{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,23]],"date-time":"2026-08-23T15:54:10Z","timestamp":1787500450240,"version":"build-2736575974"},"reference-count":29,"publisher":"Royal Society of Chemistry (RSC)","issue":"25","license":[{"start":{"date-parts":[[2025,6,6]],"date-time":"2025-06-06T00:00:00Z","timestamp":1749168000000},"content-version":"am","delay-in-days":522,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100005230","name":"Natural Science Foundation of Chongqing Municipality","doi-asserted-by":"publisher","award":["CSTB2022BSXM-JSX0012"],"award-info":[{"award-number":["CSTB2022BSXM-JSX0012"]}],"id":[{"id":"10.13039\/501100005230","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Org. Biomol. Chem."],"abstract":"<jats:p>We introduce a novel method for the selective reduction of \u03b1,\u03b2-unsaturated ketones, employing a cheap and air-stable silane (PMHS) with catalytic iron salt. This system achieves excellent results on a broad substrate scope under mild conditions.<\/jats:p>","DOI":"10.1039\/d4ob00664j","type":"journal-article","created":{"date-parts":[[2024,6,6]],"date-time":"2024-06-06T02:01:35Z","timestamp":1717639295000},"page":"5097-5100","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Highly efficient iron-catalyzed conjugate reduction of \u03b1,\u03b2-unsaturated ketones with polymethylhydrosiloxane"],"prefix":"10.1039","volume":"22","author":[{"given":"Hang","family":"Wang","sequence":"first","affiliation":[{"name":"College of Chemistry, Chongqing Normal University, Chongqing 401331, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Libo","family":"Chen","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering, Chongqing University of Science and Technology, Chongqing 401331, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4157-8709","authenticated-orcid":false,"given":"Yushuang","family":"Chen","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering, Chongqing University of Science and Technology, Chongqing 401331, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7182-2544","authenticated-orcid":false,"given":"Yulong","family":"Zhang","sequence":"additional","affiliation":[{"name":"College of Chemistry, Chongqing Normal University, Chongqing 401331, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2024]]},"reference":[{"key":"D4OB00664J\/cit1a\/1","doi-asserted-by":"crossref","first-page":"11274","DOI":"10.1021\/acs.inorgchem.9b01377","volume":"58","author":"Das","year":"2019","journal-title":"Inorg. Chem."},{"key":"D4OB00664J\/cit1b\/1","doi-asserted-by":"crossref","first-page":"2757","DOI":"10.1002\/cctc.201900385","volume":"11","author":"Zhang","year":"2019","journal-title":"ChemCatChem"},{"key":"D4OB00664J\/cit2a\/1","doi-asserted-by":"crossref","first-page":"708","DOI":"10.2174\/1570193X20666221021104906","volume":"20","author":"Alam","year":"2023","journal-title":"Mini-Rev. Org. Chem."},{"key":"D4OB00664J\/cit2b\/1","doi-asserted-by":"crossref","first-page":"2662","DOI":"10.1039\/C9GC00705A","volume":"21","author":"Hein","year":"2019","journal-title":"Green Chem."},{"key":"D4OB00664J\/cit3\/1","doi-asserted-by":"crossref","first-page":"6685","DOI":"10.1039\/C6CS00244G","volume":"45","author":"Volkov","year":"2016","journal-title":"Chem. Soc. Rev."},{"key":"D4OB00664J\/cit4a\/1","doi-asserted-by":"crossref","first-page":"2783","DOI":"10.1021\/ja01473a053","volume":"83","author":"Stork","year":"1961","journal-title":"J. Am. Chem. Soc."},{"key":"D4OB00664J\/cit4b\/1","doi-asserted-by":"crossref","first-page":"2965","DOI":"10.1021\/ja01474a051","volume":"83","author":"Stork","year":"1961","journal-title":"J. Am. Chem. Soc."},{"key":"D4OB00664J\/cit5a\/1","doi-asserted-by":"crossref","first-page":"3279","DOI":"10.1021\/ol061147j","volume":"8","author":"Mori","year":"2006","journal-title":"Org. Lett."},{"key":"D4OB00664J\/cit5b\/1","doi-asserted-by":"crossref","first-page":"354","DOI":"10.1002\/adsc.200505315","volume":"348","author":"Sharma","year":"2006","journal-title":"Adv. Synth. Catal."},{"key":"D4OB00664J\/cit5c\/1","doi-asserted-by":"crossref","first-page":"2981","DOI":"10.1021\/jo100256t","volume":"75","author":"Li","year":"2010","journal-title":"J. Org. Chem."