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Sci."],"abstract":"<jats:p>\n                    The first carbocyclic gallylene [(ADC)\n                    <jats:sub>2<\/jats:sub>\n                    Ga(GaI\n                    <jats:sub>2<\/jats:sub>\n                    )] and bis-gallylene [(ADC)Ga]\n                    <jats:sub>2<\/jats:sub>\n                    (ADC = PhC{N(Dipp)C}\n                    <jats:sub>2<\/jats:sub>\n                    ; Dipp = 2,6-iPr\n                    <jats:sub>2<\/jats:sub>\n                    C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>3<\/jats:sub>\n                    ) featuring a central C\n                    <jats:sub>4<\/jats:sub>\n                    Ga\n                    <jats:sub>2<\/jats:sub>\n                    ring annulated between two 1,3-imidazole rings are prepared by KC\n                    <jats:sub>8<\/jats:sub>\n                    reductions of [(ADC)GaI\n                    <jats:sub>2<\/jats:sub>\n                    ]\n                    <jats:sub>2<\/jats:sub>\n                    .\n                  <\/jats:p>","DOI":"10.1039\/d4sc06782g","type":"journal-article","created":{"date-parts":[[2024,11,14]],"date-time":"2024-11-14T02:02:15Z","timestamp":1731549735000},"page":"2222-2230","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["Annulated carbocyclic gallylene and bis-gallylene with two-coordinated Ga(\n                    <scp>i<\/scp>\n                    ) atoms"],"prefix":"10.1039","volume":"16","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8788-7200","authenticated-orcid":false,"given":"Arne","family":"Merschel","sequence":"first","affiliation":[{"name":"Molecular Inorganic Chemistry and Catalysis, Inorganic and Structural Chemistry, Center for Molecular Materials, Faculty of Chemistry, Universit\u00e4t Bielefeld, Universit\u00e4tsstrasse 25, D-33615, Bielefeld, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shkelqim","family":"Heda","sequence":"additional","affiliation":[{"name":"Molecular Inorganic Chemistry and Catalysis, Inorganic and Structural Chemistry, Center for Molecular Materials, Faculty of Chemistry, Universit\u00e4t Bielefeld, Universit\u00e4tsstrasse 25, D-33615, Bielefeld, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7130-6280","authenticated-orcid":false,"given":"Yury V.","family":"Vishnevskiy","sequence":"additional","affiliation":[{"name":"Molecular Inorganic Chemistry and Catalysis, Inorganic and Structural Chemistry, Center for Molecular Materials, Faculty of Chemistry, Universit\u00e4t Bielefeld, Universit\u00e4tsstrasse 25, D-33615, Bielefeld, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Beate","family":"Neumann","sequence":"additional","affiliation":[{"name":"Molecular Inorganic Chemistry and Catalysis, Inorganic and Structural Chemistry, Center for Molecular Materials, Faculty of Chemistry, Universit\u00e4t Bielefeld, Universit\u00e4tsstrasse 25, D-33615, Bielefeld, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hans-Georg","family":"Stammler","sequence":"additional","affiliation":[{"name":"Molecular Inorganic Chemistry and Catalysis, Inorganic and Structural Chemistry, Center for Molecular Materials, Faculty of Chemistry, Universit\u00e4t Bielefeld, Universit\u00e4tsstrasse 25, D-33615, Bielefeld, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2146-5432","authenticated-orcid":false,"given":"Rajendra S.","family":"Ghadwal","sequence":"additional","affiliation":[{"name":"Molecular Inorganic Chemistry and Catalysis, Inorganic and Structural Chemistry, Center for Molecular Materials, Faculty of Chemistry, Universit\u00e4t Bielefeld, Universit\u00e4tsstrasse 25, D-33615, Bielefeld, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D4SC06782G\/cit1\/1","doi-asserted-by":"crossref","first-page":"361","DOI":"10.1021\/ja00001a054","volume":"113","author":"Arduengo","year":"1991","journal-title":"J. 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