{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T19:43:34Z","timestamp":1782935014109,"version":"3.54.5"},"reference-count":61,"publisher":"Royal Society of Chemistry (RSC)","issue":"12","license":[{"start":{"date-parts":[[2026,2,24]],"date-time":"2026-02-24T00:00:00Z","timestamp":1771891200000},"content-version":"am","delay-in-days":419,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/100010061","name":"University of Waikato","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100010061","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<jats:p>Diacylated thiourea ligands with platinum group metals in a square planar geometry show exclusive S,N coordination which is theorised to be a result of intramolecular chalcogen and hydrogen non-covalent interactions.<\/jats:p>","DOI":"10.1039\/d4dt03390f","type":"journal-article","created":{"date-parts":[[2025,2,24]],"date-time":"2025-02-24T03:37:17Z","timestamp":1740368237000},"page":"4977-4989","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Diacylthioureas \u2013 an overlooked class of ligands; the coordination chemistry of diacylated thiourea with platinum(\n                    <scp>ii<\/scp>\n                    ), palladium(\n                    <scp>ii<\/scp>\n                    ) and gold(\n                    <scp>iii<\/scp>\n                    )"],"prefix":"10.1039","volume":"54","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1327-3820","authenticated-orcid":false,"given":"Matthew C.","family":"Risi","sequence":"first","affiliation":[{"name":"Chemistry and Applied Physics, Te Aka M\u0101tuatua \u2013 School of Science, University of Waikato, Private Bag 3105, Hamilton 3240, New Zealand"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7636-2046","authenticated-orcid":false,"given":"Simeon","family":"Atiga","sequence":"additional","affiliation":[{"name":"Chemistry and Applied Physics, Te Aka M\u0101tuatua \u2013 School of Science, University of Waikato, Private Bag 3105, Hamilton 3240, New Zealand"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6494-8480","authenticated-orcid":false,"given":"Timothy D.","family":"Christopher","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences, University of Auckland, Private Bag 92019, Auckland 1142, New Zealand"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5355-606X","authenticated-orcid":false,"given":"William","family":"Henderson","sequence":"additional","affiliation":[{"name":"Chemistry and Applied Physics, Te Aka M\u0101tuatua \u2013 School of Science, University of Waikato, Private Bag 3105, Hamilton 3240, New Zealand"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4150-5959","authenticated-orcid":false,"given":"Graham C.","family":"Saunders","sequence":"additional","affiliation":[{"name":"Chemistry and Applied Physics, Te Aka M\u0101tuatua \u2013 School of Science, University of Waikato, Private Bag 3105, Hamilton 3240, New Zealand"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D4DT03390F\/cit1\/1","doi-asserted-by":"crossref","first-page":"215620","DOI":"10.1016\/j.ccr.2023.215620","volume":"503","author":"Swaminathan","year":"2024","journal-title":"Coord. Chem. Rev."},{"key":"D4DT03390F\/cit2\/1","doi-asserted-by":"crossref","first-page":"116707","DOI":"10.1016\/j.poly.2023.116707","volume":"247","author":"Uysal","year":"2024","journal-title":"Polyhedron"},{"key":"D4DT03390F\/cit3\/1","doi-asserted-by":"crossref","first-page":"e6348","DOI":"10.1002\/aoc.6348","volume":"35","author":"Solmaz","year":"2021","journal-title":"Appl. Organomet. Chem."},{"key":"D4DT03390F\/cit4\/1","doi-asserted-by":"crossref","first-page":"215161","DOI":"10.1016\/j.ccr.2023.215161","volume":"488","author":"Ribeiro","year":"2023","journal-title":"Coord. Chem. Rev."