{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T05:24:58Z","timestamp":1782883498424,"version":"3.54.5"},"reference-count":72,"publisher":"Royal Society of Chemistry (RSC)","issue":"10","license":[{"start":{"date-parts":[[2026,1,25]],"date-time":"2026-01-25T00:00:00Z","timestamp":1769299200000},"content-version":"am","delay-in-days":389,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100001843","name":"Science and Engineering Research Board","doi-asserted-by":"publisher","award":["SRG\/2020\/000216"],"award-info":[{"award-number":["SRG\/2020\/000216"]}],"id":[{"id":"10.13039\/501100001843","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<jats:p>\n                    The reactivity of\n                    <jats:italic>ortho<\/jats:italic>\n                    -silylated phosphines featuring SiMe\n                    <jats:sub>3<\/jats:sub>\n                    and SiR\n                    <jats:sub>2<\/jats:sub>\n                    H (R = Me, Ph) units has been studied towards ruthenium(\n                    <jats:sc>ii<\/jats:sc>\n                    ) metal precursors.\n                  <\/jats:p>","DOI":"10.1039\/d4dt03550j","type":"journal-article","created":{"date-parts":[[2025,1,24]],"date-time":"2025-01-24T20:40:46Z","timestamp":1737751246000},"page":"4312-4323","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Cationic and neutral ruthenium(\n                    <scp>ii<\/scp>\n                    ) complexes bearing silyl-phosphines: synthesis, structures, and catalytic studies in selective hydroboration of carbonyl compounds"],"prefix":"10.1039","volume":"54","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1521-8008","authenticated-orcid":false,"given":"Amiya Kumar","family":"Sahoo","sequence":"first","affiliation":[{"name":"Department of Chemical Sciences; Indian Institute of Science Education and Research Berhampur; Transit Campus, Industrial Training Institute (ITI); Engineering School Road, Ganjam, Odisha, 760010, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0004-1352-9867","authenticated-orcid":false,"given":"Rageshree","family":"Dash","sequence":"additional","affiliation":[{"name":"Department of Chemical Sciences; Indian Institute of Science Education and Research Berhampur; Transit Campus, Industrial Training Institute (ITI); Engineering School Road, Ganjam, Odisha, 760010, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0001-9109-6866","authenticated-orcid":false,"given":"Suraj Kumar","family":"Agrawalla","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences, National Institute of Science Education and Research (NISER), Bhubaneswar, 752050, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2414-7635","authenticated-orcid":false,"given":"Chandra Shekhar","family":"Purohit","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences, National Institute of Science Education and Research (NISER), Bhubaneswar, 752050, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1803-4818","authenticated-orcid":false,"given":"Adinarayana","family":"Doddi","sequence":"additional","affiliation":[{"name":"Department of Chemical Sciences; Indian Institute of Science Education and Research Berhampur; Transit Campus, Industrial Training Institute (ITI); Engineering School Road, Ganjam, Odisha, 760010, India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D4DT03550J\/cit1\/1","doi-asserted-by":"crossref","first-page":"1065","DOI":"10.1039\/C5CS00697J","volume":"45","author":"Bouhadir","year":"2016","journal-title":"Chem. Soc. Rev."