{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,14]],"date-time":"2026-07-14T04:08:38Z","timestamp":1784002118406,"version":"3.55.0"},"reference-count":39,"publisher":"Royal Society of Chemistry (RSC)","issue":"39","license":[{"start":{"date-parts":[[2025,8,8]],"date-time":"2025-08-08T00:00:00Z","timestamp":1754611200000},"content-version":"vor","delay-in-days":219,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/100000078","name":"Division of Materials Research","doi-asserted-by":"publisher","award":["DMR-2350483"],"award-info":[{"award-number":["DMR-2350483"]}],"id":[{"id":"10.13039\/100000078","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000181","name":"Air Force Office of Scientific Research","doi-asserted-by":"publisher","award":["FA9550-20-10018"],"award-info":[{"award-number":["FA9550-20-10018"]}],"id":[{"id":"10.13039\/100000181","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["CHE 0840305"],"award-info":[{"award-number":["CHE 0840305"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<jats:p>Response surface methodology was employed to understand the impact that synthetic conditions of hydrogen silsesquixoane (HSQ) polymer have on polymer structure (cage %) and the resultant silicon nanocrystals\u2019 photoluminescent quantum yield (PLQY %).<\/jats:p>","DOI":"10.1039\/d5dt01479d","type":"journal-article","created":{"date-parts":[[2025,8,8]],"date-time":"2025-08-08T20:21:02Z","timestamp":1754684462000},"page":"14954-14961","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Data-driven prediction of HSQ polymer structure and silicon nanocrystal photoluminescence"],"prefix":"10.1039","volume":"54","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-0080-280X","authenticated-orcid":false,"given":"Maharram","family":"Jabrayilov","sequence":"first","affiliation":[{"name":"Department of Chemical and Biological Engineering, Iowa State University, Ames, Iowa 50011, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2500-7968","authenticated-orcid":false,"given":"Jeremy B.","family":"Essner","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biological Engineering, Iowa State University, Ames, Iowa 50011, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7480-5245","authenticated-orcid":false,"given":"Abhijit","family":"Bera","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biological Engineering, Iowa State University, Ames, Iowa 50011, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vinny","family":"Paris","sequence":"additional","affiliation":[{"name":"Department of Statistics, Iowa State University, Ames, Iowa 50011, USA"},{"name":"Department of Statistics, Grinnell College, Grinnell, Iowa 50112, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3795-2051","authenticated-orcid":false,"given":"Matthew G.","family":"Panthani","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biological Engineering, Iowa State University, Ames, Iowa 50011, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5DT01479D\/cit1\/1","doi-asserted-by":"crossref","first-page":"558","DOI":"10.1103\/PhysRev.146.558","volume":"146","author":"Kane","year":"1966","journal-title":"Phys. Rev."},{"key":"D5DT01479D\/cit2\/1","doi-asserted-by":"crossref","first-page":"1703","DOI":"10.1109\/JRPROC.1955.278039","volume":"43","author":"Herman","year":"1955","journal-title":"Proc. IRE"},{"key":"D5DT01479D\/cit3\/1","doi-asserted-by":"crossref","first-page":"349","DOI":"10.1038\/s41586-018-0028-z","volume":"556","author":"Atabaki","year":"2018","journal-title":"Nature"},{"key":"D5DT01479D\/cit4\/1","doi-asserted-by":"crossref","first-page":"L2207","DOI":"10.1143\/JJAP.27.L2207","volume":"27","author":"Furukawa","year":"1988","journal-title":"Jpn. J. Appl. Phys."