{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T14:02:56Z","timestamp":1787320976455,"version":"build-2736575974"},"reference-count":64,"publisher":"Royal Society of Chemistry (RSC)","issue":"18","license":[{"start":{"date-parts":[[2024,4,5]],"date-time":"2024-04-05T00:00:00Z","timestamp":1712275200000},"content-version":"vor","delay-in-days":95,"URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100009614","name":"Petroleum Technology Development Fund","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100009614","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000704","name":"Royal Society of Chemistry","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100000704","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000266","name":"Engineering and Physical Sciences Research Council","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100000266","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<jats:p>Michael addition of a variety of amines to ruthenium-coordinated 1,1-bis(diphenylphosphino)ethylene produces new backbone-functionalised ligands and catalysts that are highly effective for the Guerbet coupling of ethanol\/methanol to isobutanol.<\/jats:p>","DOI":"10.1039\/d4dt00561a","type":"journal-article","created":{"date-parts":[[2024,4,5]],"date-time":"2024-04-05T05:41:00Z","timestamp":1712295660000},"page":"8005-8010","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Backbone-functionalised ruthenium diphosphine complexes for catalytic upgrading of ethanol and methanol to iso-butanol"],"prefix":"10.1039","volume":"53","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3849-7417","authenticated-orcid":false,"given":"Folasade J.","family":"Sama","sequence":"first","affiliation":[{"name":"Cardiff Catalysis Institute, Cardiff University, Translational Research Hub, Maindy Road, Cathays, Cardiff, Wales, CF24 4HQ, UK"},{"name":"School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rachel A.","family":"Doyle","sequence":"additional","affiliation":[{"name":"School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8658-3897","authenticated-orcid":false,"given":"Benson M.","family":"Kariuki","sequence":"additional","affiliation":[{"name":"Cardiff Catalysis Institute, Cardiff University, Translational Research Hub, Maindy Road, Cathays, Cardiff, Wales, CF24 4HQ, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Natalie E.","family":"Pridmore","sequence":"additional","affiliation":[{"name":"School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2761-8604","authenticated-orcid":false,"given":"Hazel A.","family":"Sparkes","sequence":"additional","affiliation":[{"name":"School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8537-1884","authenticated-orcid":false,"given":"Richard L.","family":"Wingad","sequence":"additional","affiliation":[{"name":"Cardiff Catalysis Institute, Cardiff University, Translational Research Hub, Maindy Road, Cathays, Cardiff, Wales, CF24 4HQ, UK"},{"name":"School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0356-7067","authenticated-orcid":false,"given":"Duncan F.","family":"Wass","sequence":"additional","affiliation":[{"name":"Cardiff Catalysis Institute, Cardiff University, Translational Research Hub, Maindy Road, Cathays, Cardiff, Wales, CF24 4HQ, UK"},{"name":"School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2024]]},"reference":[{"key":"D4DT00561A\/cit1\/1","doi-asserted-by":"crossref","first-page":"484","DOI":"10.1126\/science.1114736","volume":"311","author":"Ragauskas","year":"2006","journal-title":"Science"},{"key":"D4DT00561A\/cit2\/1","doi-asserted-by":"crossref","first-page":"712","DOI":"10.1016\/j.rser.2014.10.013","volume":"42","author":"Guo","year":"2015","journal-title":"Renewable Sustainable Energy Rev."},{"key":"D4DT00561A\/cit3\/1","doi-asserted-by":"crossref","first-page":"11","DOI":"10.1016\/j.jclepro.2014.01.006","volume":"71","author":"Liew","year":"2014","journal-title":"J. Cleaner Prod."},{"key":"D4DT00561A\/cit4\/1","doi-asserted-by":"crossref","first-page":"82","DOI":"10.1016\/j.rser.2018.02.022","volume":"88","author":"Oumera","year":"2018","journal-title":"Renewable Sustainable Energy Rev."