},{"key":"D4DT03550J\/cit2\/1","doi-asserted-by":"crossref","first-page":"11291","DOI":"10.1021\/acs.chemrev.5b00559","volume":"116","author":"Corey","year":"2016","journal-title":"Chem. Rev."},{"key":"D4DT03550J\/cit3\/1","doi-asserted-by":"crossref","first-page":"e202218587","DOI":"10.1002\/anie.202218587","volume":"62","author":"Frenette","year":"2023","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4DT03550J\/cit4\/1","doi-asserted-by":"crossref","first-page":"10895","DOI":"10.1039\/D1CC04923B","volume":"57","author":"Frenette","year":"2021","journal-title":"Chem. Commun."},{"key":"D4DT03550J\/cit5\/1","doi-asserted-by":"crossref","first-page":"230","DOI":"10.1002\/ange.202012218","volume":"133","author":"Oma\u00f1a","year":"2021","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4DT03550J\/cit6\/1","doi-asserted-by":"crossref","first-page":"8320","DOI":"10.1002\/anie.201103719","volume":"50","author":"Gualco","year":"2011","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4DT03550J\/cit7a\/1","doi-asserted-by":"crossref","first-page":"268","DOI":"10.1002\/tcr.201600061","volume":"17","author":"Kameo","year":"2017","journal-title":"Chem. Rec."},{"key":"D4DT03550J\/cit7b\/1","doi-asserted-by":"crossref","first-page":"214837","DOI":"10.1016\/j.ccr.2022.214837","volume":"473","author":"Komuro","year":"2022","journal-title":"Coord. Chem. Rev."},{"key":"D4DT03550J\/cit8\/1","doi-asserted-by":"crossref","first-page":"15549","DOI":"10.1039\/D3DT01692G","volume":"52","author":"Sahoo","year":"2023","journal-title":"Dalton Trans."},{"key":"D4DT03550J\/cit9\/1","first-page":"e202409582","author":"Gao","year":"2024","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4DT03550J\/cit10\/1","doi-asserted-by":"crossref","first-page":"4352","DOI":"10.1039\/C8DT00289D","volume":"47","author":"Ren","year":"2018","journal-title":"Dalton Trans."},{"key":"D4DT03550J\/cit11\/1","doi-asserted-by":"crossref","first-page":"17594","DOI":"10.1039\/D1DT02832D","volume":"50","author":"Chang","year":"2021","journal-title":"Dalton. Trans."},{"key":"D4DT03550J\/cit12\/1","doi-asserted-by":"crossref","first-page":"1234","DOI":"10.1002\/asia.201700144","volume":"12","author":"Xu","year":"2017","journal-title":"Chem. \u2013 Asian J"},{"key":"D4DT03550J\/cit13\/1","doi-asserted-by":"crossref","first-page":"2586","DOI":"10.1021\/acscatal.2c06259","volume":"13","author":"Denker","year":"2023","journal-title":"ACS Catal."},{"key":"D4DT03550J\/cit14\/1","doi-asserted-by":"crossref","first-page":"1759","DOI":"10.1021\/acscatal.3c05355","volume":"14","author":"Din Reshi","year":"2024","journal-title":"ACS Catal."},{"key":"D4DT03550J\/cit15\/1","doi-asserted-by":"crossref","first-page":"3095","DOI":"10.1021\/acs.inorgchem.2c03953","volume":"62","author":"Prieto-Pascual","year":"2023","journal-title":"Inorg. Chem."},{"key":"D4DT03550J\/cit16\/1","doi-asserted-by":"crossref","first-page":"3963","DOI":"10.1039\/b709408f","author":"Montiel-Palma","year":"2007","journal-title":"Chem. Commun."},{"key":"D4DT03550J\/cit17a\/1","doi-asserted-by":"crossref","first-page":"3744","DOI":"10.1021\/om900216u","volume":"28","author":"Takaoka","year":"2009","journal-title":"Organometallics"},{"key":"D4DT03550J\/cit17b\/1","doi-asserted-by":"crossref","first-page":"4088","DOI":"10.1002\/anie.201001199","volume":"49","author":"Takaoka","year":"2010","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4DT03550J\/cit17c\/1","doi-asserted-by":"crossref","first-page":"19008","DOI":"10.1021\/ja410822p","volume":"135","author":"Bernal","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT03550J\/cit17d\/1","doi-asserted-by":"crossref","first-page":"9798","DOI":"10.1021\/ic400703r","volume":"52","author":"Montiel-Palma","year":"2013","journal-title":"Inorg. Chem."