{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,3]],"date-time":"2026-07-03T22:56:08Z","timestamp":1783119368768,"version":"3.54.6"},"reference-count":70,"publisher":"Royal Society of Chemistry (RSC)","issue":"2","license":[{"start":{"date-parts":[[2025,11,14]],"date-time":"2025-11-14T00:00:00Z","timestamp":1763078400000},"content-version":"am","delay-in-days":317,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100001843","name":"Science and Engineering Research Board","doi-asserted-by":"publisher","award":["EMR\/2014\/001059"],"award-info":[{"award-number":["EMR\/2014\/001059"]}],"id":[{"id":"10.13039\/501100001843","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Nanoscale"],"abstract":"<jats:p>\n                    Three in one: Three Cu NCs of three different characters (\n                    <jats:italic>e.g.<\/jats:italic>\n                    two electron superatomic and mixed-valent Cu\n                    <jats:sup>II<\/jats:sup>\n                    \/Cu\n                    <jats:sup>I<\/jats:sup>\n                    and Cu\n                    <jats:sup>I<\/jats:sup>\n                    \/Cu\n                    <jats:sup>0<\/jats:sup>\n                    ), stabilized in a common Cu\n                    <jats:sub>12<\/jats:sub>\n                    S\n                    <jats:sub>12<\/jats:sub>\n                    truncated octahedron, are reported.\n                  <\/jats:p>","DOI":"10.1039\/d4nr03578j","type":"journal-article","created":{"date-parts":[[2024,11,14]],"date-time":"2024-11-14T06:42:30Z","timestamp":1731566550000},"page":"982-991","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Analogous copper nanoclusters (Cu\n                    <sub>16\/17<\/sub>\n                    ) with two electron superatomic and mixed valence copper(\n                    <scp>ii<\/scp>\n                    )\/copper(\n                    <scp>i<\/scp>\n                    ) and copper(\n                    <scp>i<\/scp>\n                    )\/copper(0) characters"],"prefix":"10.1039","volume":"17","author":[{"given":"Shibaditya","family":"Kumar","sequence":"first","affiliation":[{"name":"Department of Chemistry, National Institute of Technology Durgapur, Mahatma Gandhi Avenue, Durgapur 713209, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Saikat","family":"Mishra","sequence":"additional","affiliation":[{"name":"Department of Chemistry, National Institute of Technology Durgapur, Mahatma Gandhi Avenue, Durgapur 713209, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aniruddha","family":"Das","sequence":"additional","affiliation":[{"name":"Department of Chemistry, National Institute of Technology Durgapur, Mahatma Gandhi Avenue, Durgapur 713209, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1012-2493","authenticated-orcid":false,"given":"Kuldeep","family":"Mahiya","sequence":"additional","affiliation":[{"name":"Department of Chemistry, F. G. M. Government College, Adampur, Hisar-125052, Haryana, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sourav","family":"Laha","sequence":"additional","affiliation":[{"name":"Department of Chemistry, National Institute of Technology Durgapur, Mahatma Gandhi Avenue, Durgapur 713209, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Milan","family":"Maji","sequence":"additional","affiliation":[{"name":"Department of Chemistry, National Institute of Technology Durgapur, Mahatma Gandhi Avenue, Durgapur 713209, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7232-1274","authenticated-orcid":false,"given":"Apurba