{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T07:12:38Z","timestamp":1782889958425,"version":"3.54.5"},"reference-count":34,"publisher":"Royal Society of Chemistry (RSC)","issue":"3","license":[{"start":{"date-parts":[[2025,12,13]],"date-time":"2025-12-13T00:00:00Z","timestamp":1765584000000},"content-version":"am","delay-in-days":346,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["JP19K05490"],"award-info":[{"award-number":["JP19K05490"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["JP22K05123"],"award-info":[{"award-number":["JP22K05123"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["JP22H02088"],"award-info":[{"award-number":["JP22H02088"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<jats:p>\n                    A hydrogen-bridged bis(silylene) complex showed high performance in the activation of small molecules\n                    <jats:italic>via<\/jats:italic>\n                    dehydrogenative O\u2013H bond cleavage or hydro-bis(silylation).\n                  <\/jats:p>","DOI":"10.1039\/d4dt03226h","type":"journal-article","created":{"date-parts":[[2024,12,13]],"date-time":"2024-12-13T04:41:10Z","timestamp":1734064870000},"page":"915-919","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A hydrogen-bridged bis(silylene) complex as a platform for small molecule activation\n                    <i>via<\/i>\n                    adjacent metal\u2013ligand cooperation"],"prefix":"10.1039","volume":"54","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9649-0857","authenticated-orcid":false,"given":"Hisako","family":"Hashimoto","sequence":"first","affiliation":[{"name":"Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Satomi","family":"Matsuo","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuto","family":"Odagiri","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hiromi","family":"Tobita","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D4DT03226H\/cit1\/1","doi-asserted-by":"crossref","first-page":"1124","DOI":"10.1126\/science.1134230","volume":"314","author":"Welch","year":"2006","journal-title":"Science"},{"key":"D4DT03226H\/cit2\/1","doi-asserted-by":"crossref","first-page":"46","DOI":"10.1002\/anie.200903708","volume":"49","author":"Stephane","year":"2010","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4DT03226H\/cit3\/1","doi-asserted-by":"crossref","first-page":"3592","DOI":"10.1039\/C8CS00277K","volume":"48","author":"Lam","year":"2019","journal-title":"Chem. Soc. Rev."},{"key":"D4DT03226H\/cit4\/1","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1038\/nature08634","volume":"463","author":"Power","year":"2010","journal-title":"Nature"},{"key":"D4DT03226H\/cit5\/1","doi-asserted-by":"crossref","first-page":"389","DOI":"10.1039\/C0SC00388C","volume":"2","author":"Martin","year":"2011","journal-title":"Chem. Sci."},{"key":"D4DT03226H\/cit6\/1","doi-asserted-by":"crossref","first-page":"8043","DOI":"10.1039\/D3CC02190D","volume":"59","author":"Oberdorf","year":"2023","journal-title":"Chem. Commun."},{"key":"D4DT03226H\/cit7\/1","doi-asserted-by":"crossref","first-page":"4213","DOI":"10.1002\/cctc.201800963","volume":"10","author":"Weetman","year":"2018","journal-title":"ChemCatChem"},{"key":"D4DT03226H\/cit8\/1","doi-asserted-by":"crossref","first-page":"214413","DOI":"10.1016\/j.ccr.2022.214413","volume":"457","author":"Wang","year":"2022","journal-title":"Coord. Chem. Rev."},{"key":"D4DT03226H\/cit9\/1","doi-asserted-by":"crossref","first-page":"2839","DOI":"10.1039\/D0CC07721F","volume":"57","author":"Wang","year":"2021","journal-title":"Chem. Commun."},{"key":"D4DT03226H\/cit10\/1","doi-asserted-by":"crossref","first-page":"e202203438","DOI":"10.1002\/chem.202203438","volume":"29","author":"Petrikat","year":"2023","journal-title":"Chem. \u2013 Eur. J."},{"key":"D4DT03226H\/cit11\/1","doi-asserted-by":"crossref","first-page":"10393","DOI":"10.1021\/acs.chemrev.9b00262","volume":"119","author":"Higashi","year":"2019","journal-title":"Chem. Rev."},{"key":"D4DT03226H\/cit12\/1","first-page":"334","volume-title":"in Metal-Ligand Multiple Bonds","author":"Nugent","year":"1988","unstructured":"W. A.Nugent  and  J. M.Mayer ,  in Metal-Ligand Multiple Bonds ,  Wiley ,  New York ,  1988 , p.  334"},{"key":"D4DT03226H\/cit13\/1","doi-asserted-by":"crossref","first-page":"3488","DOI":"10.1002\/ejic.202100460","author":"Somerville","year":"2021","journal-title":"Eur. J. Inorg. Chem."},{"key":"D4DT03226H\/cit14\/1","doi-asserted-by":"crossref","first-page":"e202200638","DOI":"10.1002\/ejic.202200638","volume":"26","author":"Schoening","year":"2023","journal-title":"Eur. J. Inorg. Chem."