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Commun."],"abstract":"<jats:p>\n                    Herein we developed a NNO\u2013Mn complex having a relatively low-congestion metal\u2013ligand cooperative environment, one enabling the alkylation of bulky \u03b1-branched ketones with bulky alcohols\n                    <jats:italic>via<\/jats:italic>\n                    a chelation-asisted aldol process.\n                  <\/jats:p>","DOI":"10.1039\/d5cc00048c","type":"journal-article","created":{"date-parts":[[2025,2,26]],"date-time":"2025-02-26T02:01:22Z","timestamp":1740535282000},"page":"4796-4799","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Designing a NNO\u2013manganese complex overcoming steric constraints in (de)hydrogenative coupling"],"prefix":"10.1039","volume":"61","author":[{"given":"Avijit","family":"Mondal","sequence":"first","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology-Guwahati, Kamrup, Assam 781039, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hirak Jyoti","family":"Phukan","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology-Guwahati, Kamrup, Assam 781039, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kailash","family":"Mohar","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology-Guwahati, Kamrup, Assam 781039, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Debjyoti","family":"Pal","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology-Guwahati, Kamrup, Assam 781039, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rahul","family":"Sharma","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology-Guwahati, Kamrup, Assam 781039, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4666-5214","authenticated-orcid":false,"given":"Siddhartha","family":"Purkayastha","sequence":"additional","affiliation":[{"name":"Advanced Computational Chemistry Centre, Cotton University, Guwahati 781001, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4370-8108","authenticated-orcid":false,"given":"Ankur Kanti","family":"Guha","sequence":"additional","affiliation":[{"name":"Advanced Computational Chemistry Centre, Cotton University, Guwahati 781001, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8826-9773","authenticated-orcid":false,"given":"Dipankar","family":"Srimani","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology-Guwahati, Kamrup, Assam 781039, India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5CC00048C\/cit1a\/1","doi-asserted-by":"crossref","first-page":"761","DOI":"10.1002\/anie.201307950","volume":"53","author":"Chan","year":"2014","journal-title":"Angew. 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