{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,5]],"date-time":"2026-09-05T01:57:43Z","timestamp":1788573463639,"version":"build-2803163510"},"reference-count":49,"publisher":"Royal Society of Chemistry (RSC)","issue":"48","license":[{"start":{"date-parts":[[2024,11,11]],"date-time":"2024-11-11T00:00:00Z","timestamp":1731283200000},"content-version":"vor","delay-in-days":315,"URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100000288","name":"Royal Society","doi-asserted-by":"publisher","award":["INF\\R1\\221057"],"award-info":[{"award-number":["INF\\R1\\221057"]}],"id":[{"id":"10.13039\/501100000288","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100010665","name":"H2020 Marie Sk\u0142odowska-Curie Actions","doi-asserted-by":"publisher","award":["860322"],"award-info":[{"award-number":["860322"]}],"id":[{"id":"10.13039\/100010665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100010781","name":"Centro de Instrumentaci\u00f3n Cient\u00edfico-T\u00e9cnica, Universidad de Ja\u00e9n","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100010781","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Sci."],"abstract":"<jats:p>\n                    A highly unusual mechanism for asymmetric hydrogenation catalysed by an anionic Ir\n                    <jats:sup>III<\/jats:sup>\n                    hydride system, including a strong counterion dependence on catalyst activity, is explored and rationalised.\n                  <\/jats:p>","DOI":"10.1039\/d4sc04629c","type":"journal-article","created":{"date-parts":[[2024,11,11]],"date-time":"2024-11-11T04:20:42Z","timestamp":1731298842000},"page":"20478-20492","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Understanding ketone hydrogenation catalysis with anionic iridium(\n                    <scp>iii<\/scp>\n                    ) complexes: the crucial role of counterion and solvation"],"prefix":"10.1039","volume":"15","author":[{"given":"Paven","family":"Kisten","sequence":"first","affiliation":[{"name":"CNRS, LCC (Laboratoire de Chimie de Coordination), Universit\u00e9 de Toulouse, UPS, INPT, 205 Route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France"},{"name":"Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sandrine","family":"Vincendeau","sequence":"additional","affiliation":[{"name":"CNRS, LCC (Laboratoire de Chimie de Coordination), Universit\u00e9 de Toulouse, UPS, INPT, 205 Route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eric","family":"Manoury","sequence":"additional","affiliation":[{"name":"CNRS, LCC (Laboratoire de Chimie de Coordination), Universit\u00e9 de Toulouse, UPS, INPT, 205 Route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0103-9479","authenticated-orcid":false,"given":"Jason M.","family":"Lynam","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6491-8302","authenticated-orcid":false,"given":"John M.","family":"Slattery","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9788-6615","authenticated-orcid":false,"given":"Simon B.","family":"Duckett","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7909-422X","authenticated-orcid":false,"given":"Agust\u00ed","family":"Lled\u00f3s","sequence":"additional","affiliation":[{"name":"Departament de Qu\u00edmica, Universitat Aut\u00f2noma de Barcelona, 08193 Cerdanyola del Vall\u00e8s, Catalonia, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5220-2515","authenticated-orcid":false,"given":"Rinaldo","family":"Poli","sequence":"additional","affiliation":[{"name":"CNRS, LCC (Laboratoire de Chimie de Coordination), Universit\u00e9 de Toulouse, UPS, INPT, 205 Route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France"},{"name":"Institut Universitaire de France, 1, Rue Descartes, 75231 Paris Cedex 05, France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2024]]},"reference":[{"key":"D4SC04629C\/cit1\/1","doi-asserted-by":"crossref","first-page":"3029","DOI":"10.1021\/cr020049i","volume":"103","author":"Tang","year":"2003","journal-title":"Chem. Rev."