{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T20:20:53Z","timestamp":1782937253085,"version":"3.54.5"},"reference-count":58,"publisher":"Royal Society of Chemistry (RSC)","issue":"14","license":[{"start":{"date-parts":[[2026,3,17]],"date-time":"2026-03-17T00:00:00Z","timestamp":1773705600000},"content-version":"am","delay-in-days":440,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22003034"],"award-info":[{"award-number":["22003034"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22121002"],"award-info":[{"award-number":["22121002"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22373061"],"award-info":[{"award-number":["22373061"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["92161205"],"award-info":[{"award-number":["92161205"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["92461303"],"award-info":[{"award-number":["92461303"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Phys. Chem. Chem. Phys."],"abstract":"<jats:p>\n                    Joint chemisorption and theoretical investigations evidence the existence of the first boron carbonyl complexes B\n                    <jats:sub>11<\/jats:sub>\n                    (CO)\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    <jats:sup>+<\/jats:sup>\n                    (\n                    <jats:italic>n<\/jats:italic>\n                    = 1\u20136) and B\n                    <jats:sub>15<\/jats:sub>\n                    (CO)\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    <jats:sup>+<\/jats:sup>\n                    (\n                    <jats:italic>n<\/jats:italic>\n                    = 1\u20135) with \u03c0 and \u03c3 conflicting aromaticity analogous to C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    and C\n                    <jats:sub>8<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    in \u03c0-bonding, respectively.\n                  <\/jats:p>","DOI":"10.1039\/d5cp00755k","type":"journal-article","created":{"date-parts":[[2025,3,17]],"date-time":"2025-03-17T09:20:56Z","timestamp":1742203256000},"page":"7279-7287","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Observation of boron carbonyl complexes B\n                    <sub>11<\/sub>\n                    (CO)\n                    <sub>\n                      <i>n<\/i>\n                    <\/sub>\n                    <sup>+<\/sup>\n                    (\n                    <i>n<\/i>\n                    = 1\u20136) and B\n                    <sub>15<\/sub>\n                    (CO)\n                    <sub>\n                      <i>n<\/i>\n                    <\/sub>\n                    <sup>+<\/sup>\n                    (\n                    <i>n<\/i>\n                    = 1\u20135) with conflicting aromaticity"],"prefix":"10.1039","volume":"27","author":[{"given":"Rui-Nan","family":"Yuan","sequence":"first","affiliation":[{"name":"Institute of Molecular Science, Shanxi University, Taiyuan 030006, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1488-1369","authenticated-orcid":false,"given":"Qiang","family":"Chen","sequence":"additional","affiliation":[{"name":"Institute of Molecular Science, Shanxi University, Taiyuan 030006, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hong","family":"Niu","sequence":"additional","affiliation":[{"name":"Institute of Molecular Science, Shanxi University, Taiyuan 030006, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cai-Yue","family":"Gao","sequence":"additional","affiliation":[{"name":"Institute of Molecular Science, Shanxi University, Taiyuan 030006, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao-Ni","family":"Zhao","sequence":"additional","affiliation":[{"name":"Institute of Molecular Science, Shanxi University, Taiyuan 030006, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6032-9957","authenticated-orcid":false,"given":"Yan-Bo","family":"Wu","sequence":"additional","affiliation":[{"name":"Institute of Molecular Science, Shanxi University, Taiyuan 