},{"key":"D4DT03390F\/cit5\/1","doi-asserted-by":"crossref","first-page":"1621","DOI":"10.1021\/acs.organomet.2c00127","volume":"41","author":"Swaminathan","year":"2022","journal-title":"Organometallics"},{"key":"D4DT03390F\/cit6\/1","doi-asserted-by":"crossref","first-page":"111164","DOI":"10.1016\/j.jinorgbio.2020.111164","volume":"210","author":"Obradovi\u0107","year":"2020","journal-title":"J. Inorg. Biochem."},{"key":"D4DT03390F\/cit7\/1","doi-asserted-by":"crossref","first-page":"11742","DOI":"10.1039\/D1DT01385H","volume":"50","author":"Peega","year":"2021","journal-title":"Dalton Trans."},{"issue":"25","key":"D4DT03390F\/cit8\/1","doi-asserted-by":"crossref","first-page":"18011","DOI":"10.1039\/D4RA02567A","volume":"14","author":"Ullah","year":"2024","journal-title":"RSC Adv."},{"key":"D4DT03390F\/cit9\/1","doi-asserted-by":"crossref","first-page":"3656","DOI":"10.1039\/b205056k","author":"Rodger","year":"2002","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"D4DT03390F\/cit10\/1","doi-asserted-by":"crossref","first-page":"119644","DOI":"10.1016\/j.ica.2020.119644","volume":"508","author":"Nkabyo","year":"2020","journal-title":"Inorg. Chim. Acta"},{"key":"D4DT03390F\/cit11\/1","doi-asserted-by":"crossref","first-page":"114543","DOI":"10.1016\/j.poly.2020.114543","volume":"184","author":"Plutin","year":"2020","journal-title":"Polyhedron"},{"key":"D4DT03390F\/cit12\/1","doi-asserted-by":"crossref","first-page":"540","DOI":"10.1021\/om4010548","volume":"33","author":"Sheeba","year":"2014","journal-title":"Organometallics"},{"key":"D4DT03390F\/cit13\/1","doi-asserted-by":"crossref","first-page":"120506","DOI":"10.1016\/j.ica.2021.120506","volume":"526","author":"Risi","year":"2021","journal-title":"Inorg. Chim. Acta"},{"key":"D4DT03390F\/cit14\/1","doi-asserted-by":"crossref","first-page":"116992","DOI":"10.1016\/j.poly.2024.116992","volume":"255","author":"Risi","year":"2024","journal-title":"Polyhedron"},{"key":"D4DT03390F\/cit15\/1","first-page":"1","author":"Risi","year":"2024","journal-title":"J. Coord. Chem."},{"key":"D4DT03390F\/cit16\/1","doi-asserted-by":"crossref","first-page":"2130","DOI":"10.1021\/ja02174a022","volume":"37","author":"Kohmann","year":"1915","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT03390F\/cit17\/1","doi-asserted-by":"crossref","first-page":"38","DOI":"10.1080\/00304948.2023.2209489","volume":"56","author":"El-Sayed","year":"2024","journal-title":"Org. Prep. Proced. Int."},{"key":"D4DT03390F\/cit18\/1","doi-asserted-by":"crossref","first-page":"101032","DOI":"10.1016\/j.jics.2023.101032","volume":"100","author":"Tailor","year":"2023","journal-title":"J. Indian Chem. Soc."},{"key":"D4DT03390F\/cit19\/1","doi-asserted-by":"crossref","first-page":"131271","DOI":"10.1016\/j.molstruc.2021.131271","volume":"1245","author":"Saeed","year":"2021","journal-title":"J. Mol. Struct."},{"key":"D4DT03390F\/cit20\/1","doi-asserted-by":"crossref","first-page":"e202202117","DOI":"10.1002\/slct.202202117","volume":"7","author":"Biasi-Garbin","year":"2022","journal-title":"ChemistrySelect"},{"key":"D4DT03390F\/cit21\/1","doi-asserted-by":"crossref","first-page":"121850","DOI":"10.1016\/j.ica.2023.121850","volume":"561","author":"Risi","year":"2024","journal-title":"Inorg. Chim. Acta"},{"key":"D4DT03390F\/cit22\/1","doi-asserted-by":"crossref","first-page":"101","DOI":"10.1016\/S0020-1693(01)00473-X","volume":"320","author":"Henderson","year":"2001","journal-title":"Inorg. Chim. Acta"},{"key":"D4DT03390F\/cit23\/1","doi-asserted-by":"crossref","first-page":"120707","DOI":"10.1016\/j.ica.2021.120707","volume":"531","author":"Okpareke","year":"2022","journal-title":"Inorg. Chim. Acta"},{"key":"D4DT03390F\/cit24\/1","doi-asserted-by":"crossref","first-page":"5072","DOI":"10.1021\/acs.inorgchem.0c00319","volume":"59","author":"Cunha","year":"2020","journal-title":"Inorg. Chem."