K.","family":"Patra","sequence":"additional","affiliation":[{"name":"Department of Chemistry, National Institute of Technology Durgapur, Mahatma Gandhi Avenue, Durgapur 713209, India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D4NR03578J\/cit1a\/1","doi-asserted-by":"crossref","first-page":"145","DOI":"10.1098\/rstl.1857.0011","volume":"147","author":"Faraday","year":"1857","journal-title":"Philos. Trans. R. Soc. London"},{"key":"D4NR03578J\/cit1b\/1","doi-asserted-by":"crossref","first-page":"442","DOI":"10.1111\/j.1151-2916.2001.tb00674.x","volume":"84","author":"P\u00e9rez-Arantegui","year":"2001","journal-title":"J. Am. Ceram. Soc."},{"key":"D4NR03578J\/cit1c\/1","doi-asserted-by":"crossref","first-page":"834","DOI":"10.1021\/acs.chemrev.0c00237","volume":"121","author":"Gao","year":"2021","journal-title":"Chem. Rev."},{"key":"D4NR03578J\/cit1d\/1","doi-asserted-by":"crossref","first-page":"12208","DOI":"10.1021\/acs.chemrev.9b00234","volume":"119","author":"Ha","year":"2019","journal-title":"Chem. Rev."},{"key":"D4NR03578J\/cit1e\/1","doi-asserted-by":"crossref","first-page":"9243","DOI":"10.1021\/acs.chemrev.0c01176","volume":"121","author":"Algar","year":"2021","journal-title":"Chem. Rev."},{"key":"D4NR03578J\/cit2a\/1","doi-asserted-by":"crossref","first-page":"10346","DOI":"10.1021\/acs.chemrev.5b00703","volume":"116","author":"Jin","year":"2016","journal-title":"Chem. Rev."},{"key":"D4NR03578J\/cit2b\/1","doi-asserted-by":"crossref","first-page":"8208","DOI":"10.1021\/acs.chemrev.6b00769","volume":"117","author":"Chakraborty","year":"2017","journal-title":"Chem. Rev."},{"key":"D4NR03578J\/cit2c\/1","doi-asserted-by":"crossref","first-page":"3722","DOI":"10.1021\/acs.chemrev.5b00482","volume":"116","author":"Gawande","year":"2016","journal-title":"Chem. Rev."},{"key":"D4NR03578J\/cit2d\/1","doi-asserted-by":"crossref","first-page":"2475","DOI":"10.1021\/acs.accounts.8b00349","volume":"51","author":"Sharma","year":"2018","journal-title":"Acc. Chem. Res."},{"key":"D4NR03578J\/cit2e\/1","doi-asserted-by":"crossref","first-page":"5865","DOI":"10.1021\/acs.chemrev.6b00376","volume":"117","author":"Coughlan","year":"2017","journal-title":"Chem. Rev."},{"key":"D4NR03578J\/cit3a\/1","doi-asserted-by":"crossref","first-page":"10410","DOI":"10.1021\/acs.chemrev.5b00193","volume":"115","author":"Yang","year":"2015","journal-title":"Chem. Rev."},{"key":"D4NR03578J\/cit3b\/1","doi-asserted-by":"crossref","first-page":"1269","DOI":"10.1039\/D0CS01112F","volume":"50","author":"Montes-Garc\u00eda","year":"2021","journal-title":"Chem. Soc. Rev."},{"key":"D4NR03578J\/cit3c\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1155\/2012\/751075","author":"Conde","year":"2012","journal-title":"J. Drug Delivery"},{"key":"D4NR03578J\/cit3d\/1","doi-asserted-by":"crossref","first-page":"5605","DOI":"10.1016\/j.biomaterials.2014.03.062","volume":"35","author":"Penga","year":"2014","journal-title":"Biomaterials"},{"key":"D4NR03578J\/cit3e\/1","doi-asserted-by":"crossref","first-page":"6087","DOI":"10.1039\/D0CS00338G","volume":"49","author":"Wilson","year":"2020","journal-title":"Chem. Soc. Rev."},{"key":"D4NR03578J\/cit3f\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1080\/14686996.2023.2222546","volume":"24","author":"Antoine","year":"2023","journal-title":"Sci. Technol. Adv. Mater."