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Sci."],"abstract":"<jats:p>\n                    An axially-chiral boramidine displays UV-absorption, deep-blue fluorescence (\n                    <jats:italic>\u03a6<\/jats:italic>\n                    up to 94%), and |10\n                    <jats:sup>\u22123<\/jats:sup>\n                    |\n                    <jats:italic>g<\/jats:italic>\n                    <jats:sub>abs<\/jats:sub>\n                    and\n                    <jats:italic>g<\/jats:italic>\n                    <jats:sub>lum<\/jats:sub>\n                    . Deactivation pathways of the emissive state to triplet excited states, involving increased spin\u2013orbit coupling, are identified.\n                  <\/jats:p>","DOI":"10.1039\/d4sc00870g","type":"journal-article","created":{"date-parts":[[2024,4,2]],"date-time":"2024-04-02T11:02:49Z","timestamp":1712055769000},"page":"6530-6535","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Axially-chiral boramidine for detailed (chir)optical studies"],"prefix":"10.1039","volume":"15","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9025-4095","authenticated-orcid":false,"given":"Nidal","family":"Saleh","sequence":"first","affiliation":[{"name":"Department of Organic Chemistry, University of Geneva, Quai Ernest Ansermet 30, 1211 Geneva 4, Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Estefan\u00eda","family":"Sucre-Rosales","sequence":"additional","affiliation":[{"name":"Department of Physical Chemistry, University of Geneva, Quai Ernest Ansermet 30, 1211 Geneva 4, Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6331-6219","authenticated-orcid":false,"given":"Francesco","family":"Zinna","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica e Chimica Industriale, University of Pisa, Via G. 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