},{"key":"D4DT03390F\/cit25\/1","doi-asserted-by":"crossref","first-page":"e05022","DOI":"10.1016\/j.heliyon.2020.e05022","volume":"6","author":"Durosinmi","year":"2020","journal-title":"Heliyon"},{"key":"D4DT03390F\/cit26\/1","first-page":"2502","volume":"29","author":"Silveira","year":"2018","journal-title":"J. Braz. Chem. Soc."},{"key":"D4DT03390F\/cit27\/1","doi-asserted-by":"crossref","first-page":"74","DOI":"10.1016\/j.molstruc.2011.07.028","volume":"1004","author":"Zhu","year":"2011","journal-title":"J. Mol. Struct."},{"key":"D4DT03390F\/cit28\/1","doi-asserted-by":"crossref","first-page":"16311","DOI":"10.1039\/D1DT02611A","volume":"50","author":"Swaminathan","year":"2021","journal-title":"Dalton Trans."},{"key":"D4DT03390F\/cit29\/1","doi-asserted-by":"crossref","first-page":"6498","DOI":"10.1021\/ja100936w","volume":"132","author":"Johnson","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT03390F\/cit30\/1","doi-asserted-by":"crossref","first-page":"100208","DOI":"10.1016\/j.jics.2021.100208","volume":"98","author":"Hajji","year":"2021","journal-title":"J. Indian Chem. Soc."},{"key":"D4DT03390F\/cit31\/1","doi-asserted-by":"crossref","first-page":"3263","DOI":"10.1021\/ct400420r","volume":"9","author":"Lane","year":"2013","journal-title":"J. Chem. Theory Comput."},{"key":"D4DT03390F\/cit32\/1","doi-asserted-by":"crossref","first-page":"214556","DOI":"10.1016\/j.ccr.2022.214556","volume":"464","author":"Mahmudov","year":"2022","journal-title":"Coord. Chem. Rev."},{"key":"D4DT03390F\/cit33\/1","doi-asserted-by":"crossref","first-page":"9424","DOI":"10.1021\/ic050110c","volume":"44","author":"Gonz\u00e1lez-\u00c1lvarez","year":"2005","journal-title":"Inorg. Chem."},{"key":"D4DT03390F\/cit34\/1","doi-asserted-by":"crossref","first-page":"111843","DOI":"10.1016\/j.jinorgbio.2022.111843","volume":"233","author":"Dorairaj","year":"2022","journal-title":"J. Inorg. Biochem."},{"key":"D4DT03390F\/cit35\/1","doi-asserted-by":"crossref","first-page":"17241","DOI":"10.1039\/C9DT03672E","volume":"48","author":"Nkabyo","year":"2019","journal-title":"Dalton Trans."},{"key":"D4DT03390F\/cit36\/1","doi-asserted-by":"crossref","first-page":"990","DOI":"10.1038\/s41557-020-00561-6","volume":"12","author":"Proctor","year":"2020","journal-title":"Nat. Chem."},{"key":"D4DT03390F\/cit37\/1","doi-asserted-by":"crossref","first-page":"864","DOI":"10.1039\/C6SC04157D","volume":"8","author":"Davis","year":"2017","journal-title":"Chem. Sci."},{"key":"D4DT03390F\/cit38\/1","doi-asserted-by":"crossref","first-page":"246","DOI":"10.3390\/cryst12020246","volume":"12","author":"Novikov","year":"2022","journal-title":"Crystals"},{"key":"D4DT03390F\/cit39\/1","doi-asserted-by":"crossref","first-page":"49","DOI":"10.1016\/j.abb.2015.03.024","volume":"576","author":"Rehman","year":"2015","journal-title":"Arch. Biochem. Biophys."},{"key":"D4DT03390F\/cit40\/1","doi-asserted-by":"crossref","first-page":"12983","DOI":"10.1021\/jp204278k","volume":"115","author":"Contreras-Garc\u00eda","year":"2011","journal-title":"J. Phys. Chem. A"},{"key":"D4DT03390F\/cit41\/1","doi-asserted-by":"crossref","first-page":"12165","DOI":"10.1039\/c2cp41395g","volume":"14","author":"Otero-De-La-Roza","year":"2012","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D4DT03390F\/cit42\/1","doi-asserted-by":"crossref","first-page":"5977","DOI":"10.1039\/D2DT00796G","volume":"51","author":"Gomila","year":"2022","journal-title":"Dalton Trans."},{"key":"D4DT03390F\/cit43\/1","first-page":"5945958","volume":"19","author":"Mao","year":"2017","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D4DT03390F\/cit44\/1","doi-asserted-by":"crossref","first-page":"23067","DOI":"10.1039\/C6CP03784D","volume":"18","author":"Horn","year":"2016","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D4DT03390F\/cit45\/1","doi-asserted-by":"crossref","first-page":"129","DOI":"10.1007\/BF00549096","volume":"44","author":"Hirshfeld","year":"1977","journal-title":"Theor. Chim. Acta"},{"key":"D4DT03390F\/cit46\/1","doi-asserted-by":"crossref","first-page":"31","DOI":"10.1016\/j.molstruc.2019.03.009","volume":"1186","author":"Feddaoui","year":"2019","journal-title":"J. Mol. Struct."