},{"key":"D5DT01479D\/cit5\/1","doi-asserted-by":"crossref","first-page":"1397","DOI":"10.1103\/PhysRevB.47.1397","volume":"47","author":"Delley","year":"1993","journal-title":"Phys. Rev. B: Condens. Matter Mater. Phys."},{"key":"D5DT01479D\/cit6\/1","doi-asserted-by":"crossref","first-page":"351","DOI":"10.1063\/1.125751","volume":"76","author":"Brongersma","year":"2000","journal-title":"Appl. Phys. Lett."},{"key":"D5DT01479D\/cit7\/1","doi-asserted-by":"crossref","first-page":"1046","DOI":"10.1063\/1.103561","volume":"57","author":"Canham","year":"1990","journal-title":"Appl. Phys. Lett."},{"key":"D5DT01479D\/cit8\/1","doi-asserted-by":"crossref","first-page":"24","DOI":"10.1557\/S0883769400031237","volume":"23","author":"Nozik","year":"1998","journal-title":"MRS Bull."},{"key":"D5DT01479D\/cit9\/1","doi-asserted-by":"crossref","first-page":"2443","DOI":"10.1021\/acs.nanolett.2c03138","volume":"23","author":"Yang","year":"2023","journal-title":"Nano Lett."},{"key":"D5DT01479D\/cit10\/1","doi-asserted-by":"crossref","first-page":"6139","DOI":"10.1021\/cm0602803","volume":"18","author":"Hessel","year":"2006","journal-title":"Chem. Mater."},{"key":"D5DT01479D\/cit11\/1","doi-asserted-by":"crossref","first-page":"6956","DOI":"10.1021\/jp070908c","volume":"111","author":"Hessel","year":"2007","journal-title":"J. Phys. Chem. C"},{"key":"D5DT01479D\/cit12\/1","doi-asserted-by":"crossref","first-page":"393","DOI":"10.1021\/cm2032866","volume":"24","author":"Hessel","year":"2011","journal-title":"Chem. Mater."},{"key":"D5DT01479D\/cit13\/1","doi-asserted-by":"crossref","first-page":"69","DOI":"10.1116\/1.589837","volume":"16","author":"Namatsu","year":"1998","journal-title":"J. Vac. Sci. Technol., B: Microelectron. Nanometer Struct.\u2013Process., Meas., Phenom."},{"key":"D5DT01479D\/cit14\/1","doi-asserted-by":"crossref","first-page":"3497","DOI":"10.1116\/1.1825014","volume":"22","author":"Schmid","year":"2004","journal-title":"J. Vac. Sci. Technol., B: Microelectron. Nanometer Struct.\u2013Process., Meas., Phenom."},{"key":"D5DT01479D\/cit15\/1","doi-asserted-by":"crossref","first-page":"346","DOI":"10.1021\/cm203085f","volume":"24","author":"Rodr\u00edguez N\u00fa\u00f1ez","year":"2012","journal-title":"Chem. Mater."},{"key":"D5DT01479D\/cit16\/1","doi-asserted-by":"crossref","first-page":"3325","DOI":"10.1021\/jz501609e","volume":"5","author":"Locritani","year":"2014","journal-title":"J. Phys. Chem. Lett."},{"key":"D5DT01479D\/cit17\/1","doi-asserted-by":"crossref","first-page":"1373","DOI":"10.1021\/acsami.1c18779","volume":"14","author":"Ono","year":"2022","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"D5DT01479D\/cit18\/1","doi-asserted-by":"crossref","first-page":"8766","DOI":"10.1021\/acs.langmuir.7b00518","volume":"33","author":"Amirul Islam","year":"2017","journal-title":"Langmuir"},{"key":"D5DT01479D\/cit19\/1","doi-asserted-by":"crossref","first-page":"985","DOI":"10.1021\/acsami.3c11120","volume":"16","author":"Ueda","year":"2023","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"D5DT01479D\/cit20\/1","doi-asserted-by":"crossref","first-page":"5426","DOI":"10.1021\/cm902028q","volume":"21","author":"Henderson","year":"2009","journal-title":"Chem. Mater."},{"key":"D5DT01479D\/cit21\/1","doi-asserted-by":"crossref","first-page":"17211","DOI":"10.1038\/s41598-022-21698-z","volume":"12","author":"Shirahata","year":"2022","journal-title":"Sci. Rep."},{"key":"D5DT01479D\/cit22\/1","doi-asserted-by":"crossref","first-page":"3421","DOI":"10.1021\/acs.jpcc.0c10027","volume":"125","author":"Nur Gamze \u00d6zbilgin","year":"2021","journal-title":"J. Phys. Chem. C"},{"key":"D5DT01479D\/cit23\/1","doi-asserted-by":"crossref","first-page":"8382","DOI":"10.1021\/acs.chemmater.0c02320","volume":"32","author":"Terada","year":"2020","journal-title":"Chem. Mater."},{"key":"D5DT01479D\/cit24\/1","doi-asserted-by":"crossref","first-page":"8909","DOI":"10.1021\/acs.jpclett.1c02187","volume":"12","author":"Zhou","year":"2021","journal-title":"J. Phys. Chem. Lett."