{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T21:03:23Z","timestamp":1788296603435,"version":"build-2803163510"},"reference-count":36,"publisher":"Royal Society of Chemistry (RSC)","issue":"32","license":[{"start":{"date-parts":[[2024,7,12]],"date-time":"2024-07-12T00:00:00Z","timestamp":1720742400000},"content-version":"vor","delay-in-days":193,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21971093"],"award-info":[{"award-number":["21971093"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["lzujbky-2021-sp53"],"award-info":[{"award-number":["lzujbky-2021-sp53"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100015816","name":"International Joint Research Center for Green Catalysis and Synthesis","doi-asserted-by":"publisher","award":["2016B01017"],"award-info":[{"award-number":["2016B01017"]}],"id":[{"id":"10.13039\/100015816","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100015910","name":"E.B. Eddy Endowment Fund","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100015910","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100018554","name":"Science and Technology Program of Gansu Province","doi-asserted-by":"publisher","award":["22ZD6FA006"],"award-info":[{"award-number":["22ZD6FA006"]}],"id":[{"id":"10.13039\/501100018554","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001804","name":"Canada Research Chairs","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001804","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000196","name":"Canada Foundation for Innovation","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100000196","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000038","name":"Natural Sciences and Engineering Research Council of Canada","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100000038","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003150","name":"Fonds Qu\u00e9b\u00e9cois de la Recherche sur la Nature et les Technologies","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100003150","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Sci."],"abstract":"<jats:p>We present a novel photo-induced approach that does not rely on transition metals or photosensitizers to drive C\u2013C and C\u2013N \u03c3-bond metathesis reactions. This method enables the cross-coupling of tertiary amines with \u03b1-diketones.<\/jats:p>","DOI":"10.1039\/d4sc02412e","type":"journal-article","created":{"date-parts":[[2024,7,11]],"date-time":"2024-07-11T21:01:20Z","timestamp":1720731680000},"page":"12900-12905","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":21,"title":["Intermolecular C\u2013C\/C\u2013N \u03c3-bond metathesis enabled by visible light"],"prefix":"10.1039","volume":"15","author":[{"given":"Rujuan","family":"Li","sequence":"first","affiliation":[{"name":"The State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 Tianshui Road, Lanzhou, 730000, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Renqin","family":"Zhan","sequence":"additional","affiliation":[{"name":"The State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 Tianshui Road, Lanzhou, 730000, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yatao","family":"Lang","sequence":"additional","affiliation":[{"name":"The State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 Tianshui Road, Lanzhou, 730000, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3859-8824","authenticated-orcid":false,"given":"Chao-Jun","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Chemistry, and FRQNT Centre for Green Chemistry and Catalysis, McGill University, 801 Sherbrooke St. West, Montreal, QC H3A 0B8, Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2535-111X","authenticated-orcid":false,"given":"Huiying","family":"Zeng","sequence":"additional","affiliation":[{"name":"The State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 Tianshui Road, Lanzhou, 730000, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2024]]},"reference":[{"key":"D4SC02412E\/cit1a\/1","doi-asserted-by":"crossref","first-page":"3740","DOI":"10.1002\/anie.200601234","volume":"45","author":"Chauvin","year":"2006","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4SC02412E\/cit1b\/1","doi-asserted-by":"crossref","first-page":"3708","DOI":"10.1021\/cr800524f","volume":"109","author":"Samoj\u0142owicz","year":"2009","journal-title":"Chem. Rev."