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Commun."],"abstract":"<jats:p>\n                    Herein, we report the first enantioselective synthesis of axially chiral barbiturate-substituted styrenes\n                    <jats:italic>via<\/jats:italic>\n                    vinylidene\n                    <jats:italic>ortho<\/jats:italic>\n                    -quinone methides using a quinidine-basedorganocatalyst with excellent diastereo- and enantioselectivity (up to 99%).\n                  <\/jats:p>","DOI":"10.1039\/d5cc06302g","type":"journal-article","created":{"date-parts":[[2025,12,9]],"date-time":"2025-12-09T10:05:58Z","timestamp":1765274758000},"page":"1845-1849","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["The atroposelective synthesis of barbiturate-substituted chiral styrenes"],"prefix":"10.1039","volume":"62","author":[{"given":"Manju","family":"Devi","sequence":"first","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology, Delhi, Hauz Khas, New Delhi, 110016, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gyanshree","family":"Jain","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology, Delhi, Hauz Khas, New Delhi, 110016, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Navya","family":"Gupta","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology, Delhi, Hauz Khas, New Delhi, 110016, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Najmuddin","family":"Ansari","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology, Delhi, Hauz Khas, New Delhi, 110016, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ravi P.","family":"Singh","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology, Delhi, Hauz Khas, New Delhi, 110016, India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D5CC06302G\/cit1a\/1","doi-asserted-by":"crossref","first-page":"1562","DOI":"10.1039\/C4NP00121D","volume":"32","author":"Smyth","year":"2015","journal-title":"Nat. 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