},{"key":"D5DT01479D\/cit25\/1","doi-asserted-by":"crossref","first-page":"5586","DOI":"10.1021\/ja00722a009","volume":"92","author":"Frye","year":"1970","journal-title":"J. Am. Chem. Soc."},{"key":"D5DT01479D\/cit26\/1","doi-asserted-by":"crossref","first-page":"2707","DOI":"10.1021\/ic00013a002","volume":"30","author":"Agaskar","year":"1991","journal-title":"Inorg. Chem."},{"key":"D5DT01479D\/cit27\/1","doi-asserted-by":"crossref","first-page":"2653","DOI":"10.1002\/app.13446","volume":"91","author":"Liu","year":"2004","journal-title":"J. Appl. Polym. Sci."},{"key":"D5DT01479D\/cit28\/1","doi-asserted-by":"crossref","first-page":"749","DOI":"10.1063\/1.1587876","volume":"83","author":"Soraru","year":"2003","journal-title":"Appl. Phys. Lett."},{"key":"D5DT01479D\/cit29\/1","volume-title":"Response surface methodology: process and product optimization using designed experiments","author":"Myers","year":"2016","unstructured":"R. H.Myers ,  D. C.Montgomery  and  C. M.Anderson-Cook ,  Response surface methodology: process and product optimization using designed experiments ,  John Wiley & Sons ,  2016"},{"key":"D5DT01479D\/cit30\/1","doi-asserted-by":"crossref","first-page":"8909","DOI":"10.1021\/acs.jpclett.1c02187","volume":"12","author":"Zhou","year":"2021","journal-title":"J. Phys. Chem. Lett."},{"key":"D5DT01479D\/cit31\/1","doi-asserted-by":"crossref","first-page":"2861","DOI":"10.1149\/1.1838726","volume":"145","author":"Loboda","year":"1998","journal-title":"J. Electrochem. Soc."},{"key":"D5DT01479D\/cit32\/1","doi-asserted-by":"crossref","first-page":"2861","DOI":"10.1149\/1.1838726","volume":"145","author":"Loboda","year":"1998","journal-title":"J. Electrochem. Soc."},{"key":"D5DT01479D\/cit33\/1","volume-title":"Experiments with mixtures: designs, models, and the analysis of mixture data","volume":"255","author":"Cornell","year":"1843","unstructured":"J. A.Cornell ,  Experiments with mixtures: designs, models, and the analysis of mixture data ,  Wiley-interscience ,  1843 , vol.  255"},{"key":"D5DT01479D\/cit34\/1","first-page":"9","volume":"79","author":"Downs","year":"1994","journal-title":"Am. Mineral."},{"key":"D5DT01479D\/cit35\/1","first-page":"971","volume":"61","author":"Dollase","year":"1976","journal-title":"Am. Mineral."},{"key":"D5DT01479D\/cit36\/1","doi-asserted-by":"crossref","first-page":"235","DOI":"10.1016\/j.egypro.2010.07.034","volume":"2","author":"Westra","year":"2010","journal-title":"Energy Procedia"},{"key":"D5DT01479D\/cit37\/1","first-page":"173201","volume":"26","author":"Dohnalov\u00e1","year":"2014","journal-title":"J. Phys.: Condens. Matter"},{"key":"D5DT01479D\/cit38\/1","doi-asserted-by":"crossref","first-page":"1232","DOI":"10.1021\/ac101329h","volume":"83","author":"Rurack","year":"2011","journal-title":"Anal. Chem."},{"key":"D5DT01479D\/cit39\/1","doi-asserted-by":"crossref","first-page":"80","DOI":"10.1021\/acs.chemmater.6b02667","volume":"29","author":"Clark","year":"2016","journal-title":"Chem. Mater."}],"container-title":["Dalton Transactions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/DT\/D5DT01479D","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/DT\/D5DT01479D","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T05:30:33Z","timestamp":1782883833000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/dt\/article\/54\/39\/14954-14961\/889990"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025]]},"references-count":39,"journal-issue":{"issue":"39","published-print":{"date-parts":[[2025,10,7]]}},"URL":"https:\/\/doi.org\/10.1039\/d5dt01479d","relation":{},"ISSN":["1477-9226","1477-9234"],"issn-type":[{"value":"1477-9226","type":"print"},{"value":"1477-9234","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025]]}}}