},{"key":"D4SC02412E\/cit1c\/1","doi-asserted-by":"crossref","first-page":"4763","DOI":"10.1021\/jo500467z","volume":"79","author":"Hoveyda","year":"2014","journal-title":"J. Org. Chem."},{"key":"D4SC02412E\/cit2a\/1","doi-asserted-by":"crossref","first-page":"693","DOI":"10.1021\/ja210225e","volume":"134","author":"Keitz","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"D4SC02412E\/cit2b\/1","doi-asserted-by":"crossref","first-page":"94","DOI":"10.1021\/ja311241q","volume":"135","author":"Marx","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"D4SC02412E\/cit2c\/1","doi-asserted-by":"crossref","first-page":"12438","DOI":"10.1021\/ja3056722","volume":"134","author":"Khan","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"D4SC02412E\/cit2d\/1","doi-asserted-by":"crossref","first-page":"9022","DOI":"10.1002\/chem.201801651","volume":"24","author":"Schnabel","year":"2018","journal-title":"Chem.\u2013Eur. J."},{"key":"D4SC02412E\/cit3a\/1","doi-asserted-by":"crossref","first-page":"4510","DOI":"10.1039\/C8CS00027A","volume":"47","author":"Ogba","year":"2018","journal-title":"Chem. Soc. Rev."},{"key":"D4SC02412E\/cit3b\/1","doi-asserted-by":"crossref","first-page":"10410","DOI":"10.1002\/anie.201604349","volume":"55","author":"Ma","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4SC02412E\/cit3c\/1","doi-asserted-by":"crossref","first-page":"3917","DOI":"10.1039\/C9QO01008D","volume":"6","author":"Chen","year":"2019","journal-title":"Org. Chem. Front."},{"key":"D4SC02412E\/cit4a\/1","doi-asserted-by":"crossref","first-page":"2794","DOI":"10.1002\/anie.201204513","volume":"52","author":"F\u00fcrstner","year":"2013","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4SC02412E\/cit4b\/1","doi-asserted-by":"crossref","first-page":"1812","DOI":"10.1021\/om060116p","volume":"25","author":"Zhu","year":"2006","journal-title":"Organometallics"},{"key":"D4SC02412E\/cit5\/1","doi-asserted-by":"crossref","first-page":"191","DOI":"10.1016\/0022-328X(90)85227-P","volume":"382","author":"Schwager","year":"1990","journal-title":"J. Organomet. Chem."},{"key":"D4SC02412E\/cit6a\/1","doi-asserted-by":"crossref","first-page":"1059","DOI":"10.1126\/science.aam9041","volume":"356","author":"Lian","year":"2017","journal-title":"Science"},{"key":"D4SC02412E\/cit6b\/1","doi-asserted-by":"crossref","first-page":"4177","DOI":"10.1021\/acs.orglett.9b01355","volume":"21","author":"Fujimoto","year":"2019","journal-title":"Org. Lett."},{"key":"D4SC02412E\/cit7\/1","doi-asserted-by":"crossref","first-page":"3230","DOI":"10.1021\/ol301280u","volume":"14","author":"Ishida","year":"2012","journal-title":"Org. Lett."},{"key":"D4SC02412E\/cit8a\/1","doi-asserted-by":"crossref","first-page":"6940","DOI":"10.1002\/anie.201802563","volume":"57","author":"Biberger","year":"2018","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4SC02412E\/cit8b\/1","doi-asserted-by":"crossref","first-page":"11850","DOI":"10.1002\/anie.202004002","volume":"59","author":"Wang","year":"2020","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4SC02412E\/cit9a\/1","doi-asserted-by":"crossref","first-page":"1016","DOI":"10.1038\/s41557-018-0078-8","volume":"10","author":"Lee","year":"2018","journal-title":"Nat. Chem."