},{"key":"D4SC04629C\/cit2\/1","doi-asserted-by":"crossref","first-page":"1713","DOI":"10.1021\/cr100218m","volume":"111","author":"Xie","year":"2011","journal-title":"Chem. Rev."},{"key":"D4SC04629C\/cit3\/1","doi-asserted-by":"crossref","first-page":"65","DOI":"10.1007\/3418_2011_27","volume-title":"Organometallics as Catalysts in the Fine Chemical Industry","volume":"42","author":"Blaser","year":"2012","unstructured":"H.-U.Blaser ,  B.Pugin  and  F.Spindler , in  Organometallics as Catalysts in the Fine Chemical Industry , ed.  M. Beller  and  H. U. Blaser ,  2012 ,  vol. 42 ,  pp. 65\u2013102"},{"key":"D4SC04629C\/cit4\/1","doi-asserted-by":"crossref","first-page":"47","DOI":"10.1021\/acs.organomet.8b00774","volume":"38","author":"Seo","year":"2019","journal-title":"Organometallics"},{"key":"D4SC04629C\/cit5\/1","doi-asserted-by":"crossref","first-page":"2557","DOI":"10.1021\/cr200328h","volume":"112","author":"Wang","year":"2012","journal-title":"Chem. Rev."},{"key":"D4SC04629C\/cit6\/1","doi-asserted-by":"crossref","first-page":"3211","DOI":"10.1039\/D0CS00082E","volume":"50","author":"Wen","year":"2021","journal-title":"Chem. Soc. Rev."},{"key":"D4SC04629C\/cit7\/1","doi-asserted-by":"crossref","first-page":"13490","DOI":"10.1021\/ja030272c","volume":"125","author":"Sandoval","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"D4SC04629C\/cit8\/1","doi-asserted-by":"crossref","first-page":"1466","DOI":"10.1021\/ja991638h","volume":"122","author":"Yamakawa","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"D4SC04629C\/cit9\/1","doi-asserted-by":"crossref","first-page":"4368","DOI":"10.1021\/acscatal.5b00613","volume":"5","author":"Hayes","year":"2015","journal-title":"ACS Catal."},{"key":"D4SC04629C\/cit10\/1","doi-asserted-by":"crossref","first-page":"2685","DOI":"10.1016\/j.tetasy.2005.07.027","volume":"16","author":"Routaboul","year":"2005","journal-title":"Tetrahedron: Asymmetry"},{"key":"D4SC04629C\/cit11\/1","doi-asserted-by":"crossref","first-page":"3350","DOI":"10.1039\/B601980C","author":"Malacea","year":"2006","journal-title":"Dalton Trans."},{"key":"D4SC04629C\/cit12\/1","doi-asserted-by":"crossref","first-page":"1803","DOI":"10.1002\/ejic.200600065","author":"Malacea","year":"2006","journal-title":"Eur. J. Inorg. Chem."},{"key":"D4SC04629C\/cit13\/1","doi-asserted-by":"crossref","first-page":"309","DOI":"10.1002\/adsc.200600350","volume":"349","author":"Le Roux","year":"2007","journal-title":"Adv. Synth. Catal."},{"key":"D4SC04629C\/cit14\/1","doi-asserted-by":"crossref","first-page":"2495","DOI":"10.1039\/D2DT04036K","volume":"52","author":"Kisten","year":"2023","journal-title":"Dalton"},{"key":"D4SC04629C\/cit15\/1","doi-asserted-by":"crossref","first-page":"11826","DOI":"10.1021\/ja9822106","volume":"120","author":"Abdur-Rashid","year":"1998","journal-title":"J. Am. Chem. Soc."},{"key":"D4SC04629C\/cit16\/1","doi-asserted-by":"crossref","first-page":"2995","DOI":"10.1021\/ic0255149","volume":"41","author":"Landau","year":"2002","journal-title":"Inorg. Chem."