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Sci."],"abstract":"<jats:p>\n                    A sterically demanding\n                    <jats:italic>ortho<\/jats:italic>\n                    -CF\n                    <jats:sub>3<\/jats:sub>\n                    substituent defines not only the arrangement of ligands on a Ag\n                    <jats:sub>98<\/jats:sub>\n                    (2-CF\n                    <jats:sub>3<\/jats:sub>\n                    PhC\ue002C)\n                    <jats:sub>48<\/jats:sub>\n                    Cl\n                    <jats:sub>4<\/jats:sub>\n                    nanocluster (Ag98) but also the inter-cluster interactions. Ag98 shows excellent methanol tolerance in the oxygen reduction reaction.\n                  <\/jats:p>","DOI":"10.1039\/d4sc04318a","type":"journal-article","created":{"date-parts":[[2024,10,9]],"date-time":"2024-10-09T04:00:41Z","timestamp":1728446441000},"page":"18161-18169","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Substituent effect in determining the total structure of an all-alkynyl-protected Ag98 nanocluster for methanol tolerant oxygen reduction reaction"],"prefix":"10.1039","volume":"15","author":[{"given":"Xiaoqin","family":"Cui","sequence":"first","affiliation":[{"name":"Institute of Crystalline Materials, Shanxi University, Taiyuan, 030006, Shanxi, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuehuan","family":"Zhang","sequence":"additional","affiliation":[{"name":"Institute of Molecular Science, Shanxi University, Taiyuan, 030006, Shanxi, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ting","family":"Li","sequence":"additional","affiliation":[{"name":"Institute of Crystalline Materials, Shanxi University, Taiyuan, 030006, Shanxi, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1713-0621","authenticated-orcid":false,"given":"Sheng","family":"Zhu","sequence":"additional","affiliation":[{"name":"Institute of Molecular Science, Shanxi University, Taiyuan, 030006, Shanxi, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6115-4703","authenticated-orcid":false,"given":"Gaoyi","family":"Han","sequence":"additional","affiliation":[{"name":"Institute of Molecular Science, Shanxi University, Taiyuan, 030006, Shanxi, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4229-2796","authenticated-orcid":false,"given":"Huan","family":"Li","sequence":"additional","affiliation":[{"name":"Institute of Crystalline Materials, Shanxi University, Taiyuan, 030006, Shanxi, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2024]]},"reference":[{"key":"D4SC04318A\/cit1\/1","doi-asserted-by":"crossref","first-page":"11879","DOI":"10.1021\/jacs.3c02880","volume":"145","author":"Yang","year":"2023","journal-title":"J. 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