030006, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9919-6909","authenticated-orcid":false,"given":"Sheng-Gui","family":"He","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5666-0591","authenticated-orcid":false,"given":"Si-Dian","family":"Li","sequence":"additional","affiliation":[{"name":"Institute of Molecular Science, Shanxi University, Taiyuan 030006, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5CP00755K\/cit1\/1","doi-asserted-by":"crossref","first-page":"526","DOI":"10.1016\/j.chempr.2018.11.006","volume":"5","author":"Peng","year":"2019","journal-title":"Chem"},{"key":"D5CP00755K\/cit2\/1","doi-asserted-by":"crossref","first-page":"21","DOI":"10.1016\/0022-328X(90)85120-N","volume":"383","author":"Herrmann","year":"1990","journal-title":"J. Organomet. Chem."},{"key":"D5CP00755K\/cit3\/1","doi-asserted-by":"crossref","first-page":"749","DOI":"10.1039\/CT8905700749","volume":"57","author":"Mond","year":"1890","journal-title":"J. Chem. Soc. Trans."},{"key":"D5CP00755K\/cit4\/1","doi-asserted-by":"crossref","first-page":"5298","DOI":"10.1021\/jp981356o","volume":"102","author":"Jang","year":"1998","journal-title":"J. Phys. Chem. A"},{"key":"D5CP00755K\/cit5\/1","doi-asserted-by":"crossref","first-page":"83","DOI":"10.1016\/S0010-8545(02)00115-7","volume":"231","author":"Xu","year":"2002","journal-title":"Coord. Chem. Rev."},{"key":"D5CP00755K\/cit6\/1","doi-asserted-by":"crossref","first-page":"6449","DOI":"10.1021\/ja000663g","volume":"122","author":"Diefenbach","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"D5CP00755K\/cit7\/1","doi-asserted-by":"crossref","first-page":"e202305490","DOI":"10.1002\/anie.202305490","volume":"62","author":"Wang","year":"2023","journal-title":"Angew. Chem. Int. Ed."},{"key":"D5CP00755K\/cit8\/1","doi-asserted-by":"crossref","first-page":"6236","DOI":"10.1002\/anie.201802590","volume":"57","author":"Jin","year":"2018","journal-title":"Angew. Chem. Int. Ed."},{"key":"D5CP00755K\/cit9\/1","doi-asserted-by":"crossref","first-page":"912","DOI":"10.1126\/science.aau0839","volume":"361","author":"Wu","year":"2018","journal-title":"Science"},{"key":"D5CP00755K\/cit10\/1","doi-asserted-by":"crossref","first-page":"780","DOI":"10.1021\/ja01284a002","volume":"59","author":"Burg","year":"1937","journal-title":"J. Am. Chem. Soc."},{"key":"D5CP00755K\/cit11\/1","doi-asserted-by":"crossref","first-page":"115","DOI":"10.1021\/ja01055a027","volume":"86","author":"Knoth","year":"1964","journal-title":"J. Am. Chem. Soc."},{"key":"D5CP00755K\/cit12\/1","doi-asserted-by":"crossref","first-page":"2487","DOI":"10.1039\/a806898d","author":"Fox","year":"1998","journal-title":"Chem. Commun."},{"key":"D5CP00755K\/cit13\/1","doi-asserted-by":"crossref","first-page":"2840","DOI":"10.1021\/j100160a039","volume":"95","author":"Hamrick","year":"1991","journal-title":"J. Phys. Chem."},{"key":"D5CP00755K\/cit14\/1","doi-asserted-by":"crossref","first-page":"12936","DOI":"10.1021\/ja026257+","volume":"124","author":"Zhou","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"D5CP00755K\/cit15\/1","doi-asserted-by":"crossref","first-page":"763","DOI":"10.1002\/cphc.200300736","volume":"4","author":"Zhou","year":"2003","journal-title":"ChemPhysChem"},{"key":"D5CP00755K\/cit16\/1","doi-asserted-by":"crossref","first-page":"10195","DOI":"10.1021\/j100204a020","volume":"96","author":"Burkholder","year":"1992","journal-title":"J. Phys. Chem."},{"key":"D5CP00755K\/cit17\/1","doi-asserted-by":"crossref","first-page":"14854","DOI":"10.1021\/ja027865s","volume":"124","author":"Zhou","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"D5CP00755K\/cit18\/1","doi-asserted-by":"crossref","first-page":"e202200060","DOI":"10.1002\/cphc.202200060","volume":"23","author":"Zhao","year":"2022","journal-title":"ChemPhysChem"},{"key":"D5CP00755K\/cit19\/1","doi-asserted-by":"crossref","first-page":"47","DOI":"10.1063\/1674-0068\/29\/cjcp1512238","volume":"29","author":"Jin","year":"2016","journal-title":"Chin. J. Chem. Phys."