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Sci."],"abstract":"<jats:p>\n                    Compound [Fe(Ph-BIAN)\n                    <jats:sub>3<\/jats:sub>\n                    ](BPh\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    (Ph-BIAN = bis((phenyl)imino)acenaphthene) is the first Fe complex to display thermal- and light-induced valence tautomerism with a spin transition: low-spin-Fe\n                    <jats:sup>III<\/jats:sup>\n                    -(Ph-BIAN\u02d9\n                    <jats:sup>\u2212<\/jats:sup>\n                    )(Ph-BIAN\n                    <jats:sup>0<\/jats:sup>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    \u21cc high-spin-Fe\n                    <jats:sup>II<\/jats:sup>\n                    -(Ph-BIAN\n                    <jats:sup>0<\/jats:sup>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    .\n                  <\/jats:p>","DOI":"10.1039\/d4sc07798a","type":"journal-article","created":{"date-parts":[[2025,2,24]],"date-time":"2025-02-24T16:41:16Z","timestamp":1740415276000},"page":"5857-5871","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Thermal- and light-induced valence tautomerism with a concerted spin transition in an iron tris(diimine) complex"],"prefix":"10.1039","volume":"16","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8646-3388","authenticated-orcid":false,"given":"Jett T.","family":"Janetzki","sequence":"first","affiliation":[{"name":"School of Chemistry, University of Melbourne, Victoria 3010, Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0001-3190-8260","authenticated-orcid":false,"given":"Dominic S.","family":"Brown","sequence":"additional","affiliation":[{"name":"School of Chemistry, University of Melbourne, Victoria 3010, Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0009-2066-4836","authenticated-orcid":false,"given":"Florian","family":"Daumann","sequence":"additional","affiliation":[{"name":"Institute for Inorganic and Analytical Chemistry, Friedrich Schiller University Jena, Humboldtstra\u00dfe 8, 07743 Jena, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5208-4785","authenticated-orcid":false,"given":"I. 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