},{"key":"D4DT03226H\/cit15\/1","doi-asserted-by":"crossref","first-page":"362","DOI":"10.1016\/j.ccr.2017.09.023","volume":"355","author":"Hashimoto","year":"2018","journal-title":"Coord. Chem. Rev."},{"key":"D4DT03226H\/cit16\/1","doi-asserted-by":"crossref","first-page":"17055","DOI":"10.1039\/D0DT03378B","volume":"49","author":"Saini","year":"2020","journal-title":"Dalton Trans."},{"key":"D4DT03226H\/cit17\/1","doi-asserted-by":"crossref","first-page":"778","DOI":"10.1246\/cl.200872","volume":"50","author":"Hashimoto","year":"2021","journal-title":"Chem. Lett."},{"key":"D4DT03226H\/cit18\/1","doi-asserted-by":"crossref","first-page":"158","DOI":"10.1021\/ja512336v","volume":"137","author":"Hashimoto","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT03226H\/cit19\/1","doi-asserted-by":"crossref","first-page":"8701","DOI":"10.1039\/C7DT00505A","volume":"46","author":"Hashimoto","year":"2017","journal-title":"Dalton Trans."},{"key":"D4DT03226H\/cit20\/1","doi-asserted-by":"crossref","first-page":"4092","DOI":"10.1021\/ja00220a089","volume":"110","author":"Ueno","year":"1988","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT03226H\/cit21\/1","doi-asserted-by":"crossref","first-page":"3415","DOI":"10.1021\/ja00165a026","volume":"112","author":"Tobita","year":"1990","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT03226H\/cit22\/1","doi-asserted-by":"crossref","first-page":"213","DOI":"10.1016\/S0065-3055(08)60368-8","volume":"19","author":"Curtis","year":"1981","journal-title":"Adv. Organomet. Chem."},{"key":"D4DT03226H\/cit23\/1","doi-asserted-by":"crossref","first-page":"1351","DOI":"10.1021\/cr00037a010","volume":"95","author":"Sharma","year":"1995","journal-title":"Chem. Rev."},{"key":"D4DT03226H\/cit24\/1","doi-asserted-by":"crossref","first-page":"291","DOI":"10.1002\/tcr.10034","volume":"2","author":"Ogino","year":"2002","journal-title":"Chem. Rec."},{"key":"D4DT03226H\/cit25\/1","doi-asserted-by":"crossref","first-page":"493","DOI":"10.1039\/b210588h","author":"Okazaki","year":"2003","journal-title":"Dalton Trans."},{"key":"D4DT03226H\/cit26\/1","doi-asserted-by":"crossref","first-page":"13640","DOI":"10.1021\/ja037620v","volume":"125","author":"Glaser","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT03226H\/cit27\/1","doi-asserted-by":"crossref","first-page":"428","DOI":"10.1021\/ja057494q","volume":"128","author":"Hayes","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT03226H\/cit28\/1","doi-asserted-by":"crossref","first-page":"11161","DOI":"10.1021\/ja903737j","volume":"131","author":"Calimano","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT03226H\/cit29\/1","doi-asserted-by":"crossref","first-page":"1812","DOI":"10.1039\/b819229b","author":"Ochiai","year":"2009","journal-title":"Dalton Trans."},{"key":"D4DT03226H\/cit30\/1","doi-asserted-by":"crossref","first-page":"1680","DOI":"10.1021\/om901078d","volume":"29","author":"Calimano","year":"2010","journal-title":"Organometallics"},{"key":"D4DT03226H\/cit31\/1","doi-asserted-by":"crossref","first-page":"5023","DOI":"10.1021\/om970609h","volume":"16","author":"Ueno","year":"1997","journal-title":"Organometallics"},{"key":"D4DT03226H\/cit32\/1","volume-title":"The Chemistry of Organic Silicon Compounds","volume":"2","author":"Sheldrick","year":"1989","unstructured":"W. S.Sheldrick , in  The Chemistry of Organic Silicon Compounds , ed.  S. Patai  and  Z. Rappoport ,  John Wiley & Sons ,  New York ,  1989 , ch. 3, vol.  2"},{"key":"D4DT03226H\/cit33\/1","doi-asserted-by":"crossref","first-page":"1326","DOI":"10.1021\/om020023h","volume":"21","author":"Ueno","year":"2002","journal-title":"Organometallics"},{"key":"D4DT03226H\/cit34\/1","doi-asserted-by":"crossref","first-page":"7276","DOI":"10.1021\/ja050441o","volume":"127","author":"Sakaba","year":"2005","journal-title":"J. Am. Chem. Soc."}],"container-title":["Dalton Transactions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/DT\/D4DT03226H","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T05:34:54Z","timestamp":1782884094000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/dt\/article\/54\/3\/915-919\/847868"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025]]},"references-count":34,"journal-issue":{"issue":"3","published-print":{"date-parts":[[2025,1,13]]}},"URL":"https:\/\/doi.org\/10.1039\/d4dt03226h","relation":{},"ISSN":["1477-9226","1477-9234"],"issn-type":[{"value":"1477-9226","type":"print"},{"value":"1477-9234","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025]]}}}