},{"key":"D4NR03578J\/cit3g\/1","doi-asserted-by":"crossref","first-page":"784","DOI":"10.1126\/science.adh2365","volume":"381","author":"Wang","year":"2023","journal-title":"Science"},{"key":"D4NR03578J\/cit3h\/1","doi-asserted-by":"crossref","first-page":"2376","DOI":"10.1002\/anie.201307480","volume":"53","author":"Wang","year":"2014","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4NR03578J\/cit4\/1","doi-asserted-by":"crossref","first-page":"13319","DOI":"10.1021\/jacs.5b07574","volume":"137","author":"Nguyen","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"D4NR03578J\/cit5\/1","doi-asserted-by":"crossref","first-page":"14704","DOI":"10.1002\/anie.201608609","volume":"55","author":"Chakrahari","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4NR03578J\/cit6a\/1","doi-asserted-by":"crossref","first-page":"1900833","DOI":"10.1002\/advs.201900833","volume":"6","author":"Li","year":"2019","journal-title":"Adv. Sci."},{"key":"D4NR03578J\/cit6b\/1","doi-asserted-by":"crossref","first-page":"18789","DOI":"10.1021\/acsnano.2c07521","volume":"16","author":"Huang","year":"2022","journal-title":"ACS Nano"},{"key":"D4NR03578J\/cit7\/1","doi-asserted-by":"crossref","first-page":"394","DOI":"10.1021\/jacs.7b10960","volume":"140","author":"Cook","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"D4NR03578J\/cit8\/1","doi-asserted-by":"crossref","first-page":"8385","DOI":"10.1021\/acs.chemmater.6b03879","volume":"28","author":"Nguyen","year":"2016","journal-title":"Chem. Mater."},{"key":"D4NR03578J\/cit9\/1","doi-asserted-by":"crossref","first-page":"835","DOI":"10.1002\/anie.201812236","volume":"58","author":"Yuan","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4NR03578J\/cit10\/1","doi-asserted-by":"crossref","first-page":"297","DOI":"10.1021\/acsmaterialslett.9b00122","volume":"1","author":"Ghosh","year":"2019","journal-title":"ACS Mater. Lett."},{"key":"D4NR03578J\/cit11\/1","doi-asserted-by":"crossref","first-page":"5834","DOI":"10.1021\/jacs.0c01053","volume":"142","author":"Han","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"D4NR03578J\/cit12\/1","doi-asserted-by":"crossref","first-page":"10355","DOI":"10.1021\/jacs.3c02215","volume":"145","author":"Jia","year":"2023","journal-title":"J. Am. Chem. Soc."},{"key":"D4NR03578J\/cit13\/1","doi-asserted-by":"crossref","first-page":"7616","DOI":"10.1039\/D2SC02544B","volume":"13","author":"Das","year":"2022","journal-title":"Chem. Sci."},{"key":"D4NR03578J\/cit14a\/1","doi-asserted-by":"crossref","first-page":"47","DOI":"10.1186\/s11671-021-03480-8","volume":"16","author":"Habibullah","year":"2021","journal-title":"Nanoscale Res. Lett."},{"key":"D4NR03578J\/cit14b\/1","doi-asserted-by":"crossref","first-page":"3201","DOI":"10.1038\/s41467-023-38955-y","volume":"14","author":"Kim","year":"2023","journal-title":"Nat. Commun."},{"key":"D4NR03578J\/cit15\/1","doi-asserted-by":"crossref","first-page":"1923","DOI":"10.1007\/s10876-015-0921-7","volume":"26","author":"Teo","year":"2015","journal-title":"J. Cluster Sci."},{"key":"D4NR03578J\/cit16\/1","doi-asserted-by":"crossref","first-page":"1600126","DOI":"10.1002\/advs.201600126","volume":"3","author":"Gao","year":"2016","journal-title":"Adv. Sci."},{"key":"D4NR03578J\/cit17\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.ccr.2017.02.016","volume":"338","author":"Haiduc","year":"2017","journal-title":"Coord. Chem. Rev."},{"key":"D4NR03578J\/cit17\/2","doi-asserted-by":"crossref","first-page":"71","DOI":"10.1016\/j.ccr.2017.08.012","volume":"338","author":"Haiduc","year":"2017","journal-title":"Coord. Chem. Rev."},{"key":"D4NR03578J\/cit18a\/1","doi-asserted-by":"crossref","first-page":"574","DOI":"10.1002\/anie.200352636","volume":"43","author":"Mezei","year":"2004","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4NR03578J\/cit18b\/1","doi-asserted-by":"crossref","first-page":"15002","DOI":"10.1039\/C4CC07582J","volume":"50","author":"Kostopoulos","year":"2014","journal-title":"Chem. Commun."