},{"key":"D4SC04629C\/cit17\/1","doi-asserted-by":"crossref","first-page":"5948","DOI":"10.1021\/ja00538a061","volume":"102","author":"Grey","year":"1980","journal-title":"J. Am. Chem. Soc."},{"key":"D4SC04629C\/cit18\/1","doi-asserted-by":"crossref","first-page":"783","DOI":"10.1039\/c39800000783","author":"Grey","year":"1980","journal-title":"Chem. Commun."},{"key":"D4SC04629C\/cit19\/1","doi-asserted-by":"crossref","first-page":"7536","DOI":"10.1021\/ja00415a022","volume":"103","author":"Grey","year":"1981","journal-title":"J. Am. Chem. Soc."},{"key":"D4SC04629C\/cit20\/1","doi-asserted-by":"crossref","first-page":"7528","DOI":"10.1021\/ja00415a021","volume":"103","author":"Pez","year":"1981","journal-title":"J. Am. Chem. Soc."},{"key":"D4SC04629C\/cit21\/1","doi-asserted-by":"crossref","first-page":"235","DOI":"10.1111\/j.1749-6632.1983.tb47362.x","volume":"415","author":"Grey","year":"1983","journal-title":"Ann. N. Y. Acad. Sci."},{"key":"D4SC04629C\/cit22\/1","doi-asserted-by":"crossref","first-page":"2066","DOI":"10.1021\/ja00345a067","volume":"105","author":"Wilczynski","year":"1983","journal-title":"J. Am. Chem. Soc."},{"key":"D4SC04629C\/cit23\/1","doi-asserted-by":"crossref","first-page":"115","DOI":"10.1016\/0022-328X(85)80343-0","volume":"296","author":"Fordyce","year":"1985","journal-title":"J. Organomet. Chem."},{"key":"D4SC04629C\/cit24\/1","doi-asserted-by":"crossref","first-page":"2969","DOI":"10.1021\/ja00244a019","volume":"109","author":"Linn","year":"1987","journal-title":"J. Am. Chem. Soc."},{"key":"D4SC04629C\/cit25\/1","doi-asserted-by":"crossref","first-page":"3505","DOI":"10.1021\/ja411374j","volume":"136","author":"Dub","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"D4SC04629C\/cit26\/1","doi-asserted-by":"crossref","first-page":"85","DOI":"10.1038\/nature11891","volume":"495","author":"Nielsen","year":"2013","journal-title":"Nature"},{"key":"D4SC04629C\/cit27\/1","doi-asserted-by":"crossref","first-page":"14890","DOI":"10.1021\/jacs.6b05692","volume":"138","author":"Alberico","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"D4SC04629C\/cit28\/1","doi-asserted-by":"crossref","first-page":"7531","DOI":"10.1002\/anie.201701365","volume":"56","author":"van Putten","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4SC04629C\/cit29\/1","doi-asserted-by":"crossref","first-page":"136","DOI":"10.1016\/j.jcat.2018.04.018","volume":"363","author":"Liu","year":"2018","journal-title":"J. Catal."},{"key":"D4SC04629C\/cit30\/1","doi-asserted-by":"crossref","first-page":"851","DOI":"10.1002\/cjoc.201800129","volume":"36","author":"Liang","year":"2018","journal-title":"Chin. J. Chem."},{"key":"D4SC04629C\/cit31\/1","doi-asserted-by":"crossref","first-page":"3718","DOI":"10.1038\/s41467-023-39375-8","volume":"14","author":"Yin","year":"2023","journal-title":"Nat. Commun."},{"key":"D4SC04629C\/cit32\/1","doi-asserted-by":"crossref","first-page":"3218","DOI":"10.1002\/chem.200501384","volume":"12","author":"V\u00e4stil\u00e4","year":"2006","journal-title":"Chem.\u2013Eur. J."},{"key":"D4SC04629C\/cit33\/1","doi-asserted-by":"crossref","first-page":"3445","DOI":"10.1002\/cctc.201500718","volume":"7","author":"Slagbrand","year":"2015","journal-title":"ChemCatChem"},{"key":"D4SC04629C\/cit34\/1","doi-asserted-by":"crossref","first-page":"10234","DOI":"10.1021\/ja505241x","volume":"136","author":"Bielinski","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"D4SC04629C\/cit35\/1","doi-asserted-by":"crossref","first-page":"2404","DOI":"10.1021\/acscatal.5b00137","volume":"5","author":"Bielinski","year":"2015","journal-title":"ACS Catal."