},{"key":"D4DT00561A\/cit5\/1","doi-asserted-by":"crossref","first-page":"858","DOI":"10.1016\/j.enconman.2010.08.013","volume":"52","author":"Balat","year":"2011","journal-title":"Energy Convers. Manage."},{"key":"D4DT00561A\/cit6\/1","doi-asserted-by":"crossref","first-page":"233","DOI":"10.1016\/j.pecs.2006.08.003","volume":"33","author":"Agarwal","year":"2007","journal-title":"Prog. Energy Combust. Sci."},{"key":"D4DT00561A\/cit7\/1","doi-asserted-by":"crossref","first-page":"2","DOI":"10.1002\/jctb.2540","volume":"86","author":"Harvey","year":"2011","journal-title":"J. Chem. Technol. Biotechnol."},{"key":"D4DT00561A\/cit8\/1","first-page":"47","volume-title":"Renewable Motor Fuels: The Past, the Present and the Uncertain Future","author":"Brownstein","year":"2014","unstructured":"A. M.Brownstein ,  Renewable Motor Fuels: The Past, the Present and the Uncertain Future ,  Butterworth-Heinemann ,  Oxford ,  2014 , p.  47"},{"key":"D4DT00561A\/cit9\/1","doi-asserted-by":"crossref","first-page":"512","DOI":"10.1016\/B978-012373944-5.00160-7","volume-title":"Encyclopedia of Microbiology (Third Edition)","author":"Qureshi","year":"2009","unstructured":"N.Qureshi , in  Encyclopedia of Microbiology (Third Edition) , ed.  M. Schaechter ,  Academic Press ,  Oxford ,  2009 , pp.  512\u2013528"},{"key":"D4DT00561A\/cit10\/1","doi-asserted-by":"crossref","first-page":"331","DOI":"10.1016\/j.copbio.2011.04.010","volume":"22","author":"D\u00fcrre","year":"2011","journal-title":"Curr. Opin. Biotechnol."},{"key":"D4DT00561A\/cit11\/1","doi-asserted-by":"crossref","first-page":"7","DOI":"10.1016\/j.cattod.2013.10.094","volume":"239","author":"Uyttebroek","year":"2015","journal-title":"Catal. Today"},{"key":"D4DT00561A\/cit12\/1","doi-asserted-by":"crossref","first-page":"907","DOI":"10.1016\/j.jechem.2016.08.010","volume":"25","author":"Zhang","year":"2016","journal-title":"J. Energy Chem."},{"key":"D4DT00561A\/cit13\/1","doi-asserted-by":"crossref","first-page":"49","DOI":"10.1080\/01614947208078691","volume":"6","author":"Paulik","year":"1972","journal-title":"Catal. Rev."},{"key":"D4DT00561A\/cit14\/1","doi-asserted-by":"crossref","first-page":"24734","DOI":"10.1039\/c3ra43011a","volume":"3","author":"Bankar","year":"2013","journal-title":"RSC Adv."},{"key":"D4DT00561A\/cit15\/1","doi-asserted-by":"crossref","first-page":"10991","DOI":"10.1021\/acs.iecr.5b02409","volume":"54","author":"Jordison","year":"2015","journal-title":"Ind. Eng. Chem. Res."},{"key":"D4DT00561A\/cit16\/1","doi-asserted-by":"crossref","first-page":"7181","DOI":"10.1021\/acs.iecr.5b01443","volume":"54","author":"Galadima","year":"2015","journal-title":"Ind. Eng. Chem. Res."},{"key":"D4DT00561A\/cit17\/1","doi-asserted-by":"crossref","first-page":"32","DOI":"10.1016\/j.chempr.2016.05.002","volume":"1","author":"Wu","year":"2016","journal-title":"Chem"},{"key":"D4DT00561A\/cit18\/1","first-page":"129","volume":"149","author":"Guerbet","year":"1909","journal-title":"C. R. Acad. Sci."},{"key":"D4DT00561A\/cit19\/1","first-page":"1002","author":"Guerbet","year":"1899","journal-title":"C. R. Acad. Sci."},{"key":"D4DT00561A\/cit20\/1","doi-asserted-by":"crossref","first-page":"1588","DOI":"10.1021\/cs400292f","volume":"3","author":"Kozlowski","year":"2013","journal-title":"ACS Catal."},{"key":"D4DT00561A\/cit21\/1","doi-asserted-by":"crossref","first-page":"3876","DOI":"10.1039\/C5CY00359H","volume":"5","author":"Gabri\u00ebls","year":"2015","journal-title":"Catal. Sci. Technol."},{"key":"D4DT00561A\/cit22\/1","doi-asserted-by":"crossref","first-page":"7125","DOI":"10.1021\/acscatal.6b01883","volume":"6","author":"Aitchison","year":"2016","journal-title":"ACS Catal."},{"key":"D4DT00561A\/cit23\/1","doi-asserted-by":"crossref","first-page":"114003","DOI":"10.1016\/j.cattod.2023.01.010","volume":"423","author":"Messori","year":"2023","journal-title":"Catal. Today"},{"key":"D4DT00561A\/cit24\/1","doi-asserted-by":"crossref","first-page":"1555","DOI":"10.1002\/adsc.200600638","volume":"349","author":"Haniti","year":"2007","journal-title":"Adv. Synth. Catal."