},{"key":"D4NR03578J\/cit18c\/1","doi-asserted-by":"crossref","first-page":"1598","DOI":"10.1039\/B403735A","author":"Murugesu","year":"2004","journal-title":"Chem. Commun."},{"key":"D4NR03578J\/cit18d\/1","doi-asserted-by":"crossref","first-page":"7269","DOI":"10.1021\/ic0487171","volume":"43","author":"Murugesu","year":"2004","journal-title":"Inorg. Chem."},{"key":"D4NR03578J\/cit18e\/1","doi-asserted-by":"crossref","first-page":"3554","DOI":"10.1039\/c002925b","volume":"39","author":"Liu","year":"2010","journal-title":"Dalton Trans."},{"key":"D4NR03578J\/cit19a\/1","doi-asserted-by":"crossref","first-page":"6899","DOI":"10.1002\/anie.201001301","volume":"49","author":"Fu","year":"2010","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4NR03578J\/cit19b\/1","doi-asserted-by":"crossref","first-page":"20937","DOI":"10.1021\/jacs.4c05678","volume":"146","author":"Biswas","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"D4NR03578J\/cit19c\/1","doi-asserted-by":"crossref","first-page":"14704","DOI":"10.1002\/anie.201608609","volume":"55","author":"Chakrahari","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4NR03578J\/cit19d\/1","doi-asserted-by":"crossref","first-page":"7214","DOI":"10.1002\/anie.201403324","volume":"53","author":"Edwards","year":"2014","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4NR03578J\/cit19e\/1","doi-asserted-by":"crossref","first-page":"4704","DOI":"10.1021\/ja401576s","volume":"135","author":"Dhayal","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"D4NR03578J\/cit19f\/1","doi-asserted-by":"crossref","first-page":"8369","DOI":"10.1002\/chem.201501122","volume":"21","author":"Dhayal","year":"2015","journal-title":"Chem. \u2013 Eur. J."},{"key":"D4NR03578J\/cit20a\/1","doi-asserted-by":"crossref","first-page":"3334","DOI":"10.1039\/C6CC08301C","volume":"53","author":"Maji","year":"2017","journal-title":"Chem. Commun."},{"key":"D4NR03578J\/cit20b\/1","doi-asserted-by":"crossref","first-page":"5779","DOI":"10.1021\/acs.inorgchem.1c00075","volume":"60","author":"Mishra","year":"2021","journal-title":"Inorg. Chem."},{"key":"D4NR03578J\/cit20c\/1","doi-asserted-by":"crossref","first-page":"4503","DOI":"10.1002\/anie.201008076","volume":"50","author":"Neuba","year":"2011","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4NR03578J\/cit20d\/1","doi-asserted-by":"crossref","first-page":"25673","DOI":"10.1021\/jacs.3c08549","volume":"145","author":"Xu","year":"2023","journal-title":"J. Am. Chem. Soc."},{"key":"D4NR03578J\/cit20e\/1","doi-asserted-by":"crossref","first-page":"87","DOI":"10.1002\/anie.200352350","volume":"43","author":"Mukherjee","year":"2004","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4NR03578J\/cit21\/1","doi-asserted-by":"crossref","first-page":"13365","DOI":"10.1021\/acsnano.9b06740","volume":"13","author":"Dar","year":"2019","journal-title":"ACS Nano"},{"key":"D4NR03578J\/cit22\/1","doi-asserted-by":"crossref","first-page":"5151","DOI":"10.1039\/C9NR01058K","volume":"11","author":"Li","year":"2019","journal-title":"Nanoscale"},{"key":"D4NR03578J\/cit23\/1","doi-asserted-by":"crossref","first-page":"332","DOI":"10.1021\/acsorginorgau.3c00038","volume":"3","author":"Ganguly","year":"2023","journal-title":"ACS Org. Inorg. Au"},{"key":"D4NR03578J\/cit24\/1","doi-asserted-by":"crossref","first-page":"9177","DOI":"10.1002\/anie.202001363","volume":"59","author":"Bhandari","year":"2020","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4NR03578J\/cit25\/1","first-page":"553","volume":"5","author":"Varotsis","year":"2020","journal-title":"Aspects Min. Miner. Sci."