},{"key":"D4SC04629C\/cit36\/1","doi-asserted-by":"crossref","first-page":"4291","DOI":"10.1039\/C5SC01467K","volume":"6","author":"Zhang","year":"2015","journal-title":"Chem. Sci."},{"key":"D4SC04629C\/cit37\/1","doi-asserted-by":"crossref","first-page":"404","DOI":"10.1039\/C9FD00055K","volume":"220","author":"Govindarajan","year":"2019","journal-title":"Faraday Discuss."},{"key":"D4SC04629C\/cit38\/1","doi-asserted-by":"crossref","first-page":"e202315381","DOI":"10.1002\/anie.202315381","volume":"63","author":"Gawron","year":"2024","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4SC04629C\/cit39\/1","doi-asserted-by":"crossref","first-page":"1638","DOI":"10.1021\/cs501902v","volume":"5","author":"Jia","year":"2015","journal-title":"ACS Catal."},{"key":"D4SC04629C\/cit40\/1","doi-asserted-by":"crossref","first-page":"e202200033","DOI":"10.1002\/ijch.202200033","volume":"63","author":"Epton","year":"2023","journal-title":"Isr. J. Chem."},{"key":"D4SC04629C\/cit41\/1","first-page":"1","volume-title":"Advances in Organometallic Chemistry","volume":"73","author":"Zaccaria","year":"2020","unstructured":"F.Zaccaria ,  L.Sian ,  C.Zuccaccia  and  A.Macchioni , in  Advances in Organometallic Chemistry , ed.  P. J. P\u00e9rez ,  Academic Press ,  2020 ,  vol. 73 ,  pp. 1\u201378"},{"key":"D4SC04629C\/cit42\/1","doi-asserted-by":"crossref","first-page":"603","DOI":"10.1038\/nchem.1405","volume":"4","author":"Phipps","year":"2012","journal-title":"Nat. Chem."},{"key":"D4SC04629C\/cit43\/1","doi-asserted-by":"crossref","first-page":"518","DOI":"10.1002\/anie.201205343","volume":"52","author":"Mahlau","year":"2013","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4SC04629C\/cit44\/1","doi-asserted-by":"crossref","first-page":"2832","DOI":"10.1039\/b801115j","author":"Cordero","year":"2008","journal-title":"Dalton Trans."},{"key":"D4SC04629C\/cit45\/1","doi-asserted-by":"crossref","first-page":"527","DOI":"10.1021\/ct200866d","volume":"8","author":"Marenich","year":"2012","journal-title":"J. Chem. Theory Comput."},{"key":"D4SC04629C\/cit46\/1","doi-asserted-by":"crossref","first-page":"2443","DOI":"10.1134\/S1070363219120193","volume":"89","author":"Smirnov","year":"2019","journal-title":"Russ. J. Gen. Chem."},{"key":"D4SC04629C\/cit47\/1","doi-asserted-by":"crossref","first-page":"1693","DOI":"10.1134\/S1070363220090169","volume":"90","author":"Smirnov","year":"2020","journal-title":"Russ. J. Gen. Chem."},{"key":"D4SC04629C\/cit48\/1","doi-asserted-by":"crossref","first-page":"3208","DOI":"10.1039\/D3CP05449G","volume":"26","author":"Mason","year":"2024","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D4SC04629C\/cit49\/1","doi-asserted-by":"crossref","first-page":"6719","DOI":"10.1038\/s41467-021-27065-2","volume":"12","author":"Wahlers","year":"2021","journal-title":"Nat. Commun."}],"container-title":["Chemical Science"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2024\/SC\/D4SC04629C","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T05:07:36Z","timestamp":1782882456000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/sc\/article\/15\/48\/20478-20492\/869707"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024]]},"references-count":49,"journal-issue":{"issue":"48","published-print":{"date-parts":[[2024,12,11]]}},"URL":"https:\/\/doi.org\/10.1039\/d4sc04629c","relation":{},"ISSN":["2041-6520","2041-6539"],"issn-type":[{"value":"2041-6520","type":"print"},{"value":"2041-6539","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024]]}}}