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Biomol. Chem."],"abstract":"<jats:p>We present a base- and additive-free synthesis of \u03b2-aminoketones from allyl alcohols at room temperature. Furthermore, the BINOL phosphoric acid-coordinated palladacycle, which is believed to be the active species in the reaction, was identified.<\/jats:p>","DOI":"10.1039\/d4ob01232a","type":"journal-article","created":{"date-parts":[[2024,9,23]],"date-time":"2024-09-23T02:21:02Z","timestamp":1727058062000},"page":"8488-8492","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Pyrazole based palladacycles for the synthesis of \u03b2-aminoketones by redox coupling of allyl alcohols and anilines"],"prefix":"10.1039","volume":"22","author":[{"given":"Shaikh","family":"Samser","sequence":"first","affiliation":[{"name":"School of Chemical Sciences, National Institute of Science Education and Research (NISER), Bhubaneswar, an OCC of Homi Bhabha National Institute, Bhubaneswar 752050, Odisha, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Priyabrata","family":"Biswal","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences, National Institute of Science Education and Research (NISER), Bhubaneswar, an OCC of Homi Bhabha National Institute, Bhubaneswar 752050, Odisha, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0399-4437","authenticated-orcid":false,"given":"Ramesh","family":"Mamidala","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences, National Institute of Science Education and Research (NISER), Bhubaneswar, an OCC of Homi Bhabha National Institute, Bhubaneswar 752050, Odisha, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sushanta Kumar","family":"Meher","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences, National Institute of Science Education and Research (NISER), Bhubaneswar, an OCC of Homi Bhabha National Institute, Bhubaneswar 752050, Odisha, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4858-8590","authenticated-orcid":false,"given":"Krishnan","family":"Venkatasubbaiah","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences, National Institute of Science Education and Research (NISER), Bhubaneswar, an OCC of Homi Bhabha National Institute, Bhubaneswar 752050, Odisha, India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2024]]},"reference":[{"key":"D4OB01232A\/cit1\/1","doi-asserted-by":"crossref","first-page":"1844","DOI":"10.1002\/anie.199518441","volume":"34","author":"Herrmann","year":"1995","journal-title":"Angew. 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