2014","journal-title":"Chem. Sci."},{"key":"D4DT00378K\/cit22a\/1","doi-asserted-by":"crossref","first-page":"7666","DOI":"10.1002\/anie.201101806","volume":"50","author":"Prades","year":"2011","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4DT00378K\/cit22b\/1","doi-asserted-by":"crossref","first-page":"6445","DOI":"10.1021\/om400779w","volume":"32","author":"Vald\u00e9s","year":"2013","journal-title":"Organometallics"},{"key":"D4DT00378K\/cit23\/1","doi-asserted-by":"crossref","first-page":"6903","DOI":"10.1039\/b907211j","author":"Arduengo","year":"2009","journal-title":"Dalton Trans."},{"key":"D4DT00378K\/cit24\/1","doi-asserted-by":"crossref","first-page":"640","DOI":"10.1039\/b512884f","author":"Saravanakumar","year":"2006","journal-title":"Chem. Commun."},{"key":"D4DT00378K\/cit25\/1","doi-asserted-by":"crossref","first-page":"16514","DOI":"10.1021\/ja067475w","volume":"128","author":"Sanderson","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT00378K\/cit26\/1","doi-asserted-by":"crossref","first-page":"2646","DOI":"10.1039\/C9CC08468A","volume":"56","author":"Naz","year":"2020","journal-title":"Chem. Commun."},{"key":"D4DT00378K\/cit27\/1","doi-asserted-by":"crossref","first-page":"689","DOI":"10.1039\/D0DT03915B","volume":"50","author":"Naz","year":"2021","journal-title":"Dalton Trans."},{"key":"D4DT00378K\/cit28\/1","doi-asserted-by":"crossref","first-page":"e202300991","DOI":"10.1002\/chem.202300991","volume":"29","author":"Jiang","year":"2023","journal-title":"Chem. \u2013 Eur. J."},{"key":"D4DT00378K\/cit29\/1","doi-asserted-by":"crossref","first-page":"9231","DOI":"10.1002\/anie.201704070","volume":"56","author":"Koner","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4DT00378K\/cit30\/1","doi-asserted-by":"crossref","first-page":"1182","DOI":"10.1039\/C7CC09349G","volume":"54","author":"Koner","year":"2018","journal-title":"Chem. Commun."},{"key":"D4DT00378K\/cit31\/1","doi-asserted-by":"crossref","first-page":"12776","DOI":"10.1039\/D0DT02529A","volume":"49","author":"Begum","year":"2020","journal-title":"Dalton Trans."},{"key":"D4DT00378K\/cit32a\/1","doi-asserted-by":"crossref","first-page":"1599","DOI":"10.1039\/D0QO01194K","volume":"8","author":"Shet","year":"2021","journal-title":"Org. Chem. Front."},{"key":"D4DT00378K\/cit32b\/1","doi-asserted-by":"crossref","first-page":"3","DOI":"10.2174\/138527206775193004","volume":"10","author":"Mezailles","year":"2006","journal-title":"Curr. Org. Chem."},{"key":"D4DT00378K\/cit32c\/1","doi-asserted-by":"crossref","first-page":"147","DOI":"10.1007\/7081_2008_11","volume-title":"Phosphorous Heterocycles I","volume":"20","author":"Le Floch","year":"2009","unstructured":"P.Le Floch , in  Phosphorous Heterocycles I , ed.  R. K. Bansal  and  I. M. Aladzheva ,  Springer-Verlag Berlin Heidelberg ,  Berlin, Heidelberg ,  2009 , vol.  20 , pp.  147\u2013184"},{"key":"D4DT00378K\/cit32d\/1","doi-asserted-by":"crossref","first-page":"151","DOI":"10.1007\/978-90-481-3817-3_6","volume-title":"Phosphorus compounds. Advanced tools in catalysis and material sciences","volume":"37","author":"M\u00fcller","year":"2011","unstructured":"C.M\u00fcller  and  D.Vogt , in  Phosphorus compounds. Advanced tools in catalysis and material sciences , ed.  