},{"key":"D4OB00664J\/cit5d\/1","doi-asserted-by":"crossref","first-page":"11076","DOI":"10.1002\/chem.200801568","volume":"14","author":"Himeda","year":"2008","journal-title":"Chem. \u2013 Eur. J."},{"key":"D4OB00664J\/cit5e\/1","doi-asserted-by":"crossref","first-page":"429","DOI":"10.1021\/om060892x","volume":"26","author":"Mebi","year":"2007","journal-title":"Organometallics"},{"key":"D4OB00664J\/cit6\/1","doi-asserted-by":"crossref","first-page":"5573","DOI":"10.1021\/acs.orglett.8b02244","volume":"20","author":"Li","year":"2018","journal-title":"Org. Lett."},{"key":"D4OB00664J\/cit7a\/1","doi-asserted-by":"crossref","first-page":"e202216649","DOI":"10.1002\/anie.202216649","volume":"62","author":"Lonardi","year":"2023","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4OB00664J\/cit7b\/1","doi-asserted-by":"crossref","first-page":"1755","DOI":"10.1039\/B418586B","author":"Kim","year":"2005","journal-title":"Chem. Commun."},{"key":"D4OB00664J\/cit7c\/1","doi-asserted-by":"crossref","first-page":"9187","DOI":"10.1039\/C9RA01203F","volume":"9","author":"Li","year":"2019","journal-title":"RSC Adv."},{"key":"D4OB00664J\/cit7d\/1","doi-asserted-by":"crossref","first-page":"4861","DOI":"10.1002\/ejoc.202100856","author":"Lu","year":"2021","journal-title":"Eur. J. Org. Chem."},{"key":"D4OB00664J\/cit7e\/1","doi-asserted-by":"crossref","first-page":"3288","DOI":"10.1016\/j.tetlet.2018.07.041","volume":"59","author":"Syamala","year":"2018","journal-title":"Tetrahedron Lett."},{"key":"D4OB00664J\/cit8\/1","doi-asserted-by":"crossref","first-page":"1650","DOI":"10.1039\/b603610b","volume":"4","author":"Chandrasekhar","year":"2006","journal-title":"Org. Biomol. Chem."},{"key":"D4OB00664J\/cit9\/1","doi-asserted-by":"crossref","first-page":"6143","DOI":"10.1039\/c1ob05352c","volume":"9","author":"Li","year":"2011","journal-title":"Org. Biomol. Chem."},{"key":"D4OB00664J\/cit10\/1","doi-asserted-by":"crossref","first-page":"2809","DOI":"10.1002\/ejoc.201200020","author":"Shang","year":"2012","journal-title":"Eur. J. Org. Chem."},{"key":"D4OB00664J\/cit11a\/1","doi-asserted-by":"crossref","first-page":"2497","DOI":"10.1002\/anie.200705624","volume":"47","author":"Shaikh","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4OB00664J\/cit11b\/1","doi-asserted-by":"crossref","first-page":"1687","DOI":"10.1002\/asia.201000064","volume":"5","author":"Addis","year":"2010","journal-title":"Chem. - Asian J."},{"key":"D4OB00664J\/cit11c\/1","doi-asserted-by":"crossref","first-page":"2550","DOI":"10.1021\/acs.chemrev.8b00372","volume":"119","author":"Wei","year":"2019","journal-title":"Chem. Rev."},{"key":"D4OB00664J\/cit12a\/1","doi-asserted-by":"crossref","first-page":"5429","DOI":"10.1021\/ol7021802","volume":"9","author":"Shaikh","year":"2007","journal-title":"Org. Lett."},{"key":"D4OB00664J\/cit12b\/1","first-page":"276","author":"Zotto","year":"2009","journal-title":"Synlett"},{"key":"D4OB00664J\/cit12c\/1","doi-asserted-by":"crossref","first-page":"748","DOI":"10.1002\/aoc.1832","volume":"25","author":"Buitrago","year":"2011","journal-title":"Appl. Organomet. Chem."},{"key":"D4OB00664J\/cit13a\/1","doi-asserted-by":"crossref","first-page":"9473","DOI":"10.1021\/ja992366l","volume":"121","author":"Appella","year":"1999","journal-title":"J. Am. Chem. Soc."},{"key":"D4OB00664J\/cit13b\/1","doi-asserted-by":"crossref","first-page":"11253","DOI":"10.1021\/ja0351692","volume":"125","author":"Hughes","year":"2003","journal-title":"J. Am. Chem. Soc."}],"container-title":["Organic &amp; Biomolecular Chemistry"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2024\/OB\/D4OB00664J","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T04:09:02Z","timestamp":1782965342000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/ob\/article\/22\/25\/5097-5100\/861283"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024]]},"references-count":29,"journal-issue":{"issue":"25","published-print":{"date-parts":[[2024,6,26]]}},"URL":"https:\/\/doi.org\/10.1039\/d4ob00664j","relation":{},"ISSN":["1477-0520","1477-0539"],"issn-type":[{"value":"1477-0520","type":"print"},{"value":"1477-0539","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024]]}}}