},{"key":"D5CP00755K\/cit20\/1","doi-asserted-by":"crossref","first-page":"2688","DOI":"10.1021\/acs.jpca.8b00440","volume":"122","author":"Jin","year":"2018","journal-title":"J. Phys. Chem. A"},{"key":"D5CP00755K\/cit21\/1","doi-asserted-by":"crossref","first-page":"2078","DOI":"10.1002\/anie.201509826","volume":"55","author":"Jin","year":"2016","journal-title":"Angew. Chem. Int. Ed."},{"key":"D5CP00755K\/cit22\/1","doi-asserted-by":"crossref","first-page":"17192","DOI":"10.1039\/C8DT03236J","volume":"47","author":"Jin","year":"2018","journal-title":"Dalton Trans."},{"key":"D5CP00755K\/cit23\/1","doi-asserted-by":"crossref","first-page":"8157","DOI":"10.1039\/D1SC00534K","volume":"12","author":"Tian","year":"2021","journal-title":"Chem. Sci."},{"key":"D5CP00755K\/cit24\/1","doi-asserted-by":"crossref","first-page":"31464","DOI":"10.1021\/jacs.4c07680","volume":"146","author":"Yuan","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"D5CP00755K\/cit25\/1","doi-asserted-by":"crossref","first-page":"014317","DOI":"10.1063\/1.4732308","volume":"137","author":"Romanescu","year":"2012","journal-title":"J. Chem. Phys."},{"key":"D5CP00755K\/cit26\/1","doi-asserted-by":"crossref","first-page":"1081","DOI":"10.1002\/qua.560520432","volume":"52","author":"Boustani","year":"1994","journal-title":"Int. J. Quantum Chem."},{"key":"D5CP00755K\/cit27\/1","doi-asserted-by":"crossref","first-page":"8503","DOI":"10.1002\/anie.200701915","volume":"46","author":"Oger","year":"2007","journal-title":"Angew. Chem. Int. Ed."},{"key":"D5CP00755K\/cit28\/1","doi-asserted-by":"crossref","first-page":"15774","DOI":"10.1039\/C6CP02544G","volume":"18","author":"Wang","year":"2016","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D5CP00755K\/cit29\/1","doi-asserted-by":"crossref","first-page":"226","DOI":"10.1063\/1.457510","volume":"91","author":"Ruatta","year":"1989","journal-title":"J. Chem. Phys."},{"key":"D5CP00755K\/cit30\/1","doi-asserted-by":"crossref","first-page":"6446","DOI":"10.1063\/1.460274","volume":"94","author":"Hintz","year":"1991","journal-title":"J. Chem. Phys."},{"key":"D5CP00755K\/cit31\/1","doi-asserted-by":"crossref","first-page":"9511","DOI":"10.1063\/1.473841","volume":"106","author":"Sowa-Resat","year":"1997","journal-title":"J. Chem. Phys."},{"key":"D5CP00755K\/cit32\/1","doi-asserted-by":"crossref","first-page":"2833","DOI":"10.1063\/1.459806","volume":"94","author":"Ruatta","year":"1991","journal-title":"J. Chem. Phys."},{"key":"D5CP00755K\/cit33\/1","doi-asserted-by":"crossref","first-page":"292","DOI":"10.1063\/1.458571","volume":"92","author":"Hintz","year":"1990","journal-title":"J. Chem. Phys."},{"key":"D5CP00755K\/cit34\/1","doi-asserted-by":"crossref","first-page":"2848","DOI":"10.1063\/1.454989","volume":"89","author":"Hanley","year":"1988","journal-title":"J. Chem. Phys."},{"key":"D5CP00755K\/cit35\/1","doi-asserted-by":"crossref","first-page":"57","DOI":"10.1016\/j.ijms.2011.11.011","volume":"310","author":"Wu","year":"2012","journal-title":"Int. J. Mass Spectrom."},{"key":"D5CP00755K\/cit36\/1","doi-asserted-by":"crossref","first-page":"105","DOI":"10.1016\/j.ijms.2013.06.004","volume":"354","author":"Yuan","year":"2013","journal-title":"Int. J. Mass Spectrom."},{"key":"D5CP00755K\/cit37\/1","doi-asserted-by":"crossref","first-page":"1469","DOI":"10.1039\/b516348j","author":"O\u2019Hair","year":"2006","journal-title":"Chem. Commun."},{"key":"D5CP00755K\/cit38\/1","doi-asserted-by":"crossref","first-page":"282","DOI":"10.1016\/S0009-2614(01)00447-X","volume":"340","author":"Socaciu","year":"2001","journal-title":"Chem. Phys. Lett."},{"key":"D5CP00755K\/cit39\/1","doi-asserted-by":"crossref","first-page":"14967","DOI":"10.1021\/jp5040344","volume":"118","author":"Yuan","year":"2014","journal-title":"J. Phys. Chem. C"},{"key":"D5CP00755K\/cit41\/1","doi-asserted-by":"crossref","first-page":"6158","DOI":"10.1063\/1.478522","volume":"110","author":"Adamo","year":"1999","journal-title":"J. Chem. Phys."},{"key":"D5CP00755K\/cit42\/1","doi-asserted-by":"crossref","first-page":"650","DOI":"10.1063\/1.438955","volume":"72","author":"Krishnan","year":"1980","journal-title":"J. Chem. Phys."