},{"key":"D4NR03578J\/cit26\/1","doi-asserted-by":"crossref","first-page":"1427","DOI":"10.1007\/s11244-022-01775-3","volume":"66","author":"Christophliemk","year":"2023","journal-title":"Top. Catal."},{"key":"D4NR03578J\/cit27\/1","doi-asserted-by":"crossref","first-page":"6785","DOI":"10.1039\/C8SC01508B","volume":"9","author":"Chakrahari","year":"2018","journal-title":"Chem. Sci."},{"key":"D4NR03578J\/cit28\/1","doi-asserted-by":"crossref","first-page":"168","DOI":"10.1039\/b008034i","volume":"31","author":"Brunschwig","year":"2002","journal-title":"Chem. Soc. Rev."},{"key":"D4NR03578J\/cit29a\/1","doi-asserted-by":"crossref","first-page":"9232","DOI":"10.1021\/ja00049a091","volume":"114","author":"Kitajima","year":"1992","journal-title":"J. Am. Chem. Soc."},{"key":"D4NR03578J\/cit29b\/1","doi-asserted-by":"crossref","first-page":"11620","DOI":"10.1021\/ja001591w","volume":"122","author":"Randall","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"D4NR03578J\/cit30a\/1","doi-asserted-by":"crossref","first-page":"5548","DOI":"10.1002\/ejic.200700784","author":"Maiti","year":"2007","journal-title":"Eur. J. Inorg. Chem."},{"key":"D4NR03578J\/cit30b\/1","doi-asserted-by":"crossref","first-page":"275","DOI":"10.1016\/0020-1693(94)04096-6","volume":"226","author":"Green","year":"1994","journal-title":"Inorg. Chim. Acta"},{"key":"D4NR03578J\/cit31\/1","doi-asserted-by":"crossref","first-page":"1325","DOI":"10.1002\/sia.6239","volume":"49","author":"Biesinger","year":"2017","journal-title":"Surf. Interface Anal."},{"key":"D4NR03578J\/cit32a\/1","doi-asserted-by":"crossref","first-page":"18771","DOI":"10.1021\/acs.jpcc.7b06563","volume":"121","author":"Benito","year":"2017","journal-title":"J. Phys. Chem. C"},{"key":"D4NR03578J\/cit32b\/1","doi-asserted-by":"crossref","first-page":"19324","DOI":"10.1039\/C9TA05846J","volume":"7","author":"Li","year":"2019","journal-title":"J. Mater. Chem. A"},{"key":"D4NR03578J\/cit33\/1","doi-asserted-by":"crossref","first-page":"75953","DOI":"10.1039\/C5RA14915K","volume":"5","author":"Fantauzzi","year":"2015","journal-title":"RSC Adv."},{"key":"D4NR03578J\/cit34a\/1","doi-asserted-by":"crossref","first-page":"7809","DOI":"10.1039\/D3DT00902E","volume":"52","author":"Bruschi","year":"2023","journal-title":"Dalton Trans."},{"key":"D4NR03578J\/cit34b\/1","doi-asserted-by":"crossref","first-page":"e202200121","DOI":"10.1002\/chem.202200121","volume":"28","author":"Tran","year":"2022","journal-title":"Chem. \u2013 Eur. J."},{"key":"D4NR03578J\/cit35\/1","doi-asserted-by":"crossref","first-page":"6549","DOI":"10.1039\/C8DT00413G","volume":"47","author":"Cariello","year":"2018","journal-title":"Dalton Trans."}],"container-title":["Nanoscale"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/NR\/D4NR03578J","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T05:48:43Z","timestamp":1782884923000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/nr\/article\/17\/2\/982-991\/860044"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025]]},"references-count":70,"journal-issue":{"issue":"2","published-print":{"date-parts":[[2025,1,2]]}},"URL":"https:\/\/doi.org\/10.1039\/d4nr03578j","relation":{},"ISSN":["2040-3364","2040-3372"],"issn-type":[{"value":"2040-3364","type":"print"},{"value":"2040-3372","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025]]}}}