},{"key":"D4DT03390F\/cit47\/1","doi-asserted-by":"crossref","first-page":"12323","DOI":"10.1039\/D4RA00926F","volume":"14","author":"Atiga","year":"2024","journal-title":"RSC Adv."},{"key":"D4DT03390F\/cit48\/1","doi-asserted-by":"crossref","first-page":"25","DOI":"10.1016\/j.molstruc.2018.12.072","volume":"1181","author":"Demircio\u011flu","year":"2019","journal-title":"J. Mol. Struct."},{"key":"D4DT03390F\/cit49\/1","doi-asserted-by":"crossref","first-page":"953","DOI":"10.1107\/S2056989022008489","volume":"78","author":"Irrou","year":"2022","journal-title":"Acta Crystallogr., Sect. E:Crystallogr. Commun."},{"key":"D4DT03390F\/cit50\/1","doi-asserted-by":"crossref","first-page":"467","DOI":"10.1107\/S2056989020002698","volume":"76","author":"Jeroundi","year":"2020","journal-title":"Acta Crystallogr., Sect. E:Crystallogr. Commun."},{"key":"D4DT03390F\/cit51\/1","doi-asserted-by":"crossref","first-page":"1352","DOI":"10.1107\/S2056989019011551","volume":"75","author":"Daoui","year":"2019","journal-title":"Acta Crystallogr., Sect. E:Crystallogr. Commun."},{"key":"D4DT03390F\/cit52\/1","doi-asserted-by":"crossref","first-page":"136864","DOI":"10.1016\/j.molstruc.2023.136864","volume":"1297","author":"Laamari","year":"2024","journal-title":"J. Mol. Struct."},{"key":"D4DT03390F\/cit53\/1","doi-asserted-by":"crossref","first-page":"6521","DOI":"10.1021\/ja00437a018","volume":"98","author":"McDermott","year":"1976","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT03390F\/cit54\/1","doi-asserted-by":"crossref","first-page":"185","DOI":"10.1002\/9780470132609.ch44","author":"Wimmer","year":"1992","journal-title":"Inorg. Synth."},{"key":"D4DT03390F\/cit55\/1","doi-asserted-by":"crossref","first-page":"4095","DOI":"10.1039\/a807108j","author":"Fuchita","year":"1998","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"D4DT03390F\/cit56\/1","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Crystallogr."},{"key":"D4DT03390F\/cit57\/1","doi-asserted-by":"crossref","first-page":"59","DOI":"10.1107\/S2053273314022207","volume":"71","author":"Bourhis","year":"2015","journal-title":"Acta Crystallogr., Sect. A:Found. Adv."},{"key":"D4DT03390F\/cit58\/1","doi-asserted-by":"crossref","first-page":"184","DOI":"10.1080\/00268976.2014.952696","volume":"113","author":"Shao","year":"2015","journal-title":"Mol. Phys."},{"key":"D4DT03390F\/cit59\/1","doi-asserted-by":"crossref","first-page":"580","DOI":"10.1002\/jcc.22885","volume":"33","author":"Lu","year":"2012","journal-title":"J. Comput. Chem."},{"key":"D4DT03390F\/cit60\/1","first-page":"1","volume":"4","author":"Williams","year":"1986","journal-title":"Environment"},{"key":"D4DT03390F\/cit61\/1","doi-asserted-by":"crossref","first-page":"1006","DOI":"10.1107\/S1600576721002910","volume":"54","author":"Spackman","year":"2021","journal-title":"J. Appl. Crystallogr."}],"container-title":["Dalton Transactions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/DT\/D4DT03390F","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T17:54:09Z","timestamp":1782928449000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/dt\/article\/54\/12\/4977-4989\/847957"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025]]},"references-count":61,"journal-issue":{"issue":"12","published-print":{"date-parts":[[2025,3,17]]}},"URL":"https:\/\/doi.org\/10.1039\/d4dt03390f","relation":{},"ISSN":["1477-9226","1477-9234"],"issn-type":[{"value":"1477-9226","type":"print"},{"value":"1477-9234","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025]]}}}