{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T19:16:21Z","timestamp":1788290181926,"version":"build-2803163510"},"reference-count":46,"publisher":"Royal Society of Chemistry (RSC)","issue":"21","license":[{"start":{"date-parts":[[2025,5,6]],"date-time":"2025-05-06T00:00:00Z","timestamp":1746489600000},"content-version":"vor","delay-in-days":125,"URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100000038","name":"Natural Sciences and Engineering Research Council of Canada","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100000038","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<jats:p>\n                    [\n                    <jats:italic>t<\/jats:italic>\n                    Bu\n                    <jats:sub>3<\/jats:sub>\n                    PCO\n                    <jats:sub>2<\/jats:sub>\n                    B(C\n                    <jats:sub>6<\/jats:sub>\n                    F\n                    <jats:sub>5<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    ] 1 and [TMPH][C\n                    <jats:sub>5<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    Me\n                    <jats:sub>4<\/jats:sub>\n                    NCO\n                    <jats:sub>2<\/jats:sub>\n                    B(C\n                    <jats:sub>6<\/jats:sub>\n                    F\n                    <jats:sub>5<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    ] 7 act as FLP precursors and react with H\n                    <jats:sub>2<\/jats:sub>\n                    , disulfides, alkynes, silanes and phenols. While 7 is a FLP catalyst precursor for the hydrogenation and hydrosilylation of selected substrates.\n                  <\/jats:p>","DOI":"10.1039\/d5dt00942a","type":"journal-article","created":{"date-parts":[[2025,5,6]],"date-time":"2025-05-06T12:20:53Z","timestamp":1746534053000},"page":"8410-8414","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["FLP-CO\n                    <sub>2<\/sub>\n                    adducts: convenient sources of frustrated Lewis pairs for stoichiometric and catalytic chemistry"],"prefix":"10.1039","volume":"54","author":[{"given":"Jordan","family":"Thomson","sequence":"first","affiliation":[{"name":"Department of Chemistry, University of Toronto, 80 St George St, Toronto, ON, M5S3H6, Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3016-2487","authenticated-orcid":false,"given":"Marc-Andr\u00e9","family":"Courtemanche","sequence":"additional","affiliation":[{"name":"Dow Performance Silicones, Product Development, 2200 W Salzburg Road, Auburn, MI, 48611, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rebecca C.","family":"Neu","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Toronto, 80 St George St, Toronto, ON, M5S3H6, Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8140-8355","authenticated-orcid":false,"given":"Douglas W.","family":"Stephan","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Toronto, 80 St George St, Toronto, ON, M5S3H6, Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5DT00942A\/cit1\/1","first-page":"212","author":"Massey","year":"1963","journal-title":"Proc. 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