},{"key":"D4DT00561A\/cit25\/1","doi-asserted-by":"crossref","first-page":"1723","DOI":"10.1016\/S0040-4020(01)82571-0","volume":"23","author":"Veibel","year":"1967","journal-title":"Tetrahedron"},{"key":"D4DT00561A\/cit26\/1","doi-asserted-by":"crossref","first-page":"9005","DOI":"10.1002\/anie.201303723","volume":"52","author":"Dowson","year":"2013","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4DT00561A\/cit27\/1","doi-asserted-by":"crossref","first-page":"5822","DOI":"10.1021\/acscatal.5b01327","volume":"5","author":"Wingad","year":"2015","journal-title":"ACS Catal."},{"key":"D4DT00561A\/cit28\/1","doi-asserted-by":"crossref","first-page":"5202","DOI":"10.1039\/C6CC01599A","volume":"52","author":"Wingad","year":"2016","journal-title":"Chem. Commun."},{"key":"D4DT00561A\/cit29\/1","doi-asserted-by":"crossref","first-page":"5128","DOI":"10.1039\/C7CY01553D","volume":"7","author":"Pellow","year":"2017","journal-title":"Catal. Sci. Technol."},{"key":"D4DT00561A\/cit30\/1","doi-asserted-by":"crossref","first-page":"3873","DOI":"10.1021\/acs.organomet.0c00588","volume":"39","author":"King","year":"2020","journal-title":"Organometallics"},{"key":"D4DT00561A\/cit31\/1","doi-asserted-by":"crossref","first-page":"2844","DOI":"10.1021\/acs.organomet.1c00313","volume":"40","author":"King","year":"2021","journal-title":"Organometallics"},{"key":"D4DT00561A\/cit32\/1","doi-asserted-by":"crossref","first-page":"e20220141","DOI":"10.1002\/cctc.202201410","volume":"15","author":"Wingad","year":"2023","journal-title":"ChemCatChem"},{"key":"D4DT00561A\/cit33\/1","doi-asserted-by":"crossref","first-page":"2285","DOI":"10.1039\/D3QI00142C","volume":"10","author":"Gupta","year":"2023","journal-title":"Inorg. Chem. Front."},{"key":"D4DT00561A\/cit34\/1","doi-asserted-by":"crossref","first-page":"838","DOI":"10.1246\/cl.2009.838","volume":"38","author":"Koda","year":"2009","journal-title":"Chem. Lett."},{"key":"D4DT00561A\/cit35\/1","doi-asserted-by":"crossref","first-page":"3971","DOI":"10.1039\/C4GC00510D","volume":"16","author":"Xu","year":"2014","journal-title":"Green Chem."},{"key":"D4DT00561A\/cit36\/1","doi-asserted-by":"crossref","first-page":"14264","DOI":"10.1021\/jacs.5b10257","volume":"137","author":"Chakraborty","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT00561A\/cit37\/1","doi-asserted-by":"crossref","first-page":"2901","DOI":"10.1039\/C5CC09913G","volume":"52","author":"Tseng","year":"2016","journal-title":"Chem. Commun."},{"key":"D4DT00561A\/cit38\/1","doi-asserted-by":"crossref","first-page":"9077","DOI":"10.1021\/jacs.6b05433","volume":"138","author":"Xie","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT00561A\/cit39\/1","doi-asserted-by":"crossref","first-page":"6172","DOI":"10.1039\/C7DT01022B","volume":"46","author":"Newland","year":"2017","journal-title":"Dalton Trans."},{"key":"D4DT00561A\/cit40\/1","doi-asserted-by":"crossref","first-page":"11941","DOI":"10.1021\/jacs.7b05939","volume":"139","author":"Fu","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT00561A\/cit41\/1","doi-asserted-by":"crossref","first-page":"997","DOI":"10.1021\/acscatal.7b03653","volume":"8","author":"Kulkarni","year":"2018","journal-title":"ACS Catal."},{"key":"D4DT00561A\/cit42\/1","doi-asserted-by":"crossref","first-page":"19625","DOI":"10.1039\/C8NJ03632B","volume":"42","author":"Newland","year":"2018","journal-title":"New J. Chem."},{"key":"D4DT00561A\/cit43\/1","doi-asserted-by":"crossref","first-page":"3069","DOI":"10.1002\/cssc.201802689","volume":"12","author":"Liu","year":"2019","journal-title":"ChemSusChem"},{"key":"D4DT00561A\/cit44\/1","doi-asserted-by":"crossref","first-page":"83","DOI":"10.1016\/j.poly.2018.12.001","volume":"160","author":"Wilklow-Marnell","year":"2019","journal-title":"Polyhedron"},{"key":"D4DT00561A\/cit45\/1","doi-asserted-by":"crossref","first-page":"224","DOI":"10.1021\/acssuschemeng.8b02959","volume":"7","author":"Mazzoni","year":"2019","journal-title":"ACS Sustainable Chem. Eng."},{"key":"D4DT00561A\/cit46\/1","doi-asserted-by":"crossref","first-page":"1884","DOI":"10.1021\/acs.organomet.1c00217","volume":"40","author":"DiBenedetto","year":"2021","journal-title":"Organometallics"},{"key":"D4DT00561A\/cit47\/1","doi-asserted-by":"crossref","first-page":"6729","DOI":"10.1021\/acscatal.2c01570","volume":"12","author":"Davies","year":"2022","journal-title":"ACS Catal."