M. Peruzzini  and  L. Gonsalvi ,  Springer ,  Dordrecht ,  2011 , vol.  37 , pp.  151\u2013181"},{"key":"D4DT00378K\/cit33\/1","doi-asserted-by":"crossref","first-page":"3432","DOI":"10.1021\/ja01477a019","volume":"83","author":"Krespan","year":"1961","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT00378K\/cit34a\/1","doi-asserted-by":"crossref","first-page":"1801","DOI":"10.1021\/ja00736a050","volume":"93","author":"Weinberg","year":"1971","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT00378K\/cit34b\/1","doi-asserted-by":"crossref","first-page":"3586","DOI":"10.1021\/jo00912a027","volume":"40","author":"Weinberg","year":"1975","journal-title":"J. Org. Chem."},{"key":"D4DT00378K\/cit34c\/1","doi-asserted-by":"crossref","first-page":"819","DOI":"10.1246\/bcsj.82.819","volume":"82","author":"Uchiyama","year":"2009","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"D4DT00378K\/cit34d\/1","doi-asserted-by":"crossref","first-page":"553","DOI":"10.1002\/aoc.590020609","volume":"2","author":"Ai-Soudani","year":"1988","journal-title":"Appl. Organomet. Chem."},{"key":"D4DT00378K\/cit34e\/1","doi-asserted-by":"crossref","first-page":"9","DOI":"10.1016\/S0022-328X(00)89361-4","volume":"112","author":"Woodard","year":"1976","journal-title":"J. Organomet. Chem."},{"key":"D4DT00378K\/cit35\/1","doi-asserted-by":"crossref","first-page":"8259","DOI":"10.1016\/S0040-4039(00)61405-3","volume":"34","author":"Ishii","year":"1993","journal-title":"Tetrahedron Lett."},{"key":"D4DT00378K\/cit36\/1","doi-asserted-by":"crossref","first-page":"e202200458","DOI":"10.1002\/cplu.202200458","volume":"88","author":"Werra","year":"2023","journal-title":"ChemPlusChem"},{"key":"D4DT00378K\/cit38\/1","doi-asserted-by":"crossref","first-page":"3715","DOI":"10.1016\/S0040-4039(00)93089-2","volume":"17","author":"Kobayashi","year":"1976","journal-title":"Tetrahedron Lett."},{"key":"D4DT00378K\/cit39\/1","doi-asserted-by":"crossref","first-page":"5530","DOI":"10.1021\/ja00040a007","volume":"114","author":"Arduengo","year":"1992","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT00378K\/cit40a\/1","doi-asserted-by":"crossref","first-page":"1567","DOI":"10.1002\/anie.201711188","volume":"57","author":"Pak","year":"2018","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4DT00378K\/cit40b\/1","doi-asserted-by":"crossref","first-page":"729","DOI":"10.1002\/(SICI)1521-3749(199905)625:5<729::AID-ZAAC729>3.0.CO;2-D","volume":"625","author":"Kuhn","year":"1999","journal-title":"Z. Anorg. Allg. Chem."},{"key":"D4DT00378K\/cit41\/1","doi-asserted-by":"crossref","first-page":"1882","DOI":"10.1002\/ejic.200801110","volume":"2009","author":"Delaude","year":"2009","journal-title":"Eur. J. Inorg. Chem."},{"key":"D4DT00378K\/cit42\/1","doi-asserted-by":"crossref","first-page":"893","DOI":"10.1021\/om3012085","volume":"32","author":"Warratz","year":"2013","journal-title":"Organometallics"}],"container-title":["Dalton Transactions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2024\/DT\/D4DT00378K","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T17:43:40Z","timestamp":1783014220000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/dt\/article\/53\/11\/5043-5050\/846461"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024]]},"references-count":70,"journal-issue":{"issue":"11","published-print":{"date-parts":[[2024,3,12]]}},"URL":"https:\/\/doi.org\/10.1039\/d4dt00378k","relation":{},"ISSN":["1477-9226","1477-9234"],"issn-type":[{"value":"1477-9226","type":"print"},{"value":"1477-9234","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024]]}}}