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Commun."],"abstract":"<jats:p>\n                    Herein, we describe a TMSCl-promoted allylic phosphorothiolation and intermolecular difunctionalization of alkenes for the divergent synthesis of structurally diverse\n                    <jats:italic>S<\/jats:italic>\n                    -alkyl phosphorothioates from olefins with\n                    <jats:italic>N<\/jats:italic>\n                    -phosphorothiosuccinimide.\n                  <\/jats:p>","DOI":"10.1039\/d5cc04576b","type":"journal-article","created":{"date-parts":[[2025,9,18]],"date-time":"2025-09-18T06:01:36Z","timestamp":1758175296000},"page":"16472-16475","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["TMSCl-promoted allylic phosphorothiolation and intermolecular difunctionalization of alkenes"],"prefix":"10.1039","volume":"61","author":[{"given":"Xu","family":"Chen","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Zhongshan 528458, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingyang","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Zhongshan 528458, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiongying","family":"Yang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Zhongshan 528458, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuesi","family":"Zhou","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Zhongshan 528458, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0004-3301-5740","authenticated-orcid":false,"given":"Wenbin","family":"Xu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Zhongshan 528458, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8825-0175","authenticated-orcid":false,"given":"Hua","family":"Cao","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Zhongshan 528458, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6973-3809","authenticated-orcid":false,"given":"Xiang","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Zhongshan 528458, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5CC04576B\/cit1a\/1","doi-asserted-by":"crossref","first-page":"3210","DOI":"10.1002\/adsc.201900291","volume":"361","author":"Shi","year":"2019","journal-title":"Adv. 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