},{"key":"D4DT03550J\/cit17e\/1","doi-asserted-by":"crossref","first-page":"2122","DOI":"10.1002\/zaac.201500539","volume":"641","author":"Bernal","year":"2015","journal-title":"Z. Anorg. Allg. Chem."},{"key":"D4DT03550J\/cit17f\/1","doi-asserted-by":"crossref","first-page":"15850","DOI":"10.1039\/C6DT01869F","volume":"45","author":"MacInnis","year":"2016","journal-title":"Dalton Trans."},{"key":"D4DT03550J\/cit18a\/1","doi-asserted-by":"crossref","first-page":"2390","DOI":"10.1021\/om051080o","volume":"25","author":"Kawachi","year":"2006","journal-title":"Organometallics"},{"key":"D4DT03550J\/cit18b\/1","doi-asserted-by":"crossref","first-page":"905","DOI":"10.1002\/aoc.3519","volume":"30","author":"Li","year":"2016","journal-title":"Appl. Organomet. Chem."},{"key":"D4DT03550J\/cit19\/1","first-page":"905","author":"Quintard","year":"2004","journal-title":"Synthesis"},{"key":"D4DT03550J\/cit20\/1","doi-asserted-by":"crossref","first-page":"6843","DOI":"10.1039\/b806447d","author":"Gutsulyak","year":"2008","journal-title":"Dalton Trans."},{"key":"D4DT03550J\/cit21a\/1","doi-asserted-by":"crossref","first-page":"1539","DOI":"10.1021\/cs300296x","volume":"2","author":"Jeon","year":"2012","journal-title":"ACS Catal."},{"key":"D4DT03550J\/cit21b\/1","doi-asserted-by":"crossref","first-page":"e202204912","DOI":"10.1002\/anie.202204912","volume":"61","author":"Yuan","year":"2022","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4DT03550J\/cit21c\/1","doi-asserted-by":"crossref","first-page":"2991","DOI":"10.1021\/acs.organomet.3c00324","volume":"42","author":"Prieto-Pascual","year":"2023","journal-title":"Organometallics"},{"key":"D4DT03550J\/cit21d\/1","doi-asserted-by":"crossref","first-page":"e202302458","DOI":"10.1002\/chem.202302458","volume":"30","author":"Huang","year":"2024","journal-title":"Chem. \u2013 Eur. J."},{"key":"D4DT03550J\/cit22\/1","doi-asserted-by":"crossref","first-page":"349","DOI":"10.1021\/acs.organomet.3c00474","volume":"43","author":"Baker","year":"2024","journal-title":"Organometallics"},{"key":"D4DT03550J\/cit23\/1","doi-asserted-by":"crossref","first-page":"3670","DOI":"10.1021\/acs.organomet.5b00074","volume":"34","author":"D\u00edaz-\u00c1lvarez","year":"2015","journal-title":"Organometallics"},{"key":"D4DT03550J\/cit24\/1","doi-asserted-by":"crossref","first-page":"10785","DOI":"10.1021\/acs.inorgchem.7b01798","volume":"56","author":"Peters","year":"2017","journal-title":"Inorg. Chem."},{"key":"D4DT03550J\/cit25\/1","doi-asserted-by":"crossref","first-page":"m2838","DOI":"10.1107\/S1600536806039869","volume":"62","author":"Elsegood","year":"2006","journal-title":"Acta Crystallogr., Sect. E:Struct. Rep. Online"},{"key":"D4DT03550J\/cit26\/1","doi-asserted-by":"crossref","first-page":"115980","DOI":"10.1016\/j.poly.2022.115980","volume":"224","author":"Guimar\u00e3es","year":"2022","journal-title":"Polyhedron"},{"key":"D4DT03550J\/cit27a\/1","doi-asserted-by":"crossref","first-page":"4708","DOI":"10.1021\/ja01502a063","volume":"82","author":"Brown","year":"1960","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT03550J\/cit27b\/1","doi-asserted-by":"crossref","first-page":"1075","DOI":"10.1021\/ic50182a055","volume":"17","author":"Dewar","year":"1978","journal-title":"Inorg. Chem."