},{"key":"D5CP00755K\/cit43\/1","doi-asserted-by":"crossref","first-page":"1910","DOI":"10.1063\/1.443164","volume":"76","author":"Purvis","year":"1982","journal-title":"J. Chem. Phys."},{"key":"D5CP00755K\/cit44\/1","doi-asserted-by":"crossref","first-page":"3700","DOI":"10.1063\/1.455827","volume":"90","author":"Scuseria","year":"1989","journal-title":"J. Chem. Phys."},{"key":"D5CP00755K\/cit45\/1","doi-asserted-by":"crossref","first-page":"7382","DOI":"10.1063\/1.455269","volume":"89","author":"Scuseria","year":"1988","journal-title":"J. Chem. Phys."},{"key":"D5CP00755K\/cit46\/1","doi-asserted-by":"crossref","first-page":"2154","DOI":"10.1063\/1.456010","volume":"90","author":"Gonzalez","year":"1989","journal-title":"J. Chem. Phys."},{"key":"D5CP00755K\/cit47\/1","doi-asserted-by":"crossref","first-page":"5523","DOI":"10.1021\/j100377a021","volume":"94","author":"Gonzalez","year":"1990","journal-title":"J. Phys. Chem."},{"key":"D5CP00755K\/cit48\/1","doi-asserted-by":"crossref","first-page":"103","DOI":"10.1016\/j.cpc.2004.12.014","volume":"167","author":"VandeVondele","year":"2005","journal-title":"Comput. Phys. Commun."},{"key":"D5CP00755K\/cit49\/1","doi-asserted-by":"crossref","first-page":"1703","DOI":"10.1103\/PhysRevB.54.1703","volume":"54","author":"Goedecker","year":"1996","journal-title":"Phys. Rev. B: Condens. Matter Mater. Phys."},{"key":"D5CP00755K\/cit50\/1","doi-asserted-by":"crossref","first-page":"10304","DOI":"10.1021\/acs.jpclett.1c02918","volume":"12","author":"Li","year":"2021","journal-title":"J. Phys. Chem. Lett."},{"key":"D5CP00755K\/cit51\/1","doi-asserted-by":"crossref","first-page":"9590","DOI":"10.1039\/C9CP00379G","volume":"21","author":"Tkachenko","year":"2019","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D5CP00755K\/cit52\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1007\/BF02401406","volume":"46","author":"Ziegler","year":"1977","journal-title":"Theor. Chim. Acta"},{"key":"D5CP00755K\/cit53\/1","doi-asserted-by":"crossref","first-page":"962","DOI":"10.1021\/ct800503d","volume":"5","author":"Mitoraj","year":"2009","journal-title":"J. Chem. Theory Comput."},{"key":"D5CP00755K\/cit54\/1","doi-asserted-by":"crossref","first-page":"6576","DOI":"10.1021\/om700754n","volume":"26","author":"Mitoraj","year":"2007","journal-title":"Organometallics"},{"key":"D5CP00755K\/cit55\/1","doi-asserted-by":"crossref","first-page":"931","DOI":"10.1002\/jcc.1056","volume":"22","author":"Velde","year":"2001","journal-title":"J. Comput. Chem."},{"key":"D5CP00755K\/cit56\/1","doi-asserted-by":"crossref","first-page":"4597","DOI":"10.1063\/1.466059","volume":"99","author":"VanLenthe","year":"1993","journal-title":"J. Chem. Phys."},{"key":"D5CP00755K\/cit57\/1","doi-asserted-by":"crossref","first-page":"17639","DOI":"10.1039\/C6NR06383G","volume":"8","author":"Jalife","year":"2016","journal-title":"Nanoscale"},{"key":"D5CP00755K\/cit58\/1","doi-asserted-by":"crossref","first-page":"827","DOI":"10.1038\/nmat1012","volume":"2","author":"Zhai","year":"2003","journal-title":"Nat. Mater."},{"key":"D5CP00755K\/cit59\/1","doi-asserted-by":"crossref","first-page":"54","DOI":"10.1007\/s00894-024-06276-6","volume":"31","author":"Zhang","year":"2025","journal-title":"J. Mol. Model."}],"container-title":["Physical Chemistry Chemical Physics"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/CP\/D5CP00755K","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T18:25:39Z","timestamp":1782930339000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/cp\/article\/27\/14\/7279-7287\/886162"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025]]},"references-count":58,"journal-issue":{"issue":"14","published-print":{"date-parts":[[2025,4,3]]}},"URL":"https:\/\/doi.org\/10.1039\/d5cp00755k","relation":{},"ISSN":["1463-9076","1463-9084"],"issn-type":[{"value":"1463-9076","type":"print"},{"value":"1463-9084","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025]]}}}