},{"key":"D4DT00561A\/cit48\/1","doi-asserted-by":"crossref","first-page":"47","DOI":"10.1016\/j.jcat.2021.11.027","volume":"405","author":"Cesari","year":"2022","journal-title":"J. Catal."},{"key":"D4DT00561A\/cit49\/1","doi-asserted-by":"crossref","first-page":"5449","DOI":"10.1021\/acscatal.2c06322","volume":"13","author":"Ni","year":"2023","journal-title":"ACS Catal."},{"key":"D4DT00561A\/cit50\/1","doi-asserted-by":"crossref","first-page":"2129","DOI":"10.1039\/c39950002129","author":"Higgins","year":"1995","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"D4DT00561A\/cit51\/1","doi-asserted-by":"crossref","first-page":"6188","DOI":"10.1021\/ic970799o","volume":"36","author":"Barkley","year":"1997","journal-title":"Inorg. Chem."},{"key":"D4DT00561A\/cit52\/1","doi-asserted-by":"crossref","first-page":"3403","DOI":"10.1039\/DT9920003403","author":"King","year":"1992","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"D4DT00561A\/cit53\/1","doi-asserted-by":"crossref","first-page":"1907","DOI":"10.1039\/a704677d","author":"Higgins","year":"1997","journal-title":"Chem. Commun."},{"key":"D4DT00561A\/cit54\/1","doi-asserted-by":"crossref","first-page":"286","DOI":"10.1039\/c39820000286","author":"Al-Jibori","year":"1982","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"D4DT00561A\/cit55\/1","doi-asserted-by":"crossref","first-page":"L123","DOI":"10.1016\/S0020-1693(00)93517-5","volume":"65","author":"Al-Jibori","year":"1982","journal-title":"Inorg. Chim. Acta"},{"key":"D4DT00561A\/cit56\/1","doi-asserted-by":"crossref","first-page":"235","DOI":"10.1016\/S0020-1693(00)81432-2","volume":"74","author":"Al-Jibori","year":"1983","journal-title":"Inorg. Chim. Acta"},{"key":"D4DT00561A\/cit57\/1","doi-asserted-by":"crossref","first-page":"863","DOI":"10.1039\/DT9840000863","author":"Al-Jibori","year":"1984","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"D4DT00561A\/cit58\/1","doi-asserted-by":"crossref","first-page":"213","DOI":"10.1016\/0022-328X(84)80525-2","volume":"273","author":"Al-Jibori","year":"1984","journal-title":"J. Organomet. Chem."},{"key":"D4DT00561A\/cit59\/1","doi-asserted-by":"crossref","first-page":"207","DOI":"10.1016\/S0020-1693(00)81640-0","volume":"122","author":"Cooper","year":"1986","journal-title":"Inorg. Chim. Acta"},{"key":"D4DT00561A\/cit60\/1","doi-asserted-by":"crossref","first-page":"319","DOI":"10.1139\/v05-254","volume":"84","author":"Filby","year":"2006","journal-title":"Can. J. Chem."},{"key":"D4DT00561A\/cit61\/1","doi-asserted-by":"crossref","first-page":"5655","DOI":"10.1016\/j.jorganchem.2007.09.024","volume":"692","author":"Hogarth","year":"2007","journal-title":"J. Organomet. Chem."},{"key":"D4DT00561A\/cit62\/1","doi-asserted-by":"crossref","first-page":"781","DOI":"10.1007\/s10876-012-0471-1","volume":"23","author":"Ghosh","year":"2012","journal-title":"J. Cluster Sci."},{"key":"D4DT00561A\/cit63\/1","doi-asserted-by":"crossref","first-page":"179","DOI":"10.1016\/S0020-1693(00)82405-6","volume":"84","author":"Chakravarty","year":"1984","journal-title":"Inorg. Chim. Acta"},{"key":"D4DT00561A\/cit64\/1","doi-asserted-by":"crossref","first-page":"1131","DOI":"10.1016\/S0277-5387(00)80966-3","volume":"6","author":"Cotton","year":"1987","journal-title":"Polyhedron"}],"container-title":["Dalton Transactions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2024\/DT\/D4DT00561A","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T05:17:21Z","timestamp":1782883041000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/dt\/article\/53\/18\/8005-8010\/846549"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024]]},"references-count":64,"journal-issue":{"issue":"18","published-print":{"date-parts":[[2024,5,7]]}},"URL":"https:\/\/doi.org\/10.1039\/d4dt00561a","relation":{},"ISSN":["1477-9226","1477-9234"],"issn-type":[{"value":"1477-9226","type":"print"},{"value":"1477-9234","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024]]}}}