},{"key":"D4DT03550J\/cit27c\/1","doi-asserted-by":"crossref","first-page":"2546","DOI":"10.1021\/ja00400a010","volume":"103","author":"Graham","year":"1981","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT03550J\/cit27d\/1","doi-asserted-by":"crossref","first-page":"2601","DOI":"10.1021\/jo00296a013","volume":"55","author":"Wang","year":"1990","journal-title":"J. Org. Chem."},{"key":"D4DT03550J\/cit28\/1","doi-asserted-by":"crossref","first-page":"412","DOI":"10.1039\/C3CS60197H","volume":"43","author":"Lennox","year":"2014","journal-title":"Chem.\nSoc. Rev."},{"key":"D4DT03550J\/cit29a\/1","doi-asserted-by":"crossref","first-page":"1156","DOI":"10.1021\/op2003826","volume":"16","author":"Magano","year":"2012","journal-title":"Org. Process Res. Dev."},{"key":"D4DT03550J\/cit29b\/1","doi-asserted-by":"crossref","first-page":"1479","DOI":"10.1021\/op400258a","volume":"17","author":"Ciriminna","year":"2013","journal-title":"Org. Process Res. Dev."},{"key":"D4DT03550J\/cit30a\/1","doi-asserted-by":"crossref","first-page":"874","DOI":"10.1021\/acscatal.8b04096","volume":"9","author":"Zhang","year":"2019","journal-title":"ACS Catal."},{"key":"D4DT03550J\/cit30b\/1","doi-asserted-by":"crossref","first-page":"4794","DOI":"10.1002\/chem.201800299","volume":"24","author":"Prashanth","year":"2018","journal-title":"Chem. \u2013 Eur. J."},{"key":"D4DT03550J\/cit30c\/1","doi-asserted-by":"crossref","first-page":"10651","DOI":"10.1002\/anie.201806168","volume":"57","author":"Pollard","year":"2018","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4DT03550J\/cit30d\/1","doi-asserted-by":"crossref","first-page":"9940","DOI":"10.1002\/chem.201801541","volume":"24","author":"Lemmerz","year":"2018","journal-title":"Chem. \u2013 Eur. J."},{"key":"D4DT03550J\/cit31\/1","doi-asserted-by":"crossref","first-page":"12452","DOI":"10.1021\/acs.inorgchem.8b01760","volume":"57","author":"Khoo","year":"2018","journal-title":"Inorg. Chem."},{"key":"D4DT03550J\/cit32\/1","doi-asserted-by":"crossref","first-page":"14392","DOI":"10.1002\/chem.201802958","volume":"24","author":"Roy","year":"2018","journal-title":"Chem. \u2013 Eur. J."},{"key":"D4DT03550J\/cit33\/1","doi-asserted-by":"crossref","first-page":"664","DOI":"10.1039\/C8DT02857E","volume":"48","author":"Sharma","year":"2019","journal-title":"Dalton Trans."},{"key":"D4DT03550J\/cit34\/1","doi-asserted-by":"crossref","first-page":"3180","DOI":"10.1002\/ejoc.201800547","volume":"2018","author":"Harinath","year":"2018","journal-title":"Eur. J. Org. Chem."},{"key":"D4DT03550J\/cit35\/1","doi-asserted-by":"crossref","first-page":"4521","DOI":"10.1038\/s41467-018-06831-9","volume":"9","author":"Erken","year":"2018","journal-title":"Nat. Commun."},{"key":"D4DT03550J\/cit36a\/1","doi-asserted-by":"crossref","first-page":"10231","DOI":"10.1002\/anie.201806196","volume":"57","author":"Blasius","year":"2018","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4DT03550J\/cit36b\/1","doi-asserted-by":"crossref","first-page":"9231","DOI":"10.1039\/C8DT01998C","volume":"47","author":"Baishya","year":"2018","journal-title":"Dalton Trans."},{"key":"D4DT03550J\/cit37\/1","doi-asserted-by":"crossref","first-page":"455","DOI":"10.1039\/C1CC14508H","volume":"48","author":"Khalimon","year":"2012","journal-title":"Chem. Commun."},{"key":"D4DT03550J\/cit38\/1","doi-asserted-by":"crossref","first-page":"5482","DOI":"10.1039\/C8CC01880D","volume":"54","author":"Newland","year":"2018","journal-title":"Chem. Commun."},{"key":"D4DT03550J\/cit39\/1","doi-asserted-by":"crossref","first-page":"4790","DOI":"10.1021\/acs.orglett.5b02352","volume":"17","author":"Kaithal","year":"2015","journal-title":"Org. Lett."