},{"key":"D4SC02412E\/cit9b\/1","doi-asserted-by":"crossref","first-page":"10140","DOI":"10.1021\/jacs.8b06605","volume":"140","author":"De La Higuera Macias","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"D4SC02412E\/cit10\/1","doi-asserted-by":"crossref","first-page":"3723","DOI":"10.1021\/jacs.1c00529","volume":"143","author":"Delcaillau","year":"2021","journal-title":"J. Am. Chem. Soc."},{"key":"D4SC02412E\/cit11\/1","doi-asserted-by":"crossref","first-page":"836","DOI":"10.1038\/s41557-021-00757-4","volume":"13","author":"Zhu","year":"2021","journal-title":"Nat. Chem."},{"key":"D4SC02412E\/cit12a\/1","doi-asserted-by":"crossref","first-page":"698","DOI":"10.1039\/D1SC06278F","volume":"13","author":"Wang","year":"2022","journal-title":"Chem. Sci."},{"key":"D4SC02412E\/cit12b\/1","doi-asserted-by":"crossref","first-page":"7165","DOI":"10.1039\/D2SC01909D","volume":"13","author":"Pan","year":"2022","journal-title":"Chem. Sci."},{"key":"D4SC02412E\/cit12c\/1","doi-asserted-by":"crossref","first-page":"3594","DOI":"10.1039\/D1QO00359C","volume":"8","author":"Lang","year":"2021","journal-title":"Org. Chem. Front."},{"key":"D4SC02412E\/cit12d\/1","doi-asserted-by":"crossref","first-page":"5740","DOI":"10.1039\/D0SC01585G","volume":"11","author":"Dou","year":"2020","journal-title":"Chem. Sci."},{"key":"D4SC02412E\/cit12e\/1","doi-asserted-by":"crossref","first-page":"6323","DOI":"10.1039\/D0GC01649G","volume":"22","author":"Lang","year":"2020","journal-title":"Green Chem."},{"key":"D4SC02412E\/cit12f\/1","doi-asserted-by":"crossref","first-page":"767","DOI":"10.1039\/C8CC08942F","volume":"55","author":"Cao","year":"2019","journal-title":"Chem. Commun."},{"key":"D4SC02412E\/cit12g\/1","doi-asserted-by":"crossref","first-page":"1301","DOI":"10.1021\/acs.orglett.8b04081","volume":"21","author":"Zeng","year":"2019","journal-title":"Org. Lett."},{"key":"D4SC02412E\/cit12h\/1","doi-asserted-by":"crossref","first-page":"742","DOI":"10.1016\/j.fmre.2021.06.018","volume":"1","author":"Dou","year":"2021","journal-title":"Fundam. Res."},{"key":"D4SC02412E\/cit12i\/1","doi-asserted-by":"crossref","first-page":"303","DOI":"10.1016\/j.gresc.2021.04.006","volume":"2","author":"Cao","year":"2021","journal-title":"Green Synth. Catal."},{"key":"D4SC02412E\/cit12j\/1","doi-asserted-by":"crossref","first-page":"8429","DOI":"10.1039\/D1CC03496K","volume":"57","author":"Dou","year":"2021","journal-title":"Chem. Commun."},{"key":"D4SC02412E\/cit12k\/1","doi-asserted-by":"crossref","first-page":"8818","DOI":"10.1039\/D2OB01524B","volume":"20","author":"Dou","year":"2022","journal-title":"Org. Biomol. Chem."},{"key":"D4SC02412E\/cit12l\/1","doi-asserted-by":"crossref","first-page":"100766","DOI":"10.1016\/j.cogsc.2023.100766","volume":"40","author":"Dou","year":"2023","journal-title":"Curr. Opin. Green Sustainable Chem."},{"key":"D4SC02412E\/cit12m\/1","doi-asserted-by":"crossref","first-page":"2926","DOI":"10.1039\/D4CC00044G","volume":"60","author":"Zou","year":"2024","journal-title":"Chem. Commun."},{"key":"D4SC02412E\/cit12n\/1","doi-asserted-by":"crossref","first-page":"373","DOI":"10.1016\/j.gresc.2022.04.007","volume":"3","author":"Lang","year":"2022","journal-title":"Green Synth. Catal."}],"container-title":["Chemical Science"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2024\/SC\/D4SC02412E","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,8,14]],"date-time":"2024-08-14T06:28:40Z","timestamp":1723616920000},"score":1,"resource":{"primary":{"URL":"https:\/\/xlink.rsc.org\/?DOI=D4SC02412E"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024]]},"references-count":36,"journal-issue":{"issue":"32","published-print":{"date-parts":[[2024,8,14]]}},"URL":"https:\/\/doi.org\/10.1039\/d4sc02412e","relation":{},"ISSN":["2041-6520","2041-6539"],"issn-type":[{"value":"2041-6520","type":"print"},{"value":"2041-6539","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024]]}}}