},{"key":"D4DT03550J\/cit40\/1","doi-asserted-by":"crossref","first-page":"11493","DOI":"10.1039\/C9NJ02364J","volume":"43","author":"Wang","year":"2019","journal-title":"New J. Chem."},{"key":"D4DT03550J\/cit41\/1","doi-asserted-by":"crossref","first-page":"2085","DOI":"10.1021\/om801228m","volume":"28","author":"Koren-Selfridge","year":"2009","journal-title":"Organometallics"},{"issue":"18","key":"D4DT03550J\/cit42a\/1","doi-asserted-by":"crossref","first-page":"1956","DOI":"10.1021\/acs.organomet.3c00348","volume":"43","author":"Ataie","year":"2024","journal-title":"Organometallics"},{"key":"D4DT03550J\/cit42b\/1","doi-asserted-by":"crossref","first-page":"7840","DOI":"10.1021\/acs.orglett.8b03356","volume":"20","author":"Verma","year":"2018","journal-title":"Org. Lett."},{"key":"D4DT03550J\/cit43\/1","doi-asserted-by":"crossref","first-page":"401","DOI":"10.1021\/acs.orglett.8b03583","volume":"21","author":"Zeng","year":"2019","journal-title":"Org. Lett."},{"key":"D4DT03550J\/cit44\/1","doi-asserted-by":"crossref","first-page":"1103","DOI":"10.1039\/D1OB02339J","volume":"20","author":"Mahato","year":"2022","journal-title":"Org. Biomol. Chem."},{"key":"D4DT03550J\/cit45\/1","doi-asserted-by":"crossref","first-page":"2295","DOI":"10.1002\/ejic.202000310","volume":"2020","author":"Sarkar","year":"2020","journal-title":"Eur. J. Inorg. Chem."},{"key":"D4DT03550J\/cit46\/1","doi-asserted-by":"crossref","first-page":"1244","DOI":"10.1021\/acscatal.6b03332","volume":"7","author":"Weidner","year":"2017","journal-title":"ACS Catal."},{"key":"D4DT03550J\/cit47\/1","doi-asserted-by":"crossref","first-page":"69","DOI":"10.1021\/acs.joc.7b02076","volume":"83","author":"Wang","year":"2018","journal-title":"J. Org. Chem."},{"key":"D4DT03550J\/cit48\/1","doi-asserted-by":"crossref","first-page":"20237","DOI":"10.1038\/s41598-023-47518-6","volume":"13","author":"Krupa","year":"2023","journal-title":"Sci. Rep."},{"key":"D4DT03550J\/cit49a\/1","doi-asserted-by":"crossref","first-page":"11658","DOI":"10.1039\/C9CC06316A","volume":"55","author":"Naumann","year":"2019","journal-title":"Chem. Commun."},{"key":"D4DT03550J\/cit49b\/1","doi-asserted-by":"crossref","first-page":"1738","DOI":"10.1039\/C8GC00042E","volume":"20","author":"Stachowiak","year":"2018","journal-title":"Green Chem."},{"key":"D4DT03550J\/cit50\/1","doi-asserted-by":"crossref","first-page":"21213","DOI":"10.1021\/jacs.2c08559","volume":"144","author":"van Ijzendoorn","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT03550J\/cit51\/1","doi-asserted-by":"crossref","first-page":"12808","DOI":"10.1021\/jacs.5b08406","volume":"137","author":"Geri","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"D4DT03550J\/cit52\/1","doi-asserted-by":"crossref","first-page":"201","DOI":"10.1016\/j.jorganchem.2018.05.020","volume":"869","author":"Biancalana","year":"2018","journal-title":"J. Organomet. Chem."}],"container-title":["Dalton Transactions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/DT\/D4DT03550J","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T04:15:46Z","timestamp":1782879346000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/dt\/article\/54\/10\/4312-4323\/848047"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025]]},"references-count":72,"journal-issue":{"issue":"10","published-print":{"date-parts":[[2025,3,4]]}},"URL":"https:\/\/doi.org\/10.1039\/d4dt03550j","relation":{},"ISSN":["1477-9226","1477-9234"],"issn-type":[{"value":"1477-